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Polymeric building materials and equipment for indoor use in spaces intended for people may, in an essential way, contribute to the deterioration of wholesome quality of life. Phthalates, present in many products, constitute an omnipresent group of compounds used widely as plasticisers. The research results show that these substances may negatively impact human health, and thus European Union has implemented several regulatory measures restricting their use. Manufacturers and suppliers must comply with these regulations. As a result, it is necessary to investigate and determine the contents of phthalates in these materials. This paper presents the analytic profile of the method of marking phthalates extracted from polyvinyl chloride using HPLC chromatography with UV-VIS detection and selected results obtained in examinations of materials used in interior design. The results of described examinations of phthalates content indicate that not all materials recommended by manufacturers may be used indoors in spaces intended for people. The method was verified for its suitability for routine analyses of materials made of PVC and submitted for attestation. The elaborated method can be used to determine the banned phthalates’ presence in PVC. The method allows for detecting these phthalates at the level required by the REACH regulation, and its validation parameters are highly satisfactory considering a very complex matrix.
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Tom
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190--201
Opis fizyczny
Bibliogr. 20 poz., rys., tab.
Twórcy
autor
- National Institute of Public Health NIH – National Research Institute, Poland
autor
- National Institute of Public Health NIH – National Research Institute, Poland
Bibliografia
- ASTM D7823 – 20 , Standard Test Method for Determination of Low Level Phthalates in Poly (Vinyl Chloride) Plastics by Thermal Desorption – Gas Chromatography/Mass Spectrometry
- Chmielewski, J., Rutkowski, A., Wójtowicz, B., Żeber-Dzikowska, I., Szpringer, M., Czarny-Działak, M., Gworek, B., Florek-Łuszczki, M., Dziechciaż, M. (2019). Release of phthalates into the environment and related health risks, Przemysł Chemiczny, 98(1), 41-45. DOI: 10.15199/62.2019.1.2 (in Polish).
- CPSC-CH-C1001-09.1 (2009). Standard Operating Procedure for Determination of Phthalates. Gaithersburg, Consumer Product Safety Commission (CPSC), https://www.cpsc.gov/s3fs-public/pdfs/blk_pdf_CPSC-CH-C1001-09.3.pdf
- Monteiro, T.M., Wollinger, W., Nogueira, R., Cristina Pires do Rego, E., Marques Rodrigues, J., Smarçaro da Cunha, J. (2011). Method development of phtalates in products for children. 6o Congresso Brasiliero de Metrologia https://studylib.net/ doc/14580847/method-development-for-phthalates-determination-in-product.
- Mrozińska, Z., Niedźwiecki, M. (2016) The use of gas chromatography for the determination of phthalic acid esters in textiles Przegląd Włókienniczy – Włókno, Odzież, Skóra, 7, 31-33.
- PN-EN ISO 14389:2014-07 Textiles – Determination of phthalates content – method with tetrahydrofuran (in Polish).
- PN-EN 15777:2009 Textiles – Phthalate test method
- Ranganadham, U. (2017). Method Development for Analysis A of Phthalatess by HPLC Governors State University OPUS Open Portal to University Scholarship, https://opus.govst.edu/cgi/viewcontent.cgi?article=1360&context=capstones
- Consolidated text: Regulation (EC) No 1907/2006 of the European Parliament and of the Council of 18 December 2006 concerning the Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), establishing a European Chemicals Agency, amending Directive 1999/45/EC and repealing Council Regulation (EEC) No 793/93 and Commission Regulation (EC) No 1488/94 as well as Council Directive 76/769/EEC and Commission Directives 91/155/EEC, 93/67/EEC, 93/105/EC and 2000/21/EC (Text with EEA relevance)Text with EEA relevance http://data.europa.eu/eli/reg/2006/1907/2022-05-01
- Wang, Q. & Storm, B.K. (2005). Separation and analysis of low molecular weight plasticisers in poly(vinyl chloride) tubes. Polymer Testing, 24(3), 290-300. DOI: 10.1016/ j.polymertesting.2004.12.002
- Zou, Y., Cai, M. (2013) Determination of Phthalate Concentration in Toys and Children’s Products, Agilent Technologies (Shanghai) Co. Ltd https://www.agilent. com/cs/library/applications/5990-4863EN.pdf
- https://www.tcichemicals.com/BE/en/p/P0304
- JRC European Commission; Summary Risk Assessment Report; Bis(2-ethylheksyl) phthalate (DEHP), 2008, EUR 23384 EN2
- Haji, Harunarashid N.Z.I., Lim, L.H., Harunsani, M.H. (2017). Phthalate Sample Preparation Methods and Analysis in Food and Food Packaging, Food Anal. Methods, 10, 3790-3814. DOI: 10.1007/s12161-017-0938-7
- Korkmaz, S.D., Küplülü, Ö. (2019). Determination of phthalates in some milk products by liquid chromatography/tandem mass spectrometry. Ankara Univ. Vet. Fak. Derg., 66, 231-236. DOI: 10.33988/auvfd.436873
- Huang Z., Tu C., Liu H., Wang L., Zhu Z., Watanabe I. (2020) Hollow fiber-solid phase microextraction of phthalate esters from bottled water followed by flash evaporation gas chromatography-flame ionisation detection. J. Chromatogr. A., 1619, 460953-460961. DOI: 10.1016/j.chroma.2020.460953
- Mirzajani, R., Kardani, F., Ramezani, Z. (2020) Fabrication of UMCM-1 based monolithic and hollow fiber – Metal-organic framework deep eutectic solvents/molecularly imprinted polymers and their use in solid phase microextraction of phthalate esters in yogurt, water and edible oil by GC-FID. Food Chem., 314, 126179. DOI: 10.1016/j.food-chem.2020.126179
- Socas-Rodríguez, B., González-Sálamo, J., Herrera-Herrera, A.V., Santana-Mayor, Á., Hernández-Borges, J. (2018). Determination of phthalic acid esters in different baby food samples by gas chromatography tandem mass spectrometry. Anal. Bioanal. Chem., 410, 5617-5628. DOI: 10.1007/s00216-018-0977-y
- Qing, Lv, Haiyu, Li, Zhijuan, Wang, Hua, Bai, Qing, Zhang (2017). Determination of Migration of Six Phthalate Esters in Plastic Toys by GC-MS/MS Coupled with Solid-Phase Extraction Using Cucurbit[n]urils as Adsorbent, Publisher ID: TOCENGJ-11-53. DOI: 10.2174/1874123101711010053
- Perestrelo, R., Silva, C.L., Algarra, M., José, S., Câmara, J.S. (2021). Evaluation of the Occurrence of Phthalates in Plastic Materials Used in Food Packaging. Appl. Sci., 11(5), 2130. DOI: 10.3390/app11052130
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8eef9ee7-13f8-4c1c-9ce8-24b75ea71323