Synthesis, growth and characterization of organic crystal triphenylmethane p-nitroaniline: a nonlinear optical crystal

• Autorzy: Bhuvaneswari G. , Prasad L. G. , Prabhavathi N.

Identyfikatory

DOI

10.1515/msp-2017-0068

• Języki publikacji: EN

Abstrakty

EN

A triphenylmethane-4-nitroaniline salt has been synthesized and the crystals have been grown by using slow evaporation solution growth technique. The grown single crystal was investigated by recording the powder XRD, FT-IR spectrum, UV-Vis spectrum, Vickers microhardness test, dielectric measurements and powder SHG. The growth of crystal was confirmed by analyzing the XRD pattern and it was stated that the grown material crystallized in triclinic system. Vibrational peaks of the functional groups existing in the compound were identified. Vickers microhardness studies were carried to measure the mechanical strength. In order to identify the phase transition temperature, the dielectric studies were carried out at different temperatures. Dielectric constant, dielectric loss and impedance of the crystal were monitored with respect to the frequency of electric field.

Słowa kluczowe

EN

crystal growth; UV-Vis spectroscopy; FT-IR; XRD; dielectric studies; non-linear optical material

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2017
• Tom: Vol. 35, No. 3
• Strony: 667--672
• Opis fizyczny: Bibliogr. 22 poz., rys., tab.

Twórcy

autor

Bhuvaneswari G.

• Department of Physics, Muthayammal College of Arts and Science, Rasipuram, India
• Department of Physics, Sri Sarada College for Women, Salem - 636 016, India

autor

Prasad L. G.

• Department of Science & Humanities, M. Kumaraswamy College of Engineering, Karur, India

autor

Prabhavathi N.

• Department of Physics, Sri Sarada College for Women, Salem - 636 016, India

Bibliografia

• [1] CHEMLA D.S., ZYSS J., Nonlinear optical properties of organic molecules and crystals, Academic Press, New York, 1987.
• [2] PRASAD P.N., WILLIAMS D.J., Introduction to nonlinear optical effects in organic molecules and polymers, Wiley, New York, 1991.
• [3] HARI SINGH NALWA, SEIZO MIYATA, Nonlinear optics of organic molecules and polymers, CRC Press, Boca Raton, 1997.
• [4] MOHAN J., Organic Spectroscopy, principles and applications, Alpha Science International Ltd, Harrow, 2004.
• [5] KEMP W., Organic spectroscopy, Palgrave Macmillan New York, 1993.
• [6] KALSI P., Spectroscopy of organic compounds, Willey Eastern, New Delhi, 1985.
• [7] DANI V.R., Organic spectroscopy, Tata Mc Graw Hill, New Delhi, 1995.
• [8] BARZOUKAS M., JOSSE D., FREMAUX P., ZYSS J., NICOUD F., MORLEY J.O., J Opt. Soc. Am. B., 4 (1987), 977.
• [9] http://www.chemicalbook.com/ChemicalProductProperty_EN_CB5689132.htm.
• [10] MEJEBA M.X., DEVARAJAN P.A., In. J. Eng. Res. Tech., 4 (2015), 952.
• [11] PRASAD G.L., KRISHNAKUMAR V., NAGALAKSHMI R., Spectrochim. Acta A, 110 (2013), 377.
• [12] BOOPATHI K., RAMASAMY P., Optik, 126 (2015), 2125.
• [13] MARDER S.R., KIPPELEN B., JEN A.K.Y., PEYGHAMBARIAN N., Nature, 388 (1997), 845
• [14] KATZ H.E., SINGER K.D., SOHN J.E., DIRK C.W., KING L.A., GORDEN H.M., J. Am. Chem. Soc., 109 (1987), 6561.
• [15] BRESLOW R., CHU W., J. Am. Chem. Soc., 92 (1969), 2165.
• [16] JAGADEESH M.R., SURESH KUMAR H.M., ANANDA KUMAR R., Mater. Sci.-Poland, 33 (2015) 529.
• [17] RENFROW JR. W.B., HAUSER C.R., Org. Synth. Coll., 2 (1943), 607.
• [18] NORRIS J.F., Org. Synth. Coll., 1 (1941), 548.
• [19] SANGWAL K., Mater. Chem. Phys., 63 (2000), 145.
• [20] IKEDA H., SAKAI T., KAWASAKI K., Chem. Phys. Lett, 179 (1991), 551.
• [21] DMITRIEV V.G., GURZADYAN G.G., NIKOGOSYAN D.N., Nonlinear Optical Crystals, Springer, Berlin 1991.
• [22] KURTZ S.K., PERRY T.T., J. Appl. Phys., 39 (1968), 39.