Effect of Rockfos Material Granulation on Phosphorus Sorption Kinetics

• Autorzy: Zawadzka Beata , Marzec Michał , Siwiec Tadeusz , Jóźwiakowski Krzysztof

Identyfikatory

DOI

10.12913/22998624/194128

• Języki publikacji: EN

Abstrakty

EN

The objective of the study was to analyze the kinetics of phosphorus sorption on Rockfos® material in terms of its potential use in water and wastewater treatment. The objective of the study was to ascertain the sorption capacity of the material in relation to its granularity and the predominant sorption process during the removal of phosphorus on this material. The Rockfos® material is manufactured from opoka through a thermal treatment process at 900°C. Tests were conducted on three granulations of the sorbent. The granulations were tested at sizes ranging from 1.0 to 1.6 mm, from 1.6 to 2.5 mm, and from 2.0 to 5.0 mm, using a synthetic solution with a phosphorus content of 1.0 mg/L. The kinetics of phosphorus sorption were analyzed using a variety of kinetic models, including the pseudo-first-order (PFO), pseudo-second-order (PSO), Webber-Morris (W-M), and Elovich (E) models. The degree of fit between the various models and the results of the measurements was evaluated based on an error analysis. The results demonstrated that the pseudo-second-order kinetic model provided the most accurate description of the sorption process on Rockfos® material. This finding suggests that phosphorus sorption is primarily governed by the chemisorption process. The sorption rate constant exhibited the highest value for granulations of 1.6-2.5 mm and the lowest for granulations of 2.0-5.0 mm. The sorption capacity did not exceed 0.05 mg/g in any case, with the highest value observed for material granulations of 2.0-5.0 mm and the lowest observed for grains of 1.0-1.6 mm. The phosphorus removal effects from solution for granulations of 1.0-1.6 mm, 1.6-2.5 mm, and 2.0-5.0 mm were 74.3%, 92.4%, and 97.1%, respectively. These values were positively correlated with pH value.

Słowa kluczowe

EN

wastewater treatment; phosphorus removal; rockfos® material; sorption kinetics

• Wydawca: Lublin University of Technology ; Polish Society of Ecological Engineering (PTIE), Branch of PTIE in Lublin
• Czasopismo: Advances in Science and Technology. Research Journal
• Rocznik: 2024
• Tom: Vol. 18, no. 8
• Strony: 319--332
• Opis fizyczny: Bibliogr. 64 poz., fig., tab.

Twórcy

autor

Zawadzka Beata

• Department of Environmental Engineering and Geodesy, University of Life Sciences in Lublin, ul. Leszczyńskiego 7, 20-069 Lublin, Poland

autor

Marzec Michał

• Department of Environmental Engineering and Geodesy, University of Life Sciences in Lublin, ul. Leszczyńskiego 7, 20-069 Lublin, Poland

• https://orcid.org/0000-0002-8338-0672

autor

Siwiec Tadeusz

• Department of Environmental Engineering and Geodesy, University of Life Sciences in Lublin, ul. Leszczyńskiego 7, 20-069 Lublin, Poland

autor

Jóźwiakowski Krzysztof

• Department of Environmental Engineering and Geodesy, University of Life Sciences in Lublin, ul. Leszczyńskiego 7, 20-069 Lublin, Polan

Bibliografia

• 1. Gubernat S, Masłoń A, Czarnota J, Koszelnik P. Reactive materials in the removal of phosphorus compounds from wastewater—A review. Materials. 2020;13(15): 3377.
• 2. Siwek H, Bartkowiak A, Włodarczyk M. Adsorption of Phosphates from Aqueous Solutions on Alginate/ Goethite Hydrogel Composite. Water. 2019; 11(4): 633.
• 3. Hernández-Navarro C, Pérez S, Flórez E, Acelas N, Muñoz-Saldaña J. Sargassum macroalgae from Quintana Roo as raw material for the preparation of high-performance phosphate adsorbent from aqueous solutions. J Environ Manage. 2023; 342: 118312.
• 4. Arenas-Montaño V, Fenton O, Moore B, Healy MG. Evaluation of the fertiliser replacement value of phosphorus-saturated filter media. Journal of Cleaner Production. 2021; 291: 125943.
• 5. Almanassra IW, Kochkodan V, McKay G, Atieh MA, Al-Ansari T. Review of phosphate removal from water by carbonaceous sorbents. J Environ Manage. 2021; 287: 112245.
• 6. Usman MO, Aturagaba G, Ntale M, Nyakairu GW. A review of adsorption techniques for removal of phosphates from wastewater. Water Science and Technology. 2022; 86(12): 3113–3132.
• 7. Al-Ghouti MA, Da’ana DA. Guidelines for the use and interpretation of adsorption isotherm models: A review Journal of hazardous materials. 2020; 393: 122383.
• 8. Kong L, Adidharma H. A New Adsorption Model Based on Generalized van der Waals Partition Function for the Description of All Types of Adsorption Isotherms. Chemical Engineering Journal. 2019; 375: 122112.
• 9. Ayawei N, Ebelegi A, Donbebe W. Modelling and Interpretation of Adsorption Isotherms. Hindawi Journal of Chemistry. 2017; 11.
• 10. Ramirez-Muñoz A, Pérez S, Flórez E, Acelas N. Recovering phosphorus from aqueous solutions using water hyacinth (Eichhornia crassipes) toward sustainability through its transformation to apatite. Journal of Environmental Chemical Engineering. 2021; 9(5): 106225.
• 11. Cieślik B, Konieczka P.A review of phosphorus recovery methods at various steps of wastewater treatment and sewage sludge management. The concept of “no solid waste generation” and analytical methods. Journal of Cleaner Production. 2017; 142: 1728–1740.
• 12. Sørensen BL, Dall OL, Habib K. Environmental and resource implications of phosphorus recovery from waste activated sludge. Waste Manag. 2015; 45: 391–399.
• 13. Bus A, Karczmarczyk A. Properties of lime-siliceous rock opoka as reactive material to remove phosphorous from water and wastewater. Infrastructure and Ecology of Rural Areas.. 2014(II/1). (in Polish)
• 14. Jóźwiakowski K, Gajewska M, Pytka A, Marzec M, Gizińska-Górna M, Jucherski A, et al. Influence of the particle size of carbonate-siliceous rock on the efficiency of phosphorous removal from domestic wastewater. Ecological Engineering. 2017; 98: 290–296.
• 15. Kasprzyk M, Gajewska M. Phosphorus removal by application of natural and semi-natural materials for possible recovery according to assumptions of circular economy and closed circuit of P. Science of the Total Environment. 2019;650:249-56.
• 16. Kacprzak MJ, Sobik-Szołtysek J. The opoka-rock in N and P of poultry manure management according to circular economy. Journal of Environmental Management. 2022; 316: 115262.
• 17. Kasprzyk M, editor Treatment Wetland effluent quality improvement by usage sorbents of various origin. E3S Web of Conferences; 2019: EDP Sciences.
• 18. http://www.ceramika-kufel.pl/rockfos/ (Accessed: 10.05.2024).
• 19. Renman A, Renman G. Long-term phosphate re- moval by the calcium-silicate material Polonite in wastewater filtration systems. Chemosphere. 2010; 79(6): 659–664.
• 20. Jucherski A, Walczowski A, Bugajski P, Jóźwiakowski K, Rodziewicz J, Janczukowicz W, et al. Long-term operating conditions for different sorption materials to capture phosphate from domestic wastewater. Sustainable Materials and Technologies. 2022; 31: e00385.
• 21. Kasprzyk M, Węgler J, Gajewska M, editors. Analysis of efficiency of phosphates sorption by different granulation of selected reactive material. E3S Web of Conferences; 2018: EDP Sciences.
• 22. Kasprzyk M, Czerwionka K, Gajewska M. Waste materials assessment for phosphorus adsorption toward sustainable application in circular economy. Resources, Conservation and Recycling. 2021; 168: 105335.
• 23. Pytka-Woszczyło A, Różańska-Boczula M, Gizińska-Górna M, Marzec M, Listosz A, Jóźwiakowski K. Efficiency of filters filled with rockfos for phosphorus removal from domestic sewage. Advances in Science and Technology Research Journal. 2022; 16(4): 176–188.
• 24. Zawadzka B, Siwiec T, Marzec M, Jóźwiakowski K, Listosz A. Meandering Flow Filter for Phosphorus Re- moval as a Component of Small Wastewater Treatment Plants—A Case Study. Water. 2023; 15(15): 2703.
• 25. ISO P. 6878 Water Quality—Determination of Phosphorus—Spectrometric Method with Ammonium Molybdate. Polish Committee for Standardization: Warszawa, Poland. 2006.
• 26. ISO P. 10523 Water quality - Determination of pH. Polish Committee for Standardization: Warszawa, Poland. 2012.
• 27. Wawrzkiewicz M. Removal of C.I. Basic Blue 3 dye by sorption onto cation exchange resin, functionalized and non-functionalized polymeric sorbents from aqueous solutions and wastewaters. Chemical Engineering Journal. 2013; 217: 414–425.
• 28. Nastawny M, Jucherski A, Walczowski A, Jóźwiakowski K, Pytka A, Gizińska-Górna M, et al. Preliminary evaluation of selected mineral adsorbents used to remove phosphorus from domestic wastewater. Chemical Industry. 2015;94(10): 1762–1766. (in Polish)
• 29. Zamparas M, Gianni A, Stathi P, Deligiannakis Y, Zacharias I. Removal of phosphate from natural waters using innovative modified bentonites. Applied Clay Science. 2012; 62: 101–106.
• 30. Huang W, Yu X, Tang J, Zhu Y, Zhang Y, Li D. Enhanced adsorption of phosphate by flower-like meso-porous silica spheres loaded with lanthanum. Microporous and Mesoporous Materials. 2015; 217: 225–232.
• 31. Liu X, Zhang L. Removal of phosphate anions us ing the modified chitosan beads: Adsorption kinetic, isotherm and mechanism studies. Powder Technology. 2015;2 77: 112–119.
• 32. Campos NF, Barbosa CM, Rodríguez-Díaz JM, Du- arte MM. Removal of naphthenic acids using activated charcoal: Kinetic and equilibrium studies. Adsorption Science & Technology. 2018: 36(7–8): 1405–1421.
• 33. Saoudi Hassani EM, Azzouni D, Alanazi MM, Mehdaoui I, Mahmoud R, Kabra A, et al. Innovative plant-derived biomaterials for sustainable and effective removal of Cationic and Anionic dyes: kinetic and thermodynamic study. Processes. 2024; 12(5): 922.
• 34. Tsibranska I, Hristova E. Comparison of different kinetic models for adsorption of heavy metals onto activated carbon from apricot stones. Bulgarian Chemical Communications. 2011;43(3): 370-7.
• 35. Zamri NII, Zulmajdi SLN, Daud NZA, Mahadi AH, Kusrini E, Usman A. Insight into the adsorption kinetics, mechanism, and thermodynamics of methylene blue from aqueous solution onto pectinalginate-titania composite microparticles. SN Applied Sciences. 2021; 3: 1–16.
• 36. Gupta SS, Bhattacharyya KG. Adsorption of Ni (II) on clays. Journal of colloid and interface science. 2006; 295(1): 21–32.
• 37. Wu F-C, Tseng R-L, Juang R-S. Characteristics of Elovich equation used for the analysis of adsorption kinetics in dye-chitosan systems. Chemical Engineering Journal. 2009; 150(2–3): 366–373.
• 38. Wang L, Zhang J, Zhao R, Li Y, Li C, Zhang C. Adsorption of Pb (II) on activated carbon prepared from Polygonum orientale Linn.: kinetics, isotherms, pH, and ionic strength studies. Bioresource technology. 2010; 101(15): 5808–5814.
• 39. Hamdaoui O, Saoudi F, Chiha M, Naffrechoux E. Sorption of malachite green by a novel sorbent, dead leaves of plane tree: Equilibrium and kinetic modeling. Chemical engineering journal. 2008; 143(1–3): 73–84.
• 40. Largitte L, Pasquier R. A review of the kinetics adsorption models and their application to the adsorption of lead by an activated carbon. Chemical engineering research and design. 2016;109:495-504.
• 41. Chutkowski M, Petrus R, Warchol J, Koszelnik P. Sorption equilibrium in processes of metal ion removal from environment. Statistical verification of mathematical models. Przemysl Chemiczny. 2008; 87(5): 436–438.
• 42. Ho Y-S, Chiu W-T, Hsu C-S, Huang C-T. Sorption of lead ions from aqueous solution using tree fern as a sorbent. Hydrometallurgy. 2004;73(1-2):55-61.
• 43. Ho Y-S, McKay G. Pseudo-second order model for sorption processes. Process biochemistry. 1999; 34(5): 451–65.
• 44. Bus A. Assessment of sorption properties and kinetic reaction of phosphorus reactive material to limit diffuse pollution. Annals of Warsaw University of Life Sciences-SGGW Land Reclamation. 2017; 49(3).
• 45. Eljamal O, Okawauchi J, Hiramatsu K, Harada M. Phosphorus sorption from aqueous solution using natural materials. Environmental earth sciences. 2013; 68: 859–863.
• 46. Osama E, Junya O, Kazuaki H. Removal of phosphorus from water using marble dust as sorbent material. Journal of Environmental Protection. 2012; 2012.
• 47. Riahi K, Chaabane S, Thayer BB. A kinetic modeling study of phosphate adsorption onto Phoenix dactylifera L. date palm fibers in batch mode. Journal of Saudi Chemical Society. 2017;21:S143-S52.
• 48. Özacar M. Equilibrium and kinetic modelling of adsorption of phosphorus on calcined alunite. Adsorption. 2003; 9: 125–132.
• 49. Letshwenyo MW, Mokokwe G. Phosphorus and sulphates removal from wastewater using copper smelter slag washed with acid. SN Applied Sciences. 2021; 3: 1–18.
• 50. Guo H, Qin Q, Chang J-S, Lee D-J. Modified alginate materials for wastewater treatment: Application prospects. Bioresource Technology. 2023;387:129639.
• 51. Gao X, Guo C, Hao J, Zhao Z, Long H, Li M. Adsorption of heavy metal ions by sodium alginate based adsorbent-a review and new perspectives. Int J Biol Macromol. 2020; 164: 4423–4434.
• 52. Fu L, Li J, Wang G, Luan Y, Dai W. Adsorption behavior of organic pollutants on microplastics. Ecotoxicol Environ Saf. 2021; 217: 112207.
• 53. Brogowski Z, Renman G. Characterization of opoka as a basis for its use in wastewater treatment. Polish Journal of Environmental Studies. 2004; 13(1): 15–20.
• 54. Cucarella V, Zaleski T, Mazurek R. Phosphorus sorption capacity of different types of opoka. Annals of Warsaw University of Life Sciences-SGGW Land Reclamation. 2007(38): 11–18.
• 55. Johansson L. Industrial by-products and natural substrata as phosphorus sorbents. Environmental technology. 1999; 20(3): 309–316.
• 56. Nilsson C. Phosphorus removal in reactive filter materials: factors affecting the sorption capacity: KTH Royal Institute of Technology; 2012.
• 57. Jóźwiakowski K. Experiment of increasing effectiveness of phosphorus removal in a model of wastewater treatment plant. Agricultural Engineering. 2006; 10(5)(80): 249–56. (in Polish)
• 58. Johansson L, Hylander L. Phosphorus removal from waste water by filter media: Retention and estimated plant availability of sorbed phosphorus. Problematic Notebooks of the Progress of Agricultural Sciences. 1998;458.
• 59. López-Luna J, Ramírez-Montes LE, Martinez-Vargas S, Martínez AI, Mijangos-Ricardez OF, González-Chávez MdCA, et al. Linear and nonlinear kinetic and isotherm adsorption models for arsenic removal by manganese ferrite nanoparticles. SN Applied Sciences. 2019; 1: 1–19.
• 60. Ho Y-S. Review of second-order models for ad006;136(3): 681–689.
• 61. Dada A.O, Adekola F.A, Odebunmi E.O, Ogunlaja AS, Bello OS. Two–three parameters isotherm modeling, kinetics with statistical validity, desorption and thermodynamic studies of adsorption of Cu (II) ions onto zerovalent iron nanoparticles. Scientific reports. 2021; 11(1): 16454.
• 62. Jucherski A, Nastawny M, Walczowski A, Jóźwiakowski K, Gajewska M. Testing the suitability of alkaline filter materials for phosphate removal from biologically treated domestic wastewater. Environmental Protection. 2017; 39(1). (in Polish)
• 63. Westholm LJ. Substrates for phosphorus removal— Potential benefits for on-site wastewater treatment? Water research. 2006; 40(1): 23–36.
• 64. Cucarella V, Renman G. Phosphorus sorption capacity of filter materials used for on‐site wastewater treatment determined in batch experiments–a comparative study. Journal of environmental quality. 2009; 38(2): 381–392.sorption systems. Journal of hazardous materials.

Uwagi

Opracowanie rekordu ze środków MNiSW, umowa nr POPUL/SP/0154/2024/02 w ramach programu "Społeczna odpowiedzialność nauki II" - moduł: Popularyzacja nauki (2025).