Use of sodium trithiocarbonate for remove of chelated copper ions from industrial wastewater originating from the electroless copper plating process

Thomas, M.; Zdebik, D.; Białecka, B.

doi:10.24425/119682

Artykuł - szczegóły

Tytuł artykułu

Use of sodium trithiocarbonate for remove of chelated copper ions from industrial wastewater originating from the electroless copper plating process

Autorzy

Thomas M. , Zdebik D. , Białecka B.

Treść / Zawartość

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Identyfikatory

DOI

10.24425/119682

Warianty tytułu

Zastosowanie tritiowęglanu sodu do usuwania chelatowanych jonów miedzi ze ścieków przemysłowych pochodzących z procesu bezprądowego miedziowania

Języki publikacji

Abstrakty

The possibility of chelated copper ions removal from wastewater from the production of printed circuit boards using Na₂CS₃ as a precipitant agent has been presented. The use of Na₂CS₃ (pH 9–9.5, FeCl₃ 1 mL/L, E= +82 mV) enabled successful precipitation of the complexed Cu(II) ions from wastewater (Cu 0.85 mg/L) containing potassium and sodium tartrate (KNaC₄H₄O₆) as a complexing agent. The use of higher doses of Na₂CS₃ reduced the copper content to 0.05 mg/L (pH 9–9.5, FeCl₃ 1 mL/L, E= -156 mV). Application of Response Surface Methodology (RSM) allowed for the analysis and evaluation of the impact of the various independent parameters (pH, Fe(III) coagulant dose and 44.26% Na₂CS₃ dose) on the concentration of Cu(II) in treated wastewater. The lowest values of copper concentration (0.05, 0.02 and 0.03 mg/L) in the treated wastewater was obtained in the three experiments when an alkaline medium (pH 9.5 and 10) and higher concentration of Na₂CS₃ (0.23 and 0.28 mL/L) were used. The use of Na₂CS₃ solution under optimal process conditions (pH 9–9.5, E< +5 mV, FeCl₃ 0.5–1 mL/L, Na₂CS₃ 0.28 mL/L), allows for almost complete precipitation of complexed copper ions(II) (Cu≤0.05 mg/L), most probably in the form of a brown solid Na₂CS₃.

Celem przedstawionych badań było zweryfikowanie możliwości strącania Cu(II) ze ścieków pochodzących z procesu bezprądowego miedziowania, zawierających KNaC₄H₄O₆ jako związek kompleksujący Cu(II), przy zastosowaniu Na₂CS₃. Przedstawiono możliwość usuwania Cu(II) ze ścieków pochodzących z produkcji obwodów drukowanych przy zastosowaniu Na₂CS₃ jako odczynnika strącającego. Zastosowanie Na₂CS₃ przy pH 9–9,5 w obecności koagulantu żelazowego (Fe(III)), umożliwiło skuteczne strącenie skompleksowanych jonów Cu(II) ze ścieków zawierających winian sodu i potasu (KNaC₄H₄O₆), jako związek kompleksujący. Zastosowanie metody powierzchni odpowiedzi (Response Surface Methodology, RSM) pozwoliło na analizę i ocenę wpływu poszczególnych parametrów niezależnych (pH, dawka koagulantu żelazowego, dawka 44,26% Na₂CS₃) na stężenie miedzi w ściekach oczyszczonych

Słowa kluczowe

copper ions chelated copper ions complexing compounds industrial wastewater precipitation of copper sodium tartrate potassium tartrate sodium trithiocarbonate

jony miedzi jony miedzi chelatowane związki kompleksujące ścieki przemysłowe wytrącanie miedzi winian sodowy winian potasowy tritiocarbonat sodu

Wydawca

Institute of Environmental Engineering, Polish Academy of Sciences

Czasopismo

Archives of Environmental Protection

Rocznik

2018

Tom

Vol. 44, no. 2

Strony

32--42

Opis fizyczny

Bibliogr. 32 poz., rys., tab., wykr.

Twórcy

autor

Thomas M.

Chemiqua Company, Poland

autor

Zdebik D.

dzdebik@gig.eu

Główny Instytut Górnictwa, Poland

autor

Białecka B.

Główny Instytut Górnictwa, Poland

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-8a120261-c54f-4cb6-8238-d9762e4cc94a