Room-temperature sensing performance of hydrogen using palladium-based film by optical setup

• Autorzy: Yao Yiyun , Corso Alain J. , Bazzan Marco , Tessarolo Enrico , Wang Zhanshan , Huang Qiushi , Qi Runze , Martucci A. , Pelizzo Maria G.

Identyfikatory

DOI

10.37190/oa200411

• Języki publikacji: EN

Abstrakty

EN

H₂ sensing performance of novel Pd–Pt alloy films has been compared with those obtained by using Pd films and H₂-reducted PdO films. Two different detecting systems were used to measure the hydrogenation and de-hydrogenation phases with a H₂ concentration of both 5% v/v nitrogen and 1% v/v nitrogen at room temperature. The sensitivity loss observed for the Pd–Pt alloy and H₂-reducted PdO samples with respect to pure Pd samples can be explained in terms of the reduction in the lattice constant and interstitial volume due to the Pt addition, which determine a decrement of hydrogen atoms penetrating in the films. On the other hand, results show an improvement in time-response for Pd–Pt alloy and H₂-reducted PdO films with respect to pure Pd ones, presumably due to the increase of its permeability to H₂. Moreover, the sensing measurements repeated after 60 days show that the Pd–Pt alloy films, unlike the Pd-based ones, fully preserve their performances, demonstrating the advantage of the Pt inclusion for stability purposes when the samples are stored upon humidity.

Słowa kluczowe

EN

hydrogen detection; palladium-based film; palladium–platinum alloy film; optical sensor

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2020
• Tom: Vol. 50, nr 4
• Strony: 649--661
• Opis fizyczny: Bibliogr. 39 poz., rys.

Twórcy

autor

Yao Yiyun

• Key Laboratory of Advanced Micro Structural Materials MOE, Institute of Precision Optical Engineering, School of Physics Science and Engineering, Tongji University, 200092, Shanghai, China

autor

Corso Alain J.

• National Research Council of Italy, Institute for Photonics and Nanotechnologies, Via Trasea 7, 35131 Padova, Italy
• University of Padova, Department of Information Engineering, Via Gradenigo 6/B, 35131 Padova, Italy

autor

Bazzan Marco

• University of Padova, Department of Physics and Astronomy, Via Marzolo 19, 35131 Padova, Italy

autor

Tessarolo Enrico

• National Research Council of Italy, Institute for Photonics and Nanotechnologies, Via Trasea 7, 35131 Padova, Italy

autor

Wang Zhanshan

• Key Laboratory of Advanced Micro Structural Materials MOE, Institute of Precision Optical Engineering, School of Physics Science and Engineering, Tongji University, 200092, Shanghai, China

autor

Huang Qiushi

• Key Laboratory of Advanced Micro Structural Materials MOE, Institute of Precision Optical Engineering, School of Physics Science and Engineering, Tongji University, 200092, Shanghai, China

autor

Qi Runze

• Key Laboratory of Advanced Micro Structural Materials MOE, Institute of Precision Optical Engineering, School of Physics Science and Engineering, Tongji University, 200092, Shanghai, China

autor

Martucci A.

• University of Padova, Department of Industrial Engineering, Via Gradenigo 6/A, 35131 Padova, Italy

autor

Pelizzo Maria G.

• National Research Council of Italy, Institute for Photonics and Nanotechnologies, Via Trasea 7, 35131 Padova, Italy
• University of Padova, Department of Information Engineering, Via Gradenigo 6/B, 35131 Padova, Italy

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Uwagi

Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).