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In this work extraction of copper and iron from a reverberatory furnace slag was studied. A two-step extraction procedure was followed. The first step was roasting of the slag in the presence of sulphuric acid at temperatures between 150 and 800oC. The second step was leaching of the resulting calcine with distilled water. The maximum copper extraction of about 94% was achieved. In this case, the slag was roasted at 250oC with sulphuric acid higher of about 33% than that stoichiometrically required, followed by water leaching of calcine at 50oC. About 55% of iron was also dissolved under these conditions. On the other hand, for the calcine obtained at sulphation temperature of 600oC, extraction of copper in a water leaching stage was still relatively high (about 79%), whereas that of iron was comparatively low (about 6%). Dissolution of copper and iron from the calcine was found to be very fast and was complete within the first few minutes. The water temperature in the leaching step was found to have no effect on extraction of copper and iron from the calcine in the range of 30 to 85oC.
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Tom
Strony
409--421
Opis fizyczny
Bibliogr. 22 poz., rys., tab.
Twórcy
autor
- University of Belgrade, Technical Faculty at Bor, P.O. Box 50, 19210 Bor, Serbia
autor
- Mining and Metallurgical Institute, Zeleni Bulevar 35, 19210 Bor, Serbia
autor
- University of Toronto, CFIE, 33 St. George Street, Toronto, Ontario, Canada M5S 2E3
autor
- University of Belgrade, Technical Faculty at Bor, P.O. Box 50, 19210 Bor, Serbia
Bibliografia
- ALTUNDOGAN H.S., TUMEN F., 1997. Metal recovery from copper converter slag by roasting with ferric sulphate. Hydrometallurgy, 44, 261-267.
- AROMAA J., MAKINEN J., VEPSALINEN H., KAARTINEN T., WAHLSTROM M., FORSEN O., 2013. Comparison of chemical and biological leaching of sulfide tailings. Physicochemical Problems of Mineral Processing 49, 607-620.
- ARSLAN C., ARSLAN F., 2002. Recovery of copper, cobalt, and zinc from copper smelter and converter slags. Hydrometallurgy 67, 1-7.
- CHEN T., LEI C., YAN B., XIAO X., 2014. Metal recovery from the copper sulfide tailing with leaching and fractional precipitation technology. Hydrometallurgy 147-148, 178-182.
- CHMIELEWSKI T., 2015. Development of a hydrometallurgical technology for production of metals from KGHM Polska Miedz S.A. concentrates. Physicochemical Problems of Mineral Processing 51, 335-350.
- D'YACHENKO A.N., KRAIDENKO R.I., PORYVAI E.B., CHEGRINTSEV S.N., 2013. Breakdown of copper-smelting slags with ammonium chloride. Russian Journal of Non-Ferrous Metals 54, 425-428.
- FRANDEGARD P., KROOK J., SVENSSON N., EKLUND M., 2013. A novel approach for environmental evaluation of landfill mining. Journal of Cleaner Production 55, 24-34.
- GUPTA C.K., 2003. Chemical Metallurgy, Wiley-VCH, Weinheim, pp. 537-539.
- HAMAMCI C., ZIYADANOGULLARI B., 1991. Effect of roasting with ammonium sulfate and sulfuric acid on the extraction of copper and cobalt from copper converter slag. Separation Science and Technology 26, 1147-1154.
- KAPUR A., GRAEDEL T.E., 2006. Copper mines above and below the ground. Environmental Science and Technology 40, 3135-3141.
- KIM H.-I., PARK K.-H., MISHRA D., 2009. Influence of sulfuric acid baking on leaching of spent Ni –Mo/Al2O3 hydro-processing catalyst. Hydrometallurgy 98, 192-195.
- KUL M., TOPKAYA Y, KARAKAYA I., 2008. Rare earth double sulfates from pre-concentrated bastnasite. Hydrometallurgy 93, 129-135.
- MURAVYOV M.I, BULAEV A.G., KONDRAT'EVA T.F., 2014. Complex treatment of mining and metallurgical wastes for recovery of base metals. Minerals Engineering 64, 63-66.
- NADIROV R.K., SYZDYKOVA L.I., ZHUSSUPOVA A.K., USSERBAEV M.T., 2013. Recovery of value metals from copper smelter slag by ammonium chloride treatment. International Journal of Mineral Processing 124, 145-149.
- OCHROMOWICZ K., CHMIELEWSKI T., 2010. Solvent extraction in hydrometallurgical processing of Polish copper concentrates. Physicochemical Problems of Mineral Processing 46, 207-218.
- PIATAK N.M., PARSONS M.B., SEAL II R.S., 2015. Characteristics and environmental aspects of slag: A review. Applied Geochemistry 57, 236-266.
- SAFARZADEH M.S., MOATS M.S., MILLER J.D., 2012. Evaluation of sulfuric acid baking and leaching of enargite concentrates. Minerals and Metallurgical Processing 29, 97-102.
- SCHLESINGER M.E., KING M.J., SOLE K.C., DAVENPORT W.G., 2011. Extractive Metallurgy of Copper, 5th ed., Elsevier, Amsterdam, pp. 191-201.
- SHEN H., FORSSBERG E., 2003. An overview of recovery of metals from slags. Waste Management 23, 933-949.
- SUKLA L.B., PANDA S.C., JENA P.K., 1986. Recovery of cobalt, nickel and copper from converter slag through roasting with ammonium sulphate and sulphuric acid. Hydrometallurgy 16, 153-165.
- TUMEN F., BAILEY N.T., 1990. Recovery of metal values from copper smelter slags by roasting with pyrite. Hydrometallurgy, 25, 317-328.
- UROSEVIC D.M., DIMITRIJEVIC M.D., JANKOVIC Z.D., ANTIC V.A., 2015. Recovery of copper from copper slag and copper slag flotation tailings by oxidative leaching. Physicochemical Problems of Mineral Processing, 51, 73-82.
Uwagi
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8ab444fb-b570-463a-8162-2b7b7c0ee1be