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Leaching of mersin/aydincik dolomite ore in hydrochloric acid. Dissolution rates

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In this paper dissolution of dolomite ore, collected from Mersin/Aydincik in Turkey, was investigated under various experimental conditions in the presence of HCl acid. Particle size, acid/dolomite ratio, solid/liquid ratio, stirring speed, reaction time and temperature were also conducted to the determin the optimum experimental conditions. During the experiment, CO2 amount released from the dolomite was measured through the experimental apparatus to determine reaction orders and rate constants of the sample at the different temperatures by using the fractional life approach method. It was found that, reaction orders and rate constants, based on temperatures, changed from 1.505 to 1.339 and between 3.17 and 10.49 10–2 mol dm–3 sec–1 respectively. In addition, differences in reaction rate constants were examined with the Arrhenius equation and activation energy of the dissolution process was calculated as 16.69 kJ mol–1, which was consistent with the activation energies determined in literature.
Rocznik
Strony
536--550
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
autor
  • Mining Engineering Dept., Faculty of Engineering and Architecture, Cukurova University, Adana, 01330, Turkey
autor
  • Mining Engineering Dept., Faculty of Engineering and Architecture, Cukurova University, Adana, 01330, Turkey
autor
  • Environmental Engineering Dept., Faculty of Engineering and Architecture, Cukurova University, Adana, 01330, Turkey
Bibliografia
  • AKARSU H., 2004, The Research of Obtaining High Purity MgO from Icel-Yavca Dolomite, [Dissertation] (in Turkish), Cukurova University, Adana, Turkey, p. 127.
  • AKARSU H., YILDIRIM M., 2008, Leaching rates of Icel-Yavca dolomite in hydrochloric acid solution, Mineral Processing & Extractive Metall. Rev., 29, 42–56.
  • BABA A.A., OMIPIDAN A.O., ADEKOLA F.A., JOB O., ALABI A.G.F., BARAL A., SAMAL R., 2014, Optimization study of a Nigerian dolomite ore dissolution by hydrochloric acid, J. of Chem. Tech. and Metallurgy, 49, 280–287.
  • BERUTO D.T., VECCHIATTINI R.,GIORDANI M., 2003, Solid products and rate-limiting step in the thermal half decomposition of natural dolomite in a CO2 (g) atmosphere, Thermochim. Acta, 405, 183–194.
  • BUSENBERG E., PLUMMER L.N., 1982, The kinetics of dissolution of dolomite in CO2-H2O systems at 1.5 to 65°C and 0 to 1 atm PCO2, Am. J. Sci. 282, 45–78.
  • CHOU L., GARRELS R.M., WOLLAST R., 1989, Comparative study of the kinetics and mechanisms of dissolution of carbonate minerals, Chem. Geol. 78, 269–282.
  • GALAI H., PIJOLAT M., NAHDI K., TRABELSI-AYADI M., 2007, Mechanism of growth of MgO and CaCO3 during a dolomite partial decomposition, Solid State Ionics, 178, 1039–1047.
  • GAUTELIER M., OELKERS E.H., SCHOTT J., 1999, An experimental study of dolomite dissolution rates as a function of pH from -0.5 to 5 and temperature from 25 to 80 °C, Chemical Geology, 157, 13–26.
  • HASHIMOTO H., KOMAKI E., HAYASHI F., UEMATSU U. 1980, Partial decomposition of dolomite in CO2, J. Solid State Chem., 33, 181–188.
  • HERMAN J.S.,WHITE W.B., 1985, Dissolution kinetics of dolomite: effects of lithology and fluid flow velocity, Geochim. et Cosmochim. Acta, 49, 2017 – 2026.
  • HOSGUN H.L., KURAMA H., 2012, Dissolution kinetics of magnesite waste in HCl solution, Ind. Eng.Chem. Res., 51, 1087–1092.
  • LEVENSPIEL O., 1999, Chemical Reaction Engineering, 3th edition, John Wiley and Sons, Inc., p. 684.
  • LI G., LI Z., MA H., 2013, Synthesis of aragonite by carbonization from dolomite without any additives, Int. J. of Mineral Processing 123, 25–31.
  • LINGLING X., DENG M., 2005, Dolomite used as raw material to produce MgO-based expansive agent, Cement and Concrete Research, 35, 1480–1485.
  • LUND K., FOGLER, H.S., MCCUNE C.C., 1973, Acidization–I. The dissolution of dolomite in hydrochloric acid, Chem. Eng. Sci, 28, 691–700.
  • MATSUMOTO M., FUKUNAGA T., ONOE K., 2010, Polymorph control of calcium carbonate by reactive crystallization using micro bubble technique. Chem. Eng. Res. Des. 88, 1624–1630.
  • OTSUKA K., 1986, Recent studies on the decomposition of the dolomite group by thermal analysis. Thermochim Acta, 100, 69–80.
  • SAMTANI M., DOLLIMORE D., WILBURN F.W., ALEXANDER K., 2001, Isolation and identification of the intermediate and final products in the thermal decomposition of dolomite in an atmosphere of carbon dioxide, Thermochim. Acta, 367–368, 285–295.
  • YILDIRIM M., 2008, Dissolution kinetics of Icel-Aydincik dolomite in hydrochloric acid, S. Afr. J. Chem., 61, 127–132.
  • YU Q., OU H., SONG R., XU, A., 2006, The effect of polyacrylamide on the crystallization of calcium carbonate: Synthesis of aragonite single-crystal nanorods and hollow vaterite hexagons, Journal of Crystal Growth, 286, 178–183.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9253fb0f-9206-4940-8ff9-5b98b8ee59de
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