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In Turkey, the commercial laundry wastewater is usually discharged to the receiving water bodies and its reuse potential is ignored. This wastewater is grouped into the greywater due to their content of organic and inorganic pollutants. In recent years, the sequential processes have become more preferable in greywater treatment and reuse. In this study, a batch adsorption process was applied for further treatment of commercial laundry wastewater which is also pre-treated by means of the electrocoagulation process. In adsorption, two different composites of waste hazelnut shell derived activated carbons, which are supported with polyaniline (PAn/HS) and polypyrrole (PPy/HS), were used as adsorbents. The efficiency of the process was evaluated by means of an experimental design, and the response surface methodology was applied for this purpose. In the experiment with PAn/HS, the chemical oxygen demand (COD) 75% removal efficiency was accomplished with adsorbent dosage of 0.9 g, at pH 8, with 125 rpm mixing rate and for 77.5 min reaction time. For PPy/HS under the same experimental conditions, the COD removal efficiency was obtained as 20%. The utilization of waste hazelnut shell derived composites as adsorbents for commercial laundry wastewater treatment is a good alternative. The production costs of adsorbents were estimated as 0.70 USD/g and 3.21 USD/g for PAn/HS and PPy/HS, respectively. In terms of the production cost, the PAn/HS composite is approved more agreeable as adsorbents for commercial laundry wastewater treatment.
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Tom
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165--171
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Bibliogr. 21 poz., rys., tab.
Twórcy
autor
- University of Kocaeli, Department of Environmental Engineering, 41380 Kocaeli, Turkey
autor
- University of Kocaeli, Department of Environmental Engineering, 41380 Kocaeli, Turkey
autor
- University of Kocaeli, Department of Environmental Engineering, 41380 Kocaeli, Turkey
autor
- University of Kocaeli, Department of Environmental Engineering, 41380 Kocaeli, Turkey
autor
- University of Kocaeli, Department of Environmental Engineering, 41380 Kocaeli, Turkey
autor
- University of Kocaeli, Department of Environmental Engineering, 41380 Kocaeli, Turkey
autor
- University of Düzce, Department of Environmental Engineering, 81620 Düzce, Turkey
autor
- University of Kocaeli, Ali Rıza Veziroğlu Vocational School of Higher Education, Department of Environmental Protection, 41080 Kocaeli, Turkey
Bibliografia
- 1. Adesoye, A.M., Olayinka, K., Olukomaiya, O.O., Iwuchukwu, P.O. 2014. The removal of phosphates from laundry wastewater using alum and ferrous sulphate as coagulants. International Journal of Innovation and Scientific Research, 8(2), 256–260.
- 2. Ayad, M.M., El-Nasr, A.A. 2010. Adsorption of cationic dye (methylene blue) from water using polyaniline nanotubes base. Journal of Physical Chemistry C, 114(34), 14377–14383.
- 3. Bering, S., Mazur, J., Tarnowski, K., Janus, M., Mozia, S., Morawski, A.W. 2018. The application of moving bed bio-reactor (MBBR) in commercial laundry wastewater treatment. Science of the Total Environment, 627, 1638–1643.
- 4. Bhaumik, M., McCrindle, R., Maity, A. 2013. Efficient removal of Congo red from aqueous solutions by adsorption onto interconnected polypyrrolepolyaniline nanofibres. Chemical Engineering Journal, 228, 506–515.
- 5. Braga, J.K., Varesche, M.B.A. 2014. Commercial Laundry Water Characterisation. American Journal of Analytical Chemistry, 05(01), 8–16.
- 6. Ciabattia, I., Cesaro, F., Faralli, L., Fatarella, E., Tognotti, F. 2009. Demonstration of a treatment system for purification and reuse of laundry wastewater. Desalination, 245(1–3), 451–459.
- 7. Delforno, T.P., Moura, A.G.L., Okada, D.Y., Sakamoto, I.K., Varesche, M.B.A. 2015. Microbial diversity and the implications of sulfide levels in an anaerobic reactor used to remove an anionic surfactant from laundry wastewater. Bioresource Technology, 192, 37–45.
- 8. Foo, K.Y., Hameed, B.H. 2012a. Mesoporous activated carbon from wood sawdust by K2CO3 activation using microwave heating. Bioresource Technology, 111, 425–432.
- 9. Foo, K.Y., Hameed, B.H. 2012b. Preparation, characterization and evaluation of adsorptive properties of orange peel based activated carbon via microwave induced K2CO3 activation. Bioresource Technology, 104, 679–686.
- 10. Ghorbani, M., Esfandian, H., Taghipour, N., Katal, R. 2010. Application of polyaniline and polypyrrole composites for paper mill wastewater treatment. Desalination, 263(1–3), 279–284.
- 11. Kaleta, J., Elektorowicz, M. 2013. The removal of anionic surfactants from water in coagulation process. Environmental Technology (United Kingdom), 34(8), 999–1005.
- 12. Korzenowski, C., Martins, M.B.O., Bernardes, A.M., Ferreira, J.Z., Duarte, E.C.N.F., de Pinhoa, M.N. 2012. Removal of anionic surfactants by nanofiltration. Desalination and Water Treatment, 44(1–3), 269–275.
- 13. Mohan, S.M. 2014. Use of naturalized coagulants in removing laundry waste surfactant using various unit processes in lab-scale. Journal of Environmental Management, 136, 103–111.
- 14. Nazari, G., Abolghasemi, H., Esmaieli, M. 2016. Batch adsorption of cephalexin antibiotic from aqueous solution by walnut shell-based activated carbon. Journal of the Taiwan Institute of Chemical Engineers, 58, 357–365.
- 15. Pal, A., Pan, S., Saha, S. 2013. Synergistically improved adsorption of anionic surfactant and crystal violet on chitosan hydrogel beads. Chemical Engineering Journal, 217, 426–434.
- 16. Pehlivan, E., Altun, T., Cetin, S., Iqbal Bhanger, M. 2009. Lead sorption by waste biomass of hazelnut and almond shell. Journal of Hazardous Materials, 167(1–3), 1203–1208.
- 17. Schouten, N., van der Ham, L.G.J., Euverink, G.J.W., de Haan, A.B. 2009. Kinetic analysis of anionic surfactant adsorption from aqueous solution onto activated carbon and layered double hydroxide with the zero length column method. Separation and Purification Technology, 68(2), 199–207.
- 18. Terechova, E.L., Zhang, G., Chen, J., Sosnina, N.A., Yang, F. 2014. Combined chemical coagulation-flocculation/ultraviolet photolysis treatment for anionic surfactants in laundry wastewater. Journal of Environmental Chemical Engineering, 2(4), 2111–2119.
- 19. Tripathi, S.K., Tyagi, R., Nandi, B.K. 2013. Removal of Residual Surfactants from Laundry Wastewater: A Review. Journal of Dispersion Science and Technology, 34(11), 1526–1534.
- 20. Tsyntsarski, B., Petrova, B., Budinova, T., Petrov, N., Teodosiev, D.K., Sarbu, A., Sandu, T., Yardim, M.F., Sirkecioglu, A. 2014. Removal of detergents from water by adsorption on activated carbons obtained from various precursors. Desalination and Water Treatment, 52(16–18), 3445–3452.
- 21. Zou, Z., Tang, Y., Jiang, C., Zhang, J. 2015. Efficient adsorption of Cr(VI) on sunflower seed hull derived porous carbon. Journal of Environmental Chemical Engineering, 3(2), 898–905.
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Bibliografia
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bwmeta1.element.baztech-9305beaf-f808-427b-98c1-d7dda356a392