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Badania aktywności katalizatorów opartych o tlenki Ni, Co oraz Ce w procesie w produkcji wodoru na drodze parowego reformingu etanolu (ESR)

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Warianty tytułu
EN
The investigation of activity the bimetallic catalysts based on nicel oxide, cobalt oxide, cerium oxide in ethanol steam reforming (ESR)
Języki publikacji
PL
Abstrakty
PL
Przeprowadzono badania aktywności katalizatorów: Ni, Co, Ce osadzonych na Al203 do produkcji wodoru, na drodze parowego reformingu etanolu w zakresie temperatur 413-823 K. Katalizatory wytworzono metodą cytrynianową. Najlepszym spośród badanych katalizatorów okazał się katalizator niklowy, dla którego w 823 K selektywność w kierunku wodoru wynosi 79% przy wydajności wodoru 8531·h-l·kgkat-l.
EN
The studies of non-noble catalyst usage in a hydrogen production in the ethanol steam reforming process were performed. Nil Ah03, CoIAhO} and Cel Al203 were investigated in the temperature rage 413-823 K. The best Ni/Al203 catalyst achieved the highest hydrogen yield (above 850 l'h-I'kgkat-I) and H2 selectivity (about 80%) at 823 K.
Rocznik
Tom
Strony
99--117
Opis fizyczny
Bibliogr. 37 poz., rys., tab.
Twórcy
Bibliografia
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  • [27] Sun J, Qiu X., Wu F., Zhu W., Wang W., Hao S., 2004. Hydrogen from steam reforming of ethanol in low and middle temperature range for fuel celI application. Int. l Hydrogen Energ., 29, 1075-1081. DOI: 10.1016/j.ijhydene.2003.11.004.
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  • [30] Kwak B.S., Lee G., Park S.-M., Kang M., 2015. Effect of MnOx in the catalytic stabilization of C02Mn04 spinel during the ethanol steam reforming reaction. Appl. Catal. A: Gen., 503, 165-175. DOI: 10.10 I 6/j.apcata.20 15.06.037.
  • [31] Haga F., Nakajima T., Miya H., Mishima S., 1997. Catalytic properties of supported cobalt catalysts for steam reforming of ethanoJ. Cata!. Lett., 48, 223-227. DOl: 10.1 023/A: 101903940.
  • [32] Batista M.S., Santos R.K.S., Assaf E.M., Assaf J.M., Ticianelli E.A., 2004. High efficiency steam reforming of ethanol by cobalt-based catalysts. 1. Power Sources 134, 27-32. DOI: : 1 0.10 16/j .jpowsour.2004.0 1.052.
  • [33] Garcia S.R., Assaf J.M., 2012. Effect of the Preparation Method on Col Al203 Catalyst Applied to Ethanol Steam Reforming Reaction Production of Hydrogen. Modern Research Catal., l, 52-57. DOI: 10.4236/rnrc.2012.13007.
  • [34] Sahoo D.R., Vajpai S., Patel S., Pant K.K.,2007. Kinetic modeling ofsteam reforming ofethanol for the production of hydrogen over CoIAI203 catalyst. Che m. Eng. J., 125, 139-147. DOI: 10.1016/j.cej.2006.08.01l.
  • [35] Cavallaro S, Mondello N, Freni S., 200l. Hydrogen produced from ethanol for internal reforming molten carbonate fuel cell. J Power Sources, I 02: 198-204.
  • [36] de Lima S.M., Silva A.M., Graham U.M., Jacobs G., Davis B.H., Mattos L.V., Noronha F.B., 2009. Ethanol decomposition and steam reforming of ethanol over CeZr02 and Pt/CeZr02 catalyst: Reaction mechanism and deactivation. Appl. Catal. A: Gen., 352, 95-113. DOI: 10.1016/j.apcata.2008.09.040.
  • [37] Pinton N., Vidal M.V., Signoretto M., Martinez-Arias A., Cortćs Corberan V., 2017. Ethanol steam reforming on nanostructured catalysts of Ni, Co and Ce02: Influence of synthesis method on activity, deactivation and regenerability. Catal. Today, 296, 135-143. DOI: 10.10 16/j.cattod.20 17.06.022
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8f0e7fc6-9a7f-43a9-84e3-ac8a3d3f7db8
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