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In this study, a binary fluidised bed made out of quartz sand and cenospheres for the biomass combustion process was created. Materials were fluidised with air to achieve a vertical density profile (from 0.5 g/cm³ to 1.1 g/cm³) resulting from grains segregation. The density profile was selected to ensure optimal control over the location of the combusted fuel particle. This involved positioning the process as close to the bottom sieve as possible. Fluidised bed combustion was carried out at temperatures of 600 °C, 700 °C, 820 °C and 870 °C using straw, willow and sawmill pellets as fuels. Qualitative and quantitative analysis of flue gases was performed using an FTIR spectrometer. Over 90 % carbon conversion from the biomass to carbon dioxide was achieved at 700 °C. At 820 °C and 870 °C, 100 % of biomass carbon left the reactor as CO2. The composition of organic compounds in the process products remained low, reaching a maximum of 3.0 % wt. at 600 °C. To gain further insights into the processes occurring in the immediate vicinity of biomass samples, a complementary TGA/FTIR analysis was conducted. This aimed to clarify the impact of the biomass particle decomposition stage in the fluidised bed combustion process. The proposed mechanism for biomass combustion in the binary fluidised bed contains the particle decomposition stage and the subsequent stage resulting from the coalescence of bubbles containing flammable components and bubbles containing oxidiser.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
353--363
Opis fizyczny
Bibliogr. 20 poz., rys., wykr.
Twórcy
autor
- The Doctoral School of Cracow University of Technology
- Department of Chemical Engineering and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155 Kraków, Poland
autor
- Department of Chemical Engineering and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155 Kraków, Poland
autor
- Department of Chemical Engineering and Technology, Cracow University of Technology, ul. Warszawska 24, 31-155 Kraków, Poland
Bibliografia
- [1] Rodziewicz T, Teneta J, Zaremba A, Wacławek M. Analysis of solar energy resources in southern poland for photovoltaic applications. Ecol Chem Eng S. 2013;20:177-98. DOI: 10.2478/eces-2013-0014.
- [2] Chmiel S, Hałas S, Pieńkos T, Głowacki S, Maciejewska E, Polkowska Z, et al. CO2 emission to the atmosphere from carbonate waters: The study case of the Lublin Upland and Roztocze regions. Ecol Chem Eng S. 2015;22:499-511. DOI: 10.1515/eces-2015-0029.
- [3] Głąb T, Jarosz R, Gondek K, Mierzwa-Hersztek M. Maize root architecture and biomass productivity after application of organic and inorganic additives in contaminated soil. Ecol Chem Eng S 2024;31:75-87. DOI: 10.2478/eces-2024-0006
- [4] Pieratti E, Antolini D, Baggio P, Negri M. Wood Combustion Process: Characterization of Gaseous Emissions of Different Parts of a Spruce Tree By Means of a Gasifying Wood Stove. 3rd Int Symp Energy Biomass Waste 2010 - Book Abstracts Proceedings Venice 2010. Available from: https://www.researchgate.net/publication/266026029.
- [5] Paris E, Carnevale M, Vincenti B, Palma A, Guerriero E, Borello D, et al. Evaluation of VOCs emitted from biomass combustion in a small CHP plant: Difference between dry and wet poplar woodchips. Molecules. 2022;27. DOI: 10.3390/molecules27030955.
- [6] Berkowicz-Płatek G, Leski K, Żukowski W, Wrona J. Processing of low-density waste in fluidized bed made out of lightweight expanded clay aggregate. J Clean Prod. 2022;349. DOI: 10.1016/j.jclepro.2022.131328.
- [7] Cheng S, Zhou Y, Wong KH, Lai NYG, Han Z. Combustion reactivity of chars pyrolyzed from low-rank coal using a fixed bed reactor installed with internals. J Environ Chem Eng. 2023;11:109105. DOI: 10.1016/J.JECE.2022.109105.
- [8] Alghamdi YA, Peng Z, Almutairi Z, Alibrahim H, Al-Alweet FM, Moghtaderi B, et al. Assessment of correlations for minimum fluidization velocity of binary mixtures of particles in gas fluidized beds. Powder Technol. 2021;394:1231-9. DOI: 10.1016/J.POWTEC.2021.09.035.
- [9] Zou Z, Shao G, Ge Y, Wang S, Xie Z, Zhu Q, et al. From laboratory research to industrial application: a green technology of fluidized mineral processing for manganese dioxide ore reduction. Green Chem Eng. 2020;1:40-7. DOI: 10.1016/j.gce.2020.09.015.
- [10] Leckner B, Lind F. Combustion of municipal solid waste in fluidized bed or on grate - A comparison. Waste Manage. 2020;109:94-108. DOI: 10.1016/j.wasman.2020.04.050.
- [11] Escudero D, Heindel TJ. Bed height and material density effects on fluidized bed hydrodynamics. Chem Eng Sci. 2011;66:3648-55. DOI: 10.1016/j.ces.2011.04.036.
- [12] Vodička M, Michaliková K, Hrdlička J, Hofbauer C, Winter F, Skopec P, et al. External bed materials for the oxy-fuel combustion of biomass in a bubbling fluidized bed. J Clean Prod. 2021;321:128882. DOI: 10.1016/j.jclepro.2021.128882.
- [13] Chirone R, Salatino P, Scala F, Solimene R, Urciuolo M. Fluidized bed combustion of pelletized biomass and waste-derived fuels. Combust Flame. 2008;155:21-36. DOI: 10.1016/j.combustflame.2008.05.013.
- [14] Atimtay AT. Combustion of agro-waste with coal in a fluidized bed. Clean Technol Environ Policy. 2010;12:43-52. DOI: 10.1007/s10098-009-0220-9.
- [15] Peters J, May J, Ströhle J, Epple B. Flexibility of CFB combustion: An investigation of co-combustion with biomass and RDF at part load in pilot scale. Energies. 2020;13. DOI: 10.3390/en13184665.
- [16] Liu Q, Zhong W, Yu A, Wang CH. Co-firing of coal and biomass under pressurized oxy-fuel combustion mode in a 10 kWth fluidized bed: Nitrogen and sulfur pollutants. Chem Eng J. 2022;450:138401. DOI: 10.1016/J.CEJ.2022.138401.
- [17] Morris JD, Daood SS, Nimmo W. Agglomeration and the effect of process conditions on fluidized bed combustion of biomasses with olivine and silica sand as bed materials: Pilot-scale investigation. Biomass Bioenergy. 2020;142:105806. DOI: 10.1016/J.BIOMBIOE.2020.105806.
- [18] Żukowski W, Berkowicz G. The combustion of polyolefins in inert and catalytic fluidised beds. J Clean Prod. 2019;236. DOI: 10.1016/j.jclepro.2019.117663.
- [19] Chirone R, Poletto M, Barletta D, Lettieri P. The effect of temperature on the minimum fluidization conditions of industrial cohesive particles. Powder Technol. 2020;362:307-22. DOI: 10.1016/j.powtec.2019.11.102.
- [20] Dziubiński M, Prywer J. Mechanika płynów dwufazowych (Two-phase flow mechanics). Warszawa: Wydawnictwo Naukowe PWN; 2022. ISBN: 9788301199432.
Typ dokumentu
Bibliografia
Identyfikator YADDA
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