Kinetic of Oil Sludge Thermolysis Process in Presence of Nickel, Cobalt and Iron-Supported Microsilicate

• Autorzy: Tyanakh Sairagul , Baikenov Murzabek , Yun Ma Feng , Khamitova Tolkyn , Balpanova Nazerke , Tulebayeva Balzhan , Kyzkenova Aikorkem , Karimova Aliya , Rakhimzhanova N.Z. , Kochegina E.V.

Identyfikatory

DOI

10.2478/pjct-2023-0030

• Języki publikacji: EN

Abstrakty

EN

The article is devoted to the experimental determination of thermokinetic parameters of oil sludge thermal degradation using the model-free Ozawa-Flynn-Wall method in the presence of a nanocatalyst (nickel, cobalt and iron-supported microsilicate) by calculating Arrhenius kinetic parameters (activation energy and pre-exponential factor). The phase composition of the reflex microsilicate was established – 4.12; 2.51 Å – SiO₂, nickel-supported microsilicate reflexes: 2.09; 1.48 Å – NiO, reflexes: 4.25 Å – SiO₂ and acid numbers of microsilicate – 64 μmol/g of prepared nanocatalysts. Using the method of Brunauer, Emmett and Teller, the specific surface area of the microsilicate was established – 18.3 ± 0.3 m² /g, the microsilicate with nickel applied – 20.9 ± 0.2 m² /g and the adsorption isotherm of the prepared nanocatalysts (microsilicate with nickel, cobalt and iron). Thermokinetic parameters of thermal decomposition of oil sludge without a catalyst and with a catalyst at an increment of 0.9 are 99.0 and 93.3 kJ/mol nickel-supported microsilicate, 51.9 kJ/mol cobalt-supported microsilicate, 111.3 kJ/mol iron-supported microsilicate and non-metal-supported microsilicate 173.7 kJ/mol, respectively. The study of the kinetic parameters of pyrolysis of oil sludge using various catalysts makes it possible to assess their influence on the process of decomposition of organic components. The results of the experiments showed that the use of catalysts significantly affects the destruction of oil sludge. Dynamic thermal analysis at different heating rates studied the dynamics of oil sludge decomposition. The study of the effect of catalysts on the kinetic parameters of oil sludge pyrolysis is an important step in the development of new methods for the disposal of petroleum products and the reduction of their negative impact on the environment. The obtained experimental data on thermal degradation kinetics of oil sludge will find application in designing a reactor for the process of destructive hydrogenation of heavy hydrocarbon raw materials.

Słowa kluczowe

EN

thermokinetic parameters; thermogravimetry; kinetics; nanocatalyst; microsilicate; oil sludge; iron; nickel; cobalt

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2023
• Tom: Vol. 25, nr 3
• Strony: 101--109
• Opis fizyczny: Bibliogr. 21 poz., rys., tab., wz.

Twórcy

autor

Tyanakh Sairagul

• Karaganda Buketov University, Faculty of Chemistry, Department of Chemical Technologies and petrochemicals, Karaganda 100024, Kazakhstan

autor

Baikenov Murzabek

• Karaganda Buketov University, Faculty of Chemistry, Department of Chemical Technologies and petrochemicals, Karaganda 100024, Kazakhstan

autor

Yun Ma Feng

• Xinjiang University, Urumqi, XUAR, 830046,People’s Republic of China

autor

Khamitova Tolkyn

• Kazakh Agro Technical University Named after Saken Seifullin, Agronomic Faculty, The Department of Soil Science and Agrochemisrty, Astana 010000, Kazakhstan

autor

Balpanova Nazerke

• Karaganda Buketov University, Faculty of Chemistry, Department of Chemical Technologies and petrochemicals, Karaganda 100024, Kazakhstan

autor

Tulebayeva Balzhan

• Baitursynov Kostanay Regional University, Kostanay 110000, Kazakhstan

autor

Kyzkenova Aikorkem

• Karaganda Medical University, Karaganda, 100012, Kazakhstan

autor

Karimova Aliya

• Karaganda Buketov University, Faculty of Chemistry, Department of Chemical Technologies and petrochemicals, Karaganda 100024, Kazakhstan

autor

Rakhimzhanova N.Z.

• Karaganda Buketov University, Faculty of Chemistry, Department of Chemical Technologies and petrochemicals, Karaganda 100024, Kazakhstan

autor

Kochegina E.V.

• Karaganda Buketov University, Faculty of Chemistry, Department of Chemical Technologies and petrochemicals, Karaganda 100024, Kazakhstan

Bibliografia

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).