Decomposition of Azo Dye C.I. Direct Yellow 86 by the Fenton Process in the Presence of Nanoparticles of Iron Oxides

• Autorzy: Kos L , Sójka-Ledakowicz J , Michalska K , Perkowski J

Warianty tytułu

PL

Rozkład barwnika azowego C.I. Direct Yellow 86 w procesie Fentona w obecności nanocząstek tlenków żelaza

• Języki publikacji: EN

Abstrakty

EN

The aim of the study was to determine the efficiency of decomposition of azo dye C.I. Direct Yellow 86 by the Fenton method in the presence of nanoparticles of iron oxides and to compare it with the classical Fenton method. Water solutions of the dye were subjected to the classical purification method with the application of ferrous sulfate and – for comparison – to a process in which iron (II,III) oxide nanopowder was added to the ferrous sulfate. Analysis of the effect of the ferrous sulfate, iron (II,III) oxide nanopowder, hydrogen peroxide and the pH of the solution on the treatment efficiency showed that the process was optimised. The use of iron oxide nanopowder increased the efficiency of dye decomposition.

PL

Celem badań było określenie efektywności rozkładu barwnika azowego C.I. Direct Yellow 86 metodą Fentona przy udziale nanocząstek tlenków żelaza i porównanie jej z efktywnością klasycznej metody Fentona. Roztwory wodne barwnika oczyszczano metodą klasyczną stosując siarczan żelazawy oraz metodą zmodyfikowaną stosując siarczan żelazawy z dodatkiem nanocząstek tlenków żelaza (II,III). Dokonano optymalizacji procesu oczyszczania badając wpływ dawek siarczanu żelazawego i nanocząstek tlenków żelaza (II,III), dawki nadtlenku wodoru oraz pH roztworu na efektywność obróbki. Zastosowanie dodatku nanocząstek tlenków żelaza w zmodyfikowanym procesie klasycznym przebiegającym z udziałem siarczanu żelazawego zwiększało wydajność rozkładu barwnika.

Słowa kluczowe

EN

azo dye; Fenton reaction; nanoparticles; iron oxides; dye decomposition

PL

rozkład barwnika azowego; reakcja Fentona; nanocząstki; tlenki żelaza; rozkład barwnika

• Wydawca: Sieć Badawcza Łukasiewicz - Łódzki Instytut Technologiczny
• Czasopismo: Fibres & Textiles in Eastern Europe
• Rocznik: 2014
• Tom: Vol. 22, no. 5 (107)
• Strony: 114--120
• Opis fizyczny: Bibliogr. 20 poz., rys., tab.

Twórcy

autor

Kos L

• Poland, Łódź, Textile Research Institute

autor

Sójka-Ledakowicz J

• Poland, Łódź, Textile Research Institute

autor

Michalska K

• Poland, Łódź, Textile Research Institute

autor

Perkowski J

• Poland, Łódź, Lodz University of Technology, Institute of Applied Radiation Chemistry 15, 92-103 Łódź, Poland,

Bibliografia

• 1. Wei J, Song Y, Tu X, Zhao L, Zhi E. Pretreatment of dry-spun acrylic fiber manufacturing wastewater by Fenton process: Optimization, kinetics and mechanisms. Chemical Engineering Journal 2013; 218: 319-326.
• 2. Blanco J, Torrades F, De la Varga M, García-Montaño J. Fenton and biological-Fenton coupled processes for textile wastewater treatment and reuse. Desalination 2012; 286: 394-399.
• 3. Fu F, Wang Q, Tang B. Effective degradation of C.I. Acid Red 73 by advanced Fenton process. Journal of Hazardous Materials 2010; 174, 1–3: 17-22.
• 4. Modirshahla N, Behnajady M, Ghanbary F. Decolourisation and Mineralization of C.I.Acid Red 23 by Fenton and Photo- Fenton Processes. Dyes and Pigments 2007; 73: 305-310.
• 5. Papic S, Vujevic D, Koprivanac N, Sinko D. Decolourization and mineralization of commercial reactive dyes by using homogeneous and heterogeneous Fenton and UV/Fenton processes. Journal of Hazardous Materials 2009; 164: 1137-1145.
• 6. Perkowski J, Kos L. Treatment of textile dyeing wastewater by hydrogen peroxide and ferrous ions. Fibres & Textiles in Eastern Europe 2002; 38: 78-81.
• 7. Bach A, Zach-Maor A, Semiat R. Characterization of iron oxide nanocatalyst in mineralization processes. Desalination 2010; 262, 1-3: 15-20.
• 8. Zelmanov G, Semiat R. Iron (2,3) oxides based nano-particles as catalysts in advanced organic aqueous oxidation. Desalination and Water Treatment 2009; 6, 1-3: 190-191.
• 9. Rusevova K, Kopinke F, Georgi A. Nano-sized magnetic iron oxides as catalysts for heterogeneous Fenton-like reactions – Influence of Fe(II)/Fe(III) ratio on catalytic performance. Journal of Hazardous Materials 2012; 241/242: 433-440.
• 10. Choi K, Lee W. Enhanced degradation of trichloroethylene in nano-scale zerovalent iron Fenton system with Cu(II). Journal of Hazardous Materials 2012; 211-212: 146-153.
• 11. Zhang J, Zhuang J, Gao L, Zhang Y, Gu N, Feng J, Yang D, Zhu J, Yan X. Decomposition of phenol by the hidden valent of ferromagnetic nanoparticles. Chemosphere 2008; 73: 1524-1528.
• 12. Ursachi I, Stancu A, Vasile A. Magnetic α-Fe 2O3/MCM-41 nanocomposites: Preparation, characterization, and catalytic activity for methylene blue degradation. Journal of Colloid and Interface Science 2012; 377, 1: 184-190.
• 13. Zhong X, Xiang L, Royer S, Valange S, Barrault J, Zhang H. Degradation of C.I. Acid Orange 7 by heterogeneous Fenton oxidation in combination with ultrasonic irradiation. Journal of Chemical Technology and Biotechnology 2011; 86, 7: 970-977.
• 14. Xu H, Wang J-X, Wang J-F. Preparation of nano-ZnO using solid state reaction and photocatalytic degradation kinetics of reactive black 5, Gongneng Cailiao. Journal of Functional Materials 2010; 41, 4: 616-619, 622.
• 15. Chen J, Qiu X, Fang Z, Yang M, Pokeung T, Gu F, Cheng W, Lan B. Removal mechanism of antibiotic metronidazole from aquatic solutions by using nanoscale zero-valent iron particles. Chemical Engineering Journal 2012; 181/182: 113-119.
• 16. Khataee A, Zarei M. Photoelectrocatalytic decolorization of diazo dye by zinc oxide nanophotocatalyst and carbon nanotube based cathode. In: Determination of the degradation products. Desalination 2011; 278: 117-125.
• 17. Liang X, Zhong Y, He H, Yuan P, Zhu J, Zhu S, Jiang Z. The application of chromium substituted magnetite as heterogeneous Fenton catalyst for the degradation of aqueous cationic and anionic dyes. Chemical Engineering Journal 2012; 191: 177-184.
• 18. Tian SH, Tu YT, Chen DS, Chen X, Xiong Y. Degradation of Acid Orange II at neutral pH using Fe2(MoO4)3 as a heterogeneous Fenton-like catalyst. Chemical Engineering Journal 2011; 69, 1–3: 31-37.
• 19. Kos L, Michalska K, Żyłła R, Perkowski J. Effect of acetic acid on pollutant decomposition in textile wastewater treated by Fenton method. Environment Protection Engineering 2012; 38: 29-39.
• 20. Nowicki L, Godala M. Hydrogen peroxide and Fenton reaction. In: Advanced techniques of oxidation in environment protection. Ed. Polish Academy of Science, Branch in Łódź, 2002, pp. 81- 102.