Spectrofluorometric characterization of oil from pyrolysis of scrap tires

• Autorzy: Ambrosewicz-Walacik M. , Piętak A.

Identyfikatory

DOI

10.5604/12314005.1213510

• Języki publikacji: EN

Abstrakty

EN

Almost all kinds of fuel applied in combustion engines come from refining industry, in which crude oil serves as basic raw material. However, there are also searched other sources of hydrocarbons which can be used directly or as additives to conventional fuels. The most popular in this regard are vegetable oils such as rapeseed oil, from which are produced esters used as fuel for diesel engines. On the other hand, as additives to gasoline can be used alcohols derived from the fermentation of agricultural products. Another way to obtain liquid hydrocarbons is pyrolysis of scrap tires. In this article, such pyrolytic product is analysed in terms of its fluorescence properties compared to the fluorescent properties of substances derived from the distillation of the pyrolysis product in three following temperatures: 160, 204 and 350 ºC. All the tested substances show relatively strong fluorescence in ultraviolet range. Fluorometric spectra were performed applying the spectrofluorometer Hitachi F-7000 FL with 1x1 cm quartz cuvette. Studied substances were previously diluted in n-hexane to obtain concentration 4 ppm. Amount of fluorescent peaks and their positions depends on kind of distillate. Ipso facto fluorescence method seems be suitable much more – than chemical analyse – for quick identification of substances constituting a components of distillate obtained from pyrolytic product.

Słowa kluczowe

EN

fuels; used car tires; pyrolysis; fluorescence

• Wydawca: Łukasiewicz Research Network - Institute of Aviation ; European Science Society of Powertrain and Transport KONES Poland ; Wydawnictwo Instytutu Technicznego Wojsk Lotniczych
• Czasopismo: Journal of KONES
• Rocznik: 2016
• Tom: Vol. 23, No. 1
• Strony: 25--30
• Opis fizyczny: Bibliogr. 8 poz., rys.

Twórcy

autor

Ambrosewicz-Walacik M.

• University of Warmia and Mazury, Department of Mechatronics Sloneczna Street 46A, 10-710 Olsztyn, Poland tel.:+ 48 89 5245104, fax: [phone]

autor

Piętak A.

• University of Warmia and Mazury, Department of Mechatronics Sloneczna Street 46A, 10-710 Olsztyn, Poland tel.:+ 48 89 5245104, fax: [phone]

Bibliografia

• [1] Goyal, H. B., Seal, D., Saxena, R. C., Bio-fuels from thermochemical conversion of renewable resources: A review, Renewable and Sustainable Energy Reviews, Vol. 12, pp. 504-517, 2008.
• [2] Zhang, X., Wang, T., Ma, L., Chang, J., Vacuum pyrolysis of waste tires with basic additives, Waste Management, Vol. 28, pp. 2301-2310, 2008.
• [3] Pilusa, T. J., Shukla, M., Muzenda, E., Pyrolitic tire derived fuel: A review. International Conference on Chemical, Mining and Metallurgical Engineering (CMME'2013) Nov. 27-28 2013, Johannesburg (South Africa), pp. 265-268, 2013.
• [4] Prathmesh, M., Paresh, D., Suitability of tyre pyrolysis oil (TPO) as an alternative fuel for internal combustion engine, International Journal of Advanced Engineering Research and Studies, Vol. 1, pp. 61-65, 2012.
• [5] Laresgoiti, M. F., Caballero, B. M., De Marco, I., Torres A., Cabrero, M. A., Chomon, M. J., Characterization of the liquid products obtained in tire pyrolysis, Journal of Analytical and Applied Pyrolysis, Vol. 71, pp. 917-934, 2004.
• [6] Bridgwater, A. V., Review of fast pyrolysis of biomass and product upgrading, Biomass and Bioenergy, Vol. 38, pp. 68-94, 2012.
• [7] Quek, A., Balasubramanian, R., Liquefaction of waste tires by pyrolysis for oil and chemicals –A review, Journal of Analytical and Applied Pyrolysis, Vol. 101, pp. 1-16, 2013.
• [8] Rodrigues, J. J. S., Sanz, C. P., Fluorescence techniques for the determination of polycyclic aromatic hydrocarbons in marine environment: An overview. Analysis, Vol. 28, pp. 711-716, 2000.

Uwagi

PL

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.