Physicochemistry, morphology and leachability of selected metals from post-galvanized sewage sludge from screw factory in Łańcut, SE Poland

• Autorzy: Galas D. , Kalembkiewicz J. , Sitarz-Palczak E.

Identyfikatory

DOI

10.1515/ctg-2016-0006

• Języki publikacji: EN

Abstrakty

EN

Morphology, physicochemical properties, chemical composition of post-galvanized sewage sludge from Screw Factory in Łańcut, leachability and mobility of metals has been analyzed. The analyses with the use of scanning electron microscope with an adapter to perform chemical analysis of microsites (EDS) showed that the material is characterized by a high fragmentation and a predominant number of irregularly shaped grains. The sewage sludge is alkaline with a large loss of ignition (34.6%) and small bulk density (< 1 g/cm3). The EDS analyses evidenced presence of oxygen, silicon, calcium, chromium, iron and zinc in all examined areas, and presence of manganese and copper in selected areas indicating a non-uniform distribution of metals in the sewage sludge. Within one-stage mineralization and FAAS technique a predominant share of calcium, zinc and iron in terms of dry matter was recorded in the sewage sludge. The contents of Co, Cr, Cu, K, Mn, Ni and Pb in sewage sludge are below 1%. Evaluation of mobility and leaching of metals in sewage sludge was carried out by means of two parameters: accumulation coefficient of mobile fractions and leaching level related to the mass solubility of sewage sludge. The results indicate that the short-term or long-term storage of not inactivated post-galvanized sewage sludge can result in release of metals.

Słowa kluczowe

EN

post-galvanized sewage sludge; leachability; heavy metals

PL

cynkowanie; osad ściekowy; metale ciężkie

• Wydawca: De Gruyter
• Czasopismo: Contemporary Trends in Geoscience
• Rocznik: 2016
• Tom: Vol. 5, iss. 2
• Strony: 83--91
• Opis fizyczny: Bibliogr. 19 poz., wykr., zdj.

Twórcy

autor

Galas D.

• Rzeszow University of Technology, Faculty of Chemistry, Powstańców Warszawy 6 Ave., 35-959 Rzeszów, Poland

autor

Kalembkiewicz J.

autor

Sitarz-Palczak E.

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