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Tytuł artykułu

Technology for increasing the precious metals content in copper concentrate obtained by flotation

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
In the established technologies, the use of classic depressants of pyrite, such as lime represents one of the main problems in the flotation of gold-bearing copper (Cu) ores. Lime addition leads to the depression of the noble metals - gold (Au) and silver (Ag) that end up in tailings. Thus, the operator incurs economic losses. The current paper presents research aimed at replacing in flotation of copper pyrite ore, bearing gold and silver, the classical depressor lime with catholyte, i. e. with solution obtained during the electrolysis of water (pure or aqueous solutions) using a diaphragm electrolyser. Data from the conducted research show an increase in the content of precious metals in the obtained copper concentrate - from 148. 04 g/Mg Au and 112. 8 g/Mg Ag achieved by classical process to 216.45 g/Mg Au and 174.03 g/Mg Ag obtained by the proposed treatment. At the same time the Cu recovery increased by 3 % and the grade of Cu concentrate was 27.5 % Cu (compared to 16.2 % in the classical process). It seems that the main parameter influencing the selection separation process is the catholyte pH value.
Rocznik
Strony
art. no. 167424
Opis fizyczny
Bibliogr. 19 poz., rys., wykr.
Twórcy
  • Engineering Unit, Bulgarian Academy of Sciences, 1000, Sofia, Bulgaria
  • Department of Chemistry, University of Mining and Geology, 1700, Sofia, Bulgaria
Bibliografia
  • AGACAYAK, T., YILMAZ, N. B., 2021. The effect of Aerophine 3418A collector dosage on Niğde (Ulukışla-Madenköy) complex Pb-Zn sulphide ore flotation. Acad. Platf. J. Eng. Sci. 9-2, 309-313.
  • AGORHOM, E. A., SKINNER, W., ZANIN M., 2015. Post-regrind selective depression of pyrite in pyritic copper–gold flotation using aeration and diethylenetriamine. Miner. Eng. 72, 36–46.
  • AHMAD, H. S., 1951. Flotation of low-grade gold ores, Thesis presented to the Swiss Federal Institute of Technology of Zurich for the degree of doctoral of technical science. Dissertatlonsdruckerei Leemann AG, Zurich, Switzerland, 75-76.
  • AZIZI, A., MASDARIAN, M., HASSANZADEH, A., BAHRI, Z, NIEDOBA, T., SUROWIAK, A., 2020. Parametric optimization in rougher flotation performance of a sulfidized mixed copper ore. Minerals 10, 660.
  • BOULTON, A., FORNASIERO, D., RALSTON, J., 2001. A comparison of methods to selectively depress iron sulphide flotation. Proceedings of the 4th UBC McGill International Symposium of Fundamentals of Mineral Processing – Interactions in Minerals Processing. Canadian Institute of Mining, Metallurgy and Petroleum Montreal, 141–152.
  • BULATOVIC, S. M., 2007. Handbook of flotation reagents: chemistry, theory and practice: 1 - Flotation of sulphides ores. Elsevier, Amsterdam, Netherlands, 55-56.
  • CHANTURIYA, E. L., 2008. Scientific bases of gold - bearing pyrite recovery from pyrite - bearing waste products of copper-zinc sulfide ores. https://www.researchgate.net/publication/260506577.
  • CHIPAKWE, V., SEMSARI, P., KARLKVIST, T., ROSENKRANZ, J., CHELGANI, S. C., 2020. A critical review on the mechanisms of chemical additives used in grinding and their effects on the downstream processes. J. Mater. Res. Technol., 9, 8148-8162.
  • GLEMBOTSKII, V. A., KLASSEN, V. I., 1981. Flotation methods for beneficiation. Nedra, Moscow, Russia, 270-271 (in Russian).
  • LIU, W., MILLER, J. D., SUN, W., HU, Y., 2022. Analysis of the selective flotation of elemental gold from pyrite using diisobutyl monothiophosphate. Minerals, 12, 1310.
  • MBAYO, J. K., 2020. Improving the gold leaching process of refractory ores and tailings using the jet leach reactor. A dissertation submitted to the faculty of Engineering and the Built Environment, University of Witwatersrand, Johannesburg, in fulfillment of the requirements for the degree of Master of Science in Engineering, Johannesburg, South Africa, 10-11.
  • MEDINA, D., ANDERSON, C. G., 2020. A review of the cyanidation treatment of copper-gold ores and concentrates. Metals, 10, 897.
  • MU, Y., PENG, Y., LAUTEN, R. A., 2016a. The depression of pyrite in selective flotation by different reagent systems - A literature review. Miner. Eng. 96–97, 143–156.
  • MU, Y., PENG, Y., LAUTEN, R. A., 2016b. The depression of copper-activated pyrite in flotation by biopolymers with different compositions. Miner. Eng. 96–97, 113-122.
  • PANAYOTOV, V., PANAYOTOVA, M., 2017. Method for flotation extraction of precious metals in copper concentrate. Bulgarian Patent No 66563 В1 - 2017.
  • PARK, I., HONG, S., JEON, S., ITO, M., HIROYOSHI N., 2020. A review of recent advances in depression techniques for flotation separation of Cu–Mo sulfides in porphyry copper deposits. Metals, 10, 1269.
  • RAMESH, S. L., SUNDER-RAJU, P. V., ANJAIAH, K. V., MATHUR, R., RAO, T. G., DASARAM, B., CHARAN, S. N., SUBBA-RAO, D. V., SARMA, D. S., RAM-MOHAN, M., BALARAM, V., 2001. Determination of gold in rocks, ores, and other geological materials by atomic absorption techniques. Atom. Spectrosc. 22, 250-257.
  • Regulation No. 6 of 9.11.2000 on emission norms for the permissible content of harmful and dangerous substances in waste water discharged into water bodies. State Newspaper No. 97 of 28.11.2000, Sofia (in Bulgarian).
  • SCERESINI, B., 2005. Gold-copper ores. Developments in Mineral Processing Chapter 32. Advances in Gold Ore Processing. Mike D. Adams, B.A. Wills Eds. 15, 789-824.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-92292b22-efe2-42ae-a372-d2ad7b976c57
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