Identyfikatory
DOI
Warianty tytułu
Języki publikacji
Abstrakty
Cu2+ and Pb2+ are widely used as activators for the flotation of stibnite. In this work, by the treatment of Cu2+ or Pb2+, the activation product and the thickness of activation layer on the stibnite surface were both investigated. Based on the flotation results, zeta potential analysis and X-ray photoelectron spectroscopy (XPS) study, it was found that Cu2+ was reduced to Cu+ at the stibnite surface and a layer of Cu2S was formed at the surface. While, a PbS layer presenting at the stibnite surface is responsible for the activation flotation of stibnite with Pb2+. Time of flight secondary ion mass spectrometry (TOF-SIMS) analysis further implies that, when stibnite was activated with 5×10-5 mol/dm3 of CuSO4 or Pb(NO3)2, the thickness of Cu2S layer on the Cu-activated surface was close to 2.7 nm, while the thickness of PbS layer was about 1.8 nm on the Pb-activated surface.
Słowa kluczowe
Rocznik
Tom
Strony
763--770
Opis fizyczny
Bibliogr. 21 poz., rys., tab.
Twórcy
autor
- State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming, 650093, Yunnan, PR China
autor
- Faculty of Land Resources Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, PR China
autor
- Faculty of Information Engineering and Automation, Kunming University of Science and Technology, Kunming, 650093, Yunnan, PR China
autor
- State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming, 650093, Yunnan, PR China
Bibliografia
- ADAMS, M., LAWRENCE, R., BRATTY, M., (2008), Biogenic sulphide for cyanide recycle and copper recovery in gold–copper ore processing, Minerals Engineering, 21, 509-517.
- ALBERICI, S.G., ZONCA, R., PASHMOKOV, B., (2004), Ti diffusion in chalcogenides: a ToF-SIMS depth profile characterization approach, Applied Surface Science, 231, 821-825.
- ANDERSON, C.G., (2012), The metallurgy of antimony, Chemie der Erde - Geochemistry, 72, 3-8.
- CHELGANI, S.C., HART, B., (2014), TOF-SIMS studies of surface chemistry of minerals subjected to flotation separation – A review, Minerals Engineering, 57, 1-11.
- CHELGNI, S.C., HART, B., XIA, L., (2013), A TOF-SIMS surface chemical analytical study of rare earth element minerals from micro-flotation tests products, Minerals Engineering, 45, 32-40.
- DAI, Y.H., WANG, Q.L., ZHOU, H.Q., (2009), Process Study on some Antimony Ore in Xinning of Hunan Province, Hunan Nonferrous Metals, 25, 16-18.
- HUANG, K., (1987), The flotation behavior and surface electrical property of antimonite, J. Cent.-South Inst. Min. Metall.(China), 1, 105-109.
- JIANG, Y., YU, B.B., LIU, J., LI, Z.H., SUN, J.K., ZHONG, X., HU, J., SONG, W.G., WAN, L.J., (2015), Boosting the Open Circuit Voltage and Fill Factor of QDSSCs using Hierarchically Assembled ITO@Cu2S Nanowire Array Counter Electrodes, Nano Letters, 15, 3088-3095.
- KHMELEVA, T.N., BEATTIE, D.A., GEORGIEV, T.V., SKINNER, W.M., (2013), Surface study of the effect of sulphite ions on copper-activated pyrite pre-treated with xanthate, Minerals Engineering, 16, 601-608.
- LAGER, T., FORSSBERG, K.S.E., (1989), Beneficiation characteristics of antimony minerals a review- part 1, Minerals Engineering, 2, 321-336.
- LAGER, T., FORSSBERG, K.S.E., (2015), Comparative study of the flotation properties of jamesonite and stibnite, Scandinavian Journal of Metallurgy, 18, 122-130.
- LI, H., MU, S., WENG, X., ZHAO, Y., SONG, S., (2016), Rutile flotation with Pb2+ ions as activator: Adsorption of Pb2+ at rutile/water interface, Colloids and Surfaces A: Physicochemical and Engineering Aspects ,506, 431-437.
- MAO, D., BLATZ, G., JR, C.E.W., GLOECKLER, M, (2016), Correlative impurity distribution analysis in cadmium telluride (CdTe) thin-film solar cells by ToF-SIMS 2D imaging, Solar Energy Materials & Solar Cells, 157, 65-73.
- PENG, Y., GRANO, S., (2010), Effect of grinding media on the activation of pyrite flotation, Minerals Engineering, 23, 600-605.
- SARVARAMINI, A., LARACHI, F., HART, B., (2016), Collector attachment to lead-activated sphalerite – Experiments and DFT study on pH and solvent effects, Applied Surface Science, 367, 459-472.
- SOLOZHENKIN, P.M., ZINCHENKO, Z., KRILOVA, I., IVANOVA, N., (1991), Flotation of complex antimony ore, Proceedings of the 17th international conference on mineral processing, Dresden, Germany, pp. 163-174.
- SUI, C.C., BRIENNE, S.H.R., XU, Z.H., FINCH J.A., (1997), Xanthate adsorption on Pb contaminated pyrite, International Journal of Mineral Processing, 49, 207-221.
- THOMAS, J.P., ZHAO, L., ABDELLAH, M., HEINIG, N.F., LEUNG, K.T., (2013), Interfacial micropore defect formation in PEDOT:PSS-Si hybrid solar cells probed by TOF-SIMS 3D chemical imaging, Analytical Chemistry, 85, 6840-6845.
- WANG, H., ZHOU, A., PENG, F., YU, H., YANG, J., (2007), Mechanism study on adsorption of acidified multiwalled carbon nanotubes to Pb(II), Journal of Colloid & Interface Science, 316, 277-283.
- XU, X., LIU, J.A., HU, X., (1991), Non-chromate flotation separation of complex stibntie-cinnaber ore, Nonferrous Metals, 1, 25-32.
- ZWIERNIK, M.J., QUENSEN, J.F., BOYD, S.A., (1998), FeSO4 Amendments Stimulate Extensive Anaerobic PCB Dechlorination, Environmental Science & Technology, 32, 3360-3365.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8c15f085-65b7-43dc-a0fc-804be36a8f65