Preparation of bentonite/nAg nanocomposites

• Autorzy: Długosz O. , Kołodziej M. , Banach M.

Warianty tytułu

PL

Otrzymywanie nanokompozytu bentonit/nAg

• Języki publikacji: EN

Abstrakty

EN

In this work results of the preparation of bentonite/nAg nanocomposites were presented. In the first stage, the bentonite sorption properties were determined, including the equilibrium and kinetics parameters of the sorption process of silver ions on the bentonite. The study analyzed the filler sorption properties for different concentrations of silver ions in solution. The equilibrium sorption data were analyzed using Freundlich, Langmuir and Temkin equations. It was found that the best fit is given by the Freundlich equation. Analysis of the kinetics of the sorption process showed that the pseudo-second-order equation was characterized by the best fit for the experimental data, suggesting the chemical character of the adsorption process. In order to obtain a nanocomposite, silver ions contained in the composite were subjected to a reduction process using tannic acid with stabilizing and reducing properties. The obtained bentonite/nAg nanocomposites contained silver nanoparticles in the range of 162÷266 mg/g. The structures of the nanomaterials were studied by XRD and SEM methods.

PL

Celem niniejszej pracy była analiza równowagi i kinetyki procesu sorpcji jonów srebra na powierzchni napełniacza oraz otrzymanie nanokompozytu bentonit/nAg. W badaniu analizowano właściwości sorpcyjne napełniacza dla różnych stężeń jonów srebra w roztworze. Do opisu równowagi sorpcji analizowanych jonów zastosowano równania Langmuira, Freundlicha oraz Temkina. Stwierdzono, że najlepsze dopasowanie daje równanie Freundlicha. Celem badania było również określenie kinetyki sorpcji. Równanie pseudodrugiego rzędu uzyskało lepsze dopasowanie do danych doświadczalnych, co świadczy o chemicznym charakterze sorpcji. W celu otrzymania nanokompozytu jony srebra zawarte w kompozycie poddano procesowi redukcji przy użyciu kwasu taninowego, charakteryzującego się właściwościami stabilizująco-redukujących. Otrzymano nanokompozyty bentonit/nAg o zawartości nanocząstek srebra 162÷266 mg/g.

Słowa kluczowe

EN

adsorption; bentonite; equilibrium; kinetics; nanocomposite; silver

PL

adsorpcja; bentonit; równowaga; kinetyka; nanokompozyt; srebro

• Wydawca: Polskie Towarzystwo Materiałów Kompozytowych
• Czasopismo: Composites Theory and Practice
• Rocznik: 2018
• Tom: R. 18, nr 1
• Strony: 7--13
• Opis fizyczny: Bibliogr. 27 poz., rys., tab.

Twórcy

autor

Długosz O.

• Cracow University of Technology, Faculty of Chemical Engineering and Technology, Institute of Chemistry and Inorganic Technology ul. Warszawska 24, 31-155 Krakow, Poland

autor

Kołodziej M.

• Cracow University of Technology, Faculty of Chemical Engineering and Technology, Institute of Chemistry and Inorganic Technology ul. Warszawska 24, 31-155 Krakow, Poland

autor

Banach M.

• Cracow University of Technology, Faculty of Chemical Engineering and Technology, Institute of Chemistry and Inorganic Technology ul. Warszawska 24, 31-155 Krakow, Poland

Bibliografia

• [1] Wei B., Shi Z., Xiao J., Xu Y., Lv L., In vivo and in vitro antibacterial effect of nano-structured titanium coating incorporated with silver oxide nanoparticles, J. Biomater. Tissue Eng. 2017, 7, 418-425.
• [2] Lu P-J., Huang S-C., Chen Y-P., Chiueh L-C., Shih D.Y.C., Analysis of titanium dioxide and zinc oxide nanoparticles in cosmetics, J. Food Drug Anal. 2015, 23, 587-594.
• [3] Ortega-Morales B.O., Reyes-Estebanez M.M., Gaylarde C.C., Camacho-Chab J.C., Sanmartín P., Chan-Bacab M.J., Granados-Echegoyen C.A., Pereañez-Sacarias J.E., Antimicrobial properties of nanomaterials used to control microbial colonization of stone substrata, [in:] Advanced Materials for the Conservation of Stone, Springer International Publishing, Cham 2018, 277-298.
• [4] Peszke J., Dulski M., Nowak A., Balin K., Zubko M., Sułowicz S., Nowak B., Piotrowska-Seget Z., Talik E., Wojtyniak M., Mrozek-Wilczkiewicz A., Malarz K., Szade J., Unique properties of silver and copper silica-based nanocomposites as antimicrobial agents, RSC Adv. 2017, 7, 28092-28104.
• [5] Mnatsakanyan N., Trchounian A., Nanocomposite filter made from porous mineral tuff with absorbed silver nanoparticles and its application for disinfection of water, J. Water Supply Res. Technol. - Aqua jws 2018, 161.
• [6] Tahervand S., Jalali M., Sorption and desorption of potentially toxic metals (Cd, Cu, Ni and Zn) by soil amended with bentonite, calcite and zeolite as a function of pH, J. Geochemical Explor. 2017, 181, 148-159.
• [7] Monteiro M.K.S., dos Santos F.K.G., Leite R.H. de L., Aroucha E.M.M., Vitoriano J.O., Oliveira V.R.L., Hydrophilicity, solubility and optical properties in composite films of gelatin and bentonite clay in its natural form or modified, Mater. Sci. Forum 2018, 912, 136-140.
• [8] Pramanik S., Karak N., Polymer Nanocomposites for Adhesive, Coating, and Paint Applications, [in:] Properties and Applications of Polymer Nanocomposites, Springer, Berlin - Heidelberg 2017, 173-204.
• [9] Putro J.N., Santoso S.P., Ismadji S., Ju, Y.-H., Investigation of heavy metal adsorption in binary system by nanocrystalline cellulose - Bentonite nanocomposite: Improvement on extended Langmuir isotherm model, Microporous Mesoporous Mater. 2017, 246, 166-177.
• [10] Rihayat T., Salim S., Zaini H., Salmiyah, Rahmawati, C.A., Kurniati, Irawan, Y., Zaimahwati, Synthesis, characterization and microbial protection of palm oil based polyurethane / bentonite / chitosan as paint and coating material, 2nd International Conference Sustainable and Renewable Energy Engineering (ICSREE), IEEE 2017, 10-13.
• [11] Zhang X.-F., Liu, Z.-G., Shen, W., Gurunathan, S., Silver nanoparticles: Synthesis, characterization, properties, applications, and therapeutic approaches, Int. J. Mol. Sci. 2016, 17, 1534.
• [12] Hannon J.C., Kerry J.P., Cruz-Romero M., Azlin-Hasim S., Morris M., Cummins E., Kinetic desorption models for the release of nanosilver from an experimental nanosilver coating on polystyrene food packaging, Innov. Food Sci. Emerg. Technol. 2017, 44, 149-158.
• [13] Zhang C., Hu Z., Deng B., Silver nanoparticles in aquatic environments: Physiochemical behavior and antimicrobial mechanisms, Water Res. 2016, 88, 403-427.
• [14] Yakout S.M., Elsherif E., Batch kinetics, isotherm and thermodynamic studies of adsorption of strontium from aqueous solutions onto low cost rice-straw based carbons, Carbon - Sci. 2010, 1, 144-153.
• [15] Langmuir I., The constitution and fundamental properties of solids and liquids. Part I. Solids, J. Am. Chem. Soc., 1916, 38, 2221-2295.
• [16] Freundlich H., Over the adsorption in solution, Z. Phys. Chem. 1906, 57, 385-470.
• [17] Chen C., Evaluation of equilibrium sorption isotherm equations, The Open Chemical Engineering Journal 2013, 7, 24-44.
• [18] Temkin M.I., Pyzhev V., Kinetics of ammonia synthesis on promoted iron catalysts, Acta Physicochim. 1940, 12, 327-356.
• [19] Dada A.O., Olalekan A.P., Olatunya A.M., Dada O., Langmuir. Freundlich. Temkin and Dubinin-Radushkevich isotherms studies of equilibrium sorption of Zn2+ unto phosphoric acid modified rice hus, IOSR Journal of Applied Chemistry 2012, 3, 38-45.
• [20] Banach M., Bukała A., Pulit-Prociak J., Staroń P., Equilibrium and kinetics of nanosilver sorption from aqueous solutions, J. Nanosci. Nanotechnol. 2016, 16, 7898-7909.
• [21] Md Ariff N.F., Megat Hanafiah M.A.K., Wan Ngah W.S., Adsorption of Cu(II) onto cross-linked chitosan coated bentonite beads: Kinetic and isotherm studies, Key Eng. Mater. 2017, 753, 243-248.
• [22] Ghaedi M., Sadeghian B. Amiri Pebdani A., Sahraei R., Daneshfar A., Duran C., Kinetics, thermodynamics and equilibrium evaluation of direct yellow 12 removal by adsorption onto silver nanoparticles loaded activated carbon, Chemical Engineering Journal 2012, 187, 133-141.
• [23] Freitas E.D., Carmo A.C.R., Almeida Neto A.F., Vieira M.G.A., Binary adsorption of silver and copper on Verdelodo bentonite: Kinetic and equilibrium study, Appl. Clay Sci. 2017, 137, 69-76.
• [24] Constantino L.V., Quirino J.N., Monterio A.M., Abrão T., Parreira P.S., Urbano A., Santos M.J., Sorption and desorption of silver ions by bentonite clays, Environmental Science and Pollution Research 2017, 24, 11349-11359.
• [25] Zhirong L., Azhar Uddin M., Zhanxue S., FT-IR and XRD analysis of natural Na-bentonite and Cu(II)-loaded nabentonite, Spectrochim. Acta Part A, Mol. Biomol. Spectrosc. 2016, 79, 1013-1016.
• [26] Tomacheski D., Pittol M., Ferreira Ribeiro V., M. Campomanes Santana M.R., Efficiency of silver-based antibacterial additives and its influence in thermoplastic elastomers, J. Appl. Polym. Sci. 2016, 133, 1-10.
• [27] Tomacheski D., Pittol M., Simões D.N., Ribeiro V.F., Santana R.M.C., Effects of silver adsorbed on fumed silica, silver phosphate glass, bentonite organomodified with silver and titanium dioxide in aquatic indicator organisms, J. Environ. Sci. (China) 2017, 56, 230-239.

Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).