Preparation and characterization of PEO-based composite gel-polymer electrolytes complexed with lithium trifluoro methane sulfonate

• Autorzy: Nagajothi A. J. , Kannan R. , Rajashabala S.

Identyfikatory

DOI

10.1515/msp-2018-0025

• Języki publikacji: EN

Abstrakty

EN

Chitosan has been successfully incorporated as a filler in a polyethylene oxide (PEO) and lithium trifluoromethanesulfonate (LiCF₃SO₃) matrix with a combination of plasticizers, namely 1,3-dioxolane (DIOX) and tetraethylene glycol dimethylether (TEGDME). The composite gel-polymer electrolyte (CGPE) membranes were prepared by solution casting technique in an argon atmosphere. The prepared membranes were subjected to SEM, TG/DTA and FT-IR analyses. A Li/CGPE/Li symmetric cell was assembled and the variation of interfacial resistance was measured as a function of time. The lithium transference number (Li⁺_t) was measured and the value was calculated as 0.6 which is sufficient for battery applications. The electrochemical stability window of the sample was studied by linear sweep voltammetry and the polymer electrolyte was found to be stable up to 5.2 V.

Słowa kluczowe

EN

polyethylene oxide; ionic conductivity; FT-IR; transport number; interfacial properties

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2018
• Tom: Vol. 36, No. 2
• Strony: 185--192
• Opis fizyczny: Bibliogr. 41 poz., rys., tab.

Twórcy

autor

Nagajothi A. J.

• Department of Physics, University College of Engineering, Anna University, Dindigul-624 622, India

autor

Kannan R.

• Department of Physics, University College of Engineering, Anna University, Dindigul-624 622, India

autor

Rajashabala S.

• School of Physics, Madurai Kamaraj University, Madurai-21, India

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).