Ozone Degradation of Lignin; its Impact Upon the Subsequent Biodegradation

• Autorzy: Michniewicz M. , Stufka-Olczyk J. , Milczarek A.

Warianty tytułu

PL

Degradacja ligniny w wyniku działania ozonem (AOP) oraz wpływ na późniejszą biodegradację

• Języki publikacji: EN

Abstrakty

EN

The possible use of ozone and advanced oxidation processes (AOP) to degrade and eliminate lignin compounds from aqueous solutions, and the determination of the required ozone dose are the primary objectives of this study. The influence of the oxidation methods on the subsequent biological decomposition of the by-products was also investigated.During ozonisation of the alkalilignin aqueous solutions, the polymer is degraded to a degree depending on the ozone dose. Lignin content decreased by about 40 to 96.6% at an ozone dose of 0.1 and 3.6 mgO3/mgCOD, respectively, accompanied by a drop of COD in the range of 8.8 - 69.6%. An ozone dose of about 1 mgO3/mgCOD is required to reduce the lignin content by more than 80%; at such a dose, the reduction of COD was about 35%. Lignin proved to be a substance that is practically insusceptible to biodegradation under the test conditions. An increase of the susceptibility to biodegradation of the lignin disintegration products could have been observed at an appropriately high dose of ozone.

PL

Celem badań było sprawdzenie możliwości zastosowania ozonu i procesów pogłębionego utleniania (AOP) do degradacji i usunięcia związków ligninowych z roztworów wodnych oraz określenie wymaganej dawki ozonu. Ponadto przeprowadzono badania wpływu pogłębionego utleniania na dalszą biologiczną destrukcję produktów ubocznych rozkładu ligniny. W wyniku ozonowania wodnych roztworów alkaliligniny, polimer ten ulegał degradacji w stopniu zależnym od dawki ozonu. Redukcja zawartości ligniny była w miała zakresie od ok. 40,0 do 96,6%, przy dawce ozonu odpowiednio 0,1 i 3,6 mg O3/mgChZT. Jednocześnie zakres redukcji ChZT była w zakresie wynosił 8,8 – 69,6%. Dawka ozonu potrzebna do otrzymania redukcji ligniny powyżej 80% wynosi ok. 1 mgO3/mgChZT. Przy tej dawce redukcja ChZT wynosiła ok. 35%. Lignina okazała się substancją praktycznie nie podatną na biodegradację w warunkach prowadzenia testów. Przy odpowiednio wysokiej dawce ozonu stwierdzono wzrost podatności na biodegradację produktów rozpadu ligniny.

Słowa kluczowe

EN

degradation; lignin; ozone; advanced oxidation process; biodegradation

PL

degradacja; związki ligninowe; ozon; biodegradacja

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2012
• Tom: Vol. 20, no. 6B (96)
• Strony: 191--196
• Opis fizyczny: Bibliogr. 29 poz., rys., wykr., tab.

Twórcy

autor

Michniewicz M.

• Poland, Łódź, Institute of Biopolymers and Chemical Fibres

autor

Stufka-Olczyk J.

• Poland, Łódź, Institute of Biopolymers and Chemical Fibres

autor

Milczarek A.

• Poland, Łódź, Institute of Biopolymers and Chemical Fibres

Bibliografia

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