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Jarosite residues, which are generated in a zinc production plant by a hydrometallurgical process, contain a large amount of valuable metal components. In this study, a method was proposed for the recovery of lead, zinc and iron from the residues and simultaneous sulfur fixation through direct reduction followed by magnetic separation. The influences of the roasting temperature, roasting time and the concentration of SO2 gas in the direct reduction process were researched in detail. Results showed that the volatilization rates of lead, zinc and sulfur were 96.97%, 99.89% and 1.09%, respectively, and the iron metallization rate was 91.97% under optimal reduction conditions; roasting temperature 1523 K for 60 min. The magnetic concentrate with the iron content of 90.59% and recovery rate of 50.87% was obtained from the optimal reduction product by grinding and magnetic separation. The optimum fineness for separation 96.56% less than 37 μm accounted with magnetic field strength 24 kA/m. The theoretical analysis was carried out by thermodynamics, X-ray powder diffraction, gas analysis and scanning electron microscopy.
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Tom
Strony
517--526
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
- School of Civil and Resource Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing, 100083 China
autor
- School of Civil and Resource Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing, 100083 China
- yanghf@ustb.edu.cn
autor
- School of Civil and Resource Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing, 100083 China
autor
- School of Civil and Resource Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing, 100083 China
autor
- School of Civil and Resource Engineering, University of Science and Technology Beijing, 30 Xueyuan Road, Haidian District, Beijing, 100083 China
Bibliografia
- ASOKAN, P., SAXENA, M., ASOLEKAR, S., 2010. Recycling hazardous jarosite waste using coal combustion residues Materials Characterization. 61, 1342-1355.
- ASOKAN, P., SAXENA, M., ASOLEKAR, S.R., 2006. Hazardous jarosite use in developing non-hazardous product for engineering application.Journal of hazardous materials. 137, 1589-1599.
- CALLA-CHOQUE, D., NAVA-ALONSO, F., FUENTES-ACEITUNO, J., 2016. Acid decomposition and thiourea leaching of silver from hazardous jarosite residues: Effect of some cations on the stability of the thiourea system.Journal of Hazardous Materials. 317, 440-448.
- CHEN, Y., TANG, M., YANG, S., HE, J., TANG, C., YANG, J., LU, J., 2009. Novel technique of decomposition of ammonium jarosite bearing indium in NaOH medium. The Chinese Journal of Nonferrous Metals. 7, 028.
- ERDEM, M., ÖZVERDI, A., 2011. Environmental risk assessment and stabilization/solidification of zinc extraction residue: II. Stabilization/solidification.Hydrometallurgy. 105, 270-276.
- FROST, R.L., WILLS, R.-A., KLOPROGGE, J.T., MARTENS, W., 2006. Thermal decomposition of ammonium jarosite (NH4)Fe3(SO4)2(OH)6.Journal of Thermal Analysis and Calorimetry. 84, 489-496.
- GANG, Y., NING, P., LAN, Z., LIANG, Y.J., ZHOU, X.Y., BING, P., CHAI, L.Y., YANG, Z.H., 2015. Selective reduction process of zinc ferrite and its application in treatment of zinc leaching residues.Transactions of Nonferrous Metals Society of China. 25, 2744-2752.
- GUO, D., HU, M., PU,C., XIAO, B., HU, Z., LIU, S., WANG, X., ZHU, X., 2015. Kinetics and mechanisms of direct reduction of iron ore-biomass composite pellets with hydrogen gas.International Journal of Hydrogen Energy. 40, 4733-4740.
- HAN, H., SUN, W., HU, Y., JIA, B., TANG,H., 2014. Anglesite and silver recovery from jarosite residues through roasting and sulfidization-flotation in zinc hydrometallurgy.Journal of hazardous materials. 278, 49-54.
- HU, H., DENG, Q., LI, C., XIE, Y., DONG,Z., ZHANG, W., 2014. The recovery of Zn and Pb and the manufacture of lightweight bricks from zinc smelting slag and clay.Journal of hazardous materials. 271, 220-227.
- JU, S., ZHANG, Y., ZHANG, Y., XUE, P., WANG, Y., 2011. Clean hydrometallurgical route to recover zinc, silver, lead, copper, cadmium and iron from hazardous jarosite residues produced during zinc hydrometallurgy.Journal of hazardous materials. 192, 554-558.
- KEROLLI-MUSTAFA, M.,MANDIĆ, V., ĆURKOVIĆ, L., ŠIPUŠIĆ,J., 2016. Investigation of thermal decomposition of jarosite tailing waste.Journal of Thermal Analysis and Calorimetry. 123, 421-430.
- LIU, W., YANG, J., XIAO, B., 2009. Application of Bayer red mud for iron recovery and building material production from alumosilicate residues.Journal of hazardous materials. 161, 474-478.
- LIU, Z.G., SUN, T.C., WANG, X.P., GAO, E.X., 2015. Generation process of FeS and its inhibition mechanism on iron mineral reduction in selective direct reduction of laterite nickel ore.International Journal of Minerals, Metallurgy, and Materials. 22, 901-906.
- MALENGA, E.N., MULABA-BAFUBIANDI, A., NHETA, W., 2015. Alkaline leaching of nickel bearing ammonium jarosite precipitate using KOH, NaOH and NH4OH in the presence of EDTA and Na2S. Hydrometallurgy. 155, 69-78.
- MAWEJA, K., MUKONGO,T., MUTOMBO, I., 2009. Cleaning of a copper matte smelting slag from a water-jacket furnace by direct reduction of heavy metals. Journal of Hazardous Materials. 164, 856-862.
- MONTANARO, L., BIANCHINI, N., RINCON, J.M., ROMERO, M., 2001. Sintering behaviour of pressed red mud wastes from zinc hydrometallurgy. Ceramics international. 27, 29-37.
- ÖZVERDİ, A., ERDEM, M., 2010. Environmental risk assessment and stabilization/solidification of zinc extraction residue: I. Environmental risk assessment.Hydrometallurgy. 100, 103-109.
- PAPPU, A., SAXENA, M., ASOLEKAR, S.R., 2006. Jarosite characteristics and its utilisation potentials.Science of the total environment. 359, 232-243.
- PARK, J.W., AHN, J.C., SONG, H., PARK, K., SHIN, H., AHN, J.S., 2002. Reduction characteristics of oily hot rolling mill sludge by direct reduced iron method.Resources, conservation and recycling. 34, 129-140.
- SUN, Y., HAN, Y., GAO, P., YU, J., 2015. Size distribution behavior of metallic iron particles in coal-based reduction products of an oolitic iron ore.Mineral Processing and Extractive Metallurgy Review. 36, 249-257.
- YANG, H., JING, L., ZHANG, B., 2011. Recovery of iron from vanadium tailings with coal-based direct reduction followed by magnetic separation.Journal of hazardous materials. 185, 1405-1411.
- YU, W., SUN, T., CUI, Q., XU, C., KOU, J., 2015.Effect of Coal Type on the Reduction and Magnetic Separation of a High-phosphorus Oolitic Hematite Ore.ISIJ International. 55, 536-543.
Uwagi
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-9092f642-7ea9-4e43-81fe-e1ac9dd7b5ae