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In this paper results of microstructural observations for series of CuZn39Pb2 alloys produced from qualified scraps are presented. The individual alloy melts were differentiated in terms of thermal parameters of continuous casting as well as refining methods and modifications. Structural observations performed by SEM and TEM revealed formation of different types of intermetallic phases including “hard particles”. EDS results show that “hard particles” are enrich in silicon, phosphorus, iron, chromium and nickel elements. Additionally, formation of Al-Fe-Si and Al-Cr in alloy melts was observed as well. It was found that quantity and morphology of intermetallic phases strongly depends upon the chemical composition of raw materials, process parameters, modifiers and refining procedure applied during casting. It was observed that refining process results in very effective refinement of intermetallic phases, whereas modifiers, particularly carbon-based, results in formation of large particles in the microstructure.
Czasopismo
Rocznik
Tom
Strony
21--26
Opis fizyczny
Bibliogr. 16 poz., rys., tab.
Twórcy
autor
- University of Zielona Góra, Faculty of Mechanical Engineering, Zielona Góra, Poland
autor
- AGH University of Science and Technology, Faculty of Non-Ferrous Metals, Kraków, Poland
autor
- AGH University of Science and Technology, Faculty of Non-Ferrous Metals, Kraków, Poland
autor
- BOLMET S.A., Wiechlice, Poland
Bibliografia
- [1] Kozana, J., Rzadkosz, St. & Piękoś, M. (2010). Influence of the selected alloy additions on limiting the phase gamma formation in Cu-Zn alloys. Archives of Foundry Engineering. 10(1), 221-225. ISSN (1897-3310).
- [2] Anakhov, S.V. & Fominykh, S.I. (1997). Effect of the cooling rate after remelting on the structure of antifriction brass. Metal Science and Heat Treatment. 39(6), 240-243. ISSN (0026-0673).
- [3] Kondracki, M. & Szajnar, J. (2007). Possibilities for leaded brass replacement with multi-component brass. Archives of Foundry Engineering. 7(2), 57-64. ISSN (1897-3310).
- [4] Alexandrova, I.V., Alexandrov, D.V., Aseev, D.L. & Bulitcheva, S.V. (2009). Mushy layer formation during solidification of binary alloys from a cooled wall: the role of boundary conditions. Acta Physica Polonica A. 115, 6-9.
- [5] Hunt, J.D. (1984). Steady State Columnar and Equiaxed Growth of Dendrites and Eutectics. Materials Science and Engineering. 65, 75-83. ISSN (2161-6213).
- [6] Weigand, B. & Lipnicki, Z. (2016). Development of the contact layer and its role in the phase change process. International Journal of Heat and Mass Transfer. 93, 1082-1088. ISSN (0017-9310).
- [7] Vusanović, I. & Voller, V.R. (2014). Understanding Channel Segregates in Numerical Models of Alloy Solidification: A Case of Converge First and Ask Questions Later. Materials Science Forum. 790/791, 73-78.
- [8] Szajnar, J. (2004). The Columnar Crystals Shape and Castings Structure Cast in Magnetic Field. Journal of Materials Processing Technology. 157/158, 761-764.
- [9] Gandin, Ch.A., Mosbah, S., Volkmann, Th. & Herlach, D.M. (2008). Experimental and Numerical Modeling of Equiaxed Solidification in Metallic Alloys. Acta Materialia. 56, 3023-3035.
- [10] Majchrzak, E., Mochnacki, B., Dziewoński, M. & Jasiński, M. (2008). Identification of boundary heat flux on the continuous casting surface. Archives of Foundry Engineering. 8(4), 105-110.
- [11] Konozsy, L., Ishmurzin, A., Grasser, M., Wu, M.H., Ludwig, A., Tanzer, R. & Schutzenhofer, W. (2010). Columnar to Equiaxed Transition during Ingot Casting using Ternary Alloy Composition. Materials Science Forum. 649, 349-354.
- [12] Lipnicki, Z. & Pantoł, K. (2015). Role of a continuous casting forms on the shape of the solidified crust. Archives of Metallurgy and Materials. 60(4), 2553-2557.
- [13] Bydałek, A.W., Biernat, S., Schlafka, P., Holtzer, M., Wołczyński, W. & Bydałek, F. (2016). The Influence of the Chemical Composition of Selected Waste Materials from the Production of Copper on the Final Environmental Assessment. Archives of Metallurgy and Materials. 61(4), 2135-2140. ISSN (1733-3490).
- [14] Schlafka, P., Bydałek, A.W., Holtzer, M. & Wołczyński, W. (2016). The Influence Of The Ionic reactions On The Refining Secondary Raw Materials. Metalurgija. 55(4), 609-612. ISSN (0543-5846).
- [15] Rzadkosz, S., Zych, J., Garbacz-Klempka, A., Kranc, M., Kozana, J., Piękoś, M., Kolczyk, J. & Jamrozowicz, Ł. (2015). Copper alloys in investment casting technology. Metalurgija. 54(1), 293-296. ISSN (0543-5846).
- [16] DOXPED. A refining and modification agent for metal alloys. Patent RP 344768. Date of application: 20-12-2000, Date of award: 19-04-2006. (in Polish).
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8e998085-7400-4950-8c17-e9182c8c2ee8