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Abstrakty
Adsorption methods are widely used in the removal of heavy metals from aquatic environments, and adsorbents are crucial for adsorption efficiency. In this study, a magnetic nanoparticle composite material, Fe3O4@PEG@IL, modified with an imidazole-based ionic liquid [Cn MIm ]HCO3 (n = 2, 4, 6, 8) was used as an adsorbent to adsorb the heavy metal chromium (Cr(vi)) in aquatic environments, and the adsorption conditions were optimized. Moreover, the selective adsorption of Cr(vi) by the adsorbent was explored. The results show that when the pH value of the aqueous solution was 3.0, the solution temperature was 65℃, the amount of Fe3O4@PEG@IL added was 25 mg, and the time of adsorption reaction was 2.5 h, a good adsorption effect would be achieved, with an adsorption rate of 99.5%. Meanwhile, Fe3O4@PEG@IL had high adsorption selectivity for Cr(vi), and heavy metal cations, such as Pb2+, Hg2+, Cd2+, and Cu2+, did not interfere with the adsorption of Cr(vi). Moreover, the adsorbent was easy to recover and had good reusability.
Słowa kluczowe
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Czasopismo
Rocznik
Tom
Strony
128--138
Opis fizyczny
Bibliogr. 18 poz., rys.
Twórcy
autor
- School of Chemistry and Chemical Engineering, Jining Normal University Ulanqab, China
autor
- School of Chemistry and Chemical Engineering, Jining Normal University Ulanqab, China
autor
- School of Chemistry and Chemical Engineering, Jining Normal University Ulanqab, China
Bibliografia
- [1] Zeiner, M., Rezić, T., Šantek, B., Rezić, I., Hann, S., Stingeder, G., Removal of Cr, Mn, and Co from textile wastewater by horizontal rotating tubular bioreactor, Environ. Sci. Technol., 2012, 46(19): 10690–10696, 10.1021/es301596g
- [2] Feng, X., Long, R., Wang, L., Liu, C., Bai, Z., Liu, X., A review on heavy metal ions adsorption from water by layered double hydroxide and its composites, Sep. Purif. Technol., 2022, 284: 120099, 10.1016/j.seppur.2021.120099
- [3] Xia, S., Song, Z., Jeyakumar, P., Bolan, N., Wang, H., Characteristics and applications of biochar for remediating Cr(vi)-contaminated soils and wastewater, Environ. Geochem. Health, 2020, 42: 1543–1567, 10.1007/s10653-019-00445-w
- [4] Yang, D., Chen, Y., Li, J., Li, Y., Song, W., Li, X., et al., Synthesis of calcium–aluminum-layered double hydroxide and a polypyrrole decorated product for efficient removal of high concentrations of aqueous hexavalent chromium, J. Colloid Interface Sci., 2022, 607: 1963–1972, 10.1016/j.jcis.2021.10.014
- [5] Wang, J., Liu, G., Li, T., Zhou, C., Physicochemical studies toward the removal of Zn(ii) and Pb(ii) ions through adsorption on montmorillonite-supported zero-valent iron nanoparticles, RSC Adv., 2015, 5(38): 29859–29871, 10.1039/c5ra02108a
- [6] Chen, J., Dong, R., Chen, S., Tang, D., Lou, X., Ye, C., et al., Selective adsorption towards heavy metal ions on the green synthesized polythiophene/MnO2 with a synergetic effect, J. Clean. Prod., 2022, 338: 130536, 10.1016/j.jclepro.2022.130536
- [7] Shi, T., Xie, Z., Zhu, Z., Shi, W., Liu, Y., Liu, M., Highly efficient and selective adsorption of heavy metal ions by hydrazide-modified sodium alginate, Carbohydr. Polym., 2022, 276: 118797, 10.1016/j.carbpol.2021.118797
- [8] Gupta, K., Joshi, P., Gusain, R., Khatri, O., Recent advances in adsorptive removal of heavy metal and metalloid ions by metal oxide-based nanomaterials, Coord. Chem. Rev., 2021, 445: 214100, 10.1016/j.ccr.2021.214100
- [9] Yang, L., Su, P., Chen, X., Zhang, R., Yang, Y., Microwave-assisted synthesis of poly (ionic liquid)-coated magnetic nanoparticles for the extraction of sulfonylurea herbicides from soil for HPLC, Anal. Methods., 2015, 7(7): 3246–3252, 10.1039/c4ay02830a
- [10] Zhang, M., Chen, J., Zhao, F., Zeng, B., Determination of fluoroquinolones in foods using ionic liquid modified Fe3O4/MWCNTs as the adsorbent for magnetic solid phase extraction coupled with HPLC, Anal. Methods, 2020, 12(36): 4457–4465, 10.1039/d0ay01045f
- [11] Dang, Y., Ma, X., Zou, J., Preparation of silica-coated magnetic nanomaterials modified with ionic liquid and its application in detection of trace cadmium ion in water, J. Instrum. Anal., 2012, 31(7): 823–827, 10.3969/j.issn.1004-4957.2012.07.011
- [12] Rajadurai, V., Anguraj, B., Ionic liquids to remove toxic metal pollution, Environ. Chem. Lett., 2021, 19(2): 1173–1203, 10.1007/s10311-020-01115-5
- [13] Imdad, S., Dohare, R., A critical review on heavy metals removal using ionic liquid membranes from the industrial wastewater, Chem. Eng. Process., 2022, 173: 108812, 10.1016/j.cep.2022.108812
- [14] Wang, Z., Xi, H., Kong, L., Zuo, Y., Shi, Z., Zhao, S., Solubility and selective oxidation of 2-chloroethyl ethyl sulfide in imidazole-based ionic liquids, Mol. Catal., 2017, 430: 1–8, 10.1016/j.molcata.2016.12.005
- [15] Antarnusa, G., Jayanti, P.D., Denny, Y.R., Suherman, A., Utilization of co-precipitation method on synthesis of Fe3O4/PEG with different concentrations of PEG for biosensor applications, Materialia, 2022, 25: 101525, 10.1016/j.mtla.2022.101525
- [16] Wang, X., Zhou, Z., Jing, G., Synthesis of Fe3O4 poly (styrene–glycidyl methacrylate) magnetic porous microspheres and application in the immobilization of Klebsiella sp. FD-3 to reduce Fe(iii) EDTA in a NOx scrubbing solution, Bioresour. Technol., 2013, 130: 750–756, 10.1016/j.biortech.2012.12.010
- [17] Kong, L., Lu, X., Bian, X., Zhang, W., Wang, C., Constructing carbon-coated Fe3O4 microspheres as antiacid and magnetic support for palladium nanoparticles for catalytic applications, ACS Appl. Mater. Interfaces, 2011, 3(1): 35–42, 10.1021/am101077a
- [18] Wieszczycka, K., Filipowiak, K., Wojciechowska, I., Aksamitowski, P., Novel ionic liquid-modified polymers for highly effective adsorption of heavy metals ions, Sep. Purif. Technol., 2020, 236: 116313, 10.1016/j.seppur.2019.116313
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8e40f5fa-f808-4f92-8bf1-ac5859f3b566