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Purpose: The aim of this work is studying surface topography and optical properties of organic thin films of TiOPc and PTCDA blends deposited by thermal vacuum evaporation. Design/methodology/approach: Thin films of blends of organic materials are provided as donor/acceptor couples in bulk heterojunction based organic solar cells. Thin films of TiOPc - PTCDA mixture have been deposited by thermal vacuum evaporation from one source with various ratios of blends components and deposition rates used. Both the chemical composition and technological parameters of the deposition process have appeared to influence on optical properties, UV-Vis absorption spectra in particular, and surface morphology of the as-prepared thin films. The paper reveals the methodology of deposition thin films of TiPc-PTCDA donor/ acceptor blends and the influence of deposition parameters on their properties. Findings: Thin films of such blends can be used for the research on the planar heterojunction solar cells based on donor-acceptor couple active layers. Results of these investigations suggest that blends of TiOPc and PTCDA can be suitable materials for preparing organic photovoltaic devices. Research limitations/implications: Deposition parameters and proportions of the blend components used determine the properties of TiOPc/PTCDA thin films. Originality/value: The goal of this paper is also to define relations connecting the surface morphology and optical properties of thin films of TiOPc-PTCDA blend prepared with their composition and parameters of the evaporation process.
Wydawca
Rocznik
Tom
Strony
396--402
Opis fizyczny
Bibliogr. 13 poz., rys., tab.
Twórcy
autor
- Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
- Center of Polymer Chemistry, Polish Academy of Sciences, ul. Marii Sklodowskiej Curie 34, 41-819 Zabrze, Poland
autor
- Institute of Engineering Materials and Biomaterials, Silesian University of Technology, ul. Konarskiego 18a, 44-100 Gliwice, Poland
autor
- Center of Polymer Chemistry, Polish Academy of Sciences, ul. Marii Sklodowskiej Curie 34, 41-819 Zabrze, Poland
autor
- Center of Polymer Chemistry, Polish Academy of Sciences, ul. Marii Sklodowskiej Curie 34, 41-819 Zabrze, Poland
Bibliografia
- [1] H. Hoppe, N.S. Sariciftci, Morphology of polymer/fullerene bulk heterojunction solar cells, Journal of Materials Chemistry 16/45 (2006) 45-61.
- [2] B. Hajduk, P. Jarka, J. Weszka, M. Bruma, J. Jurusik, M. Chwastek, D. Mańkowski, Studying of polyoxadiazole with Si atom in the backbone, Archives of Materials Science and Engineering 42/2 (2010) 77-84.
- [3] J. Weszka, M.M. Szindler, M. Chwastek-Ogierman, M. Bruma, P. Jarka, B. Tomiczek, Surface morphology of thin films polyoxadiazoles, Journal of Achievements in Materials and Manufacturing Engineering 49/2 (2011) 224-232.
- [4] J. Weszka, P. Jarka, M. Chwastek-Ogierman, B. Hajduk, Researches of topography and optical properties of the thin films NiPc/PTCDA donor acceptor couple, Journal of Achievements in Materials and Manufacturing Engineering 53/2 (2012) 81-88.
- [5] J. Kalowekamo, E. Baker, Estimating the manufacturing cost of purely organic solar cells, Solar Energy 83 (2009) 1224-1231.
- [6] A. Al-Mohamad, Solar cells based on two organic layers, Energy Conversion and Management 45 (2004) 2661-2665.
- [7] D.K. Susarova, P.A. Troshin, D. Hoglinger, R. Koeppe, S.D. Babenko, R.N. Lyubovskaya, V.F. Razumov, N.S. Sariciftci, Donor-acceptor complex formation in evaporated small molecular organic photovoltaic cell, Solar Energy Materials and Solar Cells 94 (2010) 803-811.
- [8] R. Ye, M. Baba, K. Suzuki, K. Mori, Structure and morphology of CuPc and F16CuPc p-n heterojunction, Applied Surface Science 254 (2008) 7885-7888.
- [9] H. Derouiche, J.C. Berne'de, J. L’Hyver, Optimization of the properties of bulk heterojunctions obtained by coevaporation of Zn-phthalocyanine/perylene, Dyes and Pigments 63 (2004) 277-289.
- [10] A. Pivrikas, M. Ullah, C. Simbrunner, H. Sitter, H. Neugebauer, N. S. Sariciftci, Comparative study of bulk and interface transport in disordered fullerene films, Physical Status Solidi B 248/11 (2011) 2656-2659.
- [11] M. Palewicz, A. Iwan, Poliazometine, properties and applications in photovoltaics, Proceedings of Elektrotechnical Institute 243 (2009) 115-125 (in Polish).
- [12] H. Hoppe, N.S. Sariciftci, Organic solar cells, An overview, Journal of Materials Researches 19/7(2004) 1924-1945.
- [13] J.A. Mikroyannidisa, D.V. Tsagkournosa, S.S. Sharmad, A. Kumard, Y.K. Vijayd, G.D. Sharmab, Efficient bulk heterojunction solar cells based on low band gap bisazo dyes containing anthracene and/or pyrrole units, Solar Energy Materials and Solar Cells 94/12 (2010) 2318-2327.
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Bibliografia
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bwmeta1.element.baztech-92e132e9-8b86-4c9d-8aa7-2985a35f7867