Determination of acidic pharmaceuticals in municipal wastewater by using solid-phase extraction followed by gas chromatography-mass spectrometry

• Autorzy: Nosek K. , Styszko K. , Gołaś J.

Warianty tytułu

PL

Oznaczanie kwasowych leków w ściekach komunalnych metodą chromatografii gazowej ze spektrometrem mas z wykorzystaniem ekstrakcji do fazy stałej

• Języki publikacji: EN

Abstrakty

EN

The appearance of pharmaceutical compounds and the need of their determination in an aquatic environment has become a subject of growing concern over recent years. This paper describes an application of a quantitative analytical method for the determination of selected nonsteroidal anti-inflammatory drugs: ketoprofen, naproxen, diclofenac and other newly emerging contaminants - triclosan and bisphenol A in influent and effluent from a wastewater treatment plant located in Kraków (Poland). Samples were isolated and preconcentrated by using the solid - phase extraction (SPE) technique, then eluat was derivatized with N-methy-N-(trimethylsilyl)-trifluoroacetamide (MSTFA) and analyzed by gas chromatography coupled with mass spectrometry. All of tested pharmaceuticals were present in the wastewater treatment plant effluent and influent at concentration ppt to ppb.

Słowa kluczowe

EN

pharmaceuticals; wastewater; GC-MS; solid-phase extraction; derivatization

PL

farmaceutyki; ścieki komunalne; GC-MS; ekstrakcja do fazy stałej; derywatyzacja

• Wydawca: AGH University of Science and Technology Press
• Czasopismo: Geomatics and Environmental Engineering
• Rocznik: 2012
• Tom: Vol. 6, no. 3
• Strony: 45--60
• Opis fizyczny: Bibliogr. 31 poz., rys., tab., wykr.

Twórcy

autor

Nosek K.

• AGH University of Science and Technology, Faculty of Energy and Fuels, Department of Coal Chemistry and Environmental Sciences, Krakow, Poland

autor

Styszko K.

• AGH University of Science and Technology, Faculty of Energy and Fuels, Department of Coal Chemistry and Environmental Sciences, Krakow, Poland

autor

Gołaś J.

• AGH University of Science and Technology, Faculty of Energy and Fuels, Department of Coal Chemistry and Environmental Sciences, Krakow, Poland

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