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Estimation of emulsified and dissolved oil content in seawater

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Języki publikacji
EN
Abstrakty
EN
The demand to control the amount of oil discharged to the seawater is the consequence of increasing shipping activities. Oil products enter marine environment on daily basis in the form of fuels, engine oils or crude oils. Each of them have a significant impact on marine life and the coastal water management. Oil content influences many environmental factors, like water quality and bio-optical parameters (e.g. water-leaving radiance, inherent optical properties, seawater fluorescence). It should be measured on regular basis to avoid over or underestimation of those parameters. Currently there are several methods used to estimate the total hydrocarbon content in seawater, mostly based on fluorescence measurements. We present a unique method suitable to determine the concentration of oil products in two forms: the amount of dissolved oil and the amount of oil-in-water emulsion. The method consist of several steps: seawater sampling, vacuum filtering, extracting of oil in n-hexane, fluorescence measurements and calculation of oil concentration in comparison to the reference samples, i.e. the solutions of different types of crude oil in n-hexane. The results have been measured for the samples collected in Southern Baltic Sea during several ship cruises in 2012. We discuss the advantages and disadvantages of presented method in the context of radiative transfer modelling and potential remote detection of dispersed oil.
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autor
  • Gdynia Maritime University Faculty of Marine Engineering Morska Street 81-87, 81-225 Gdynia, Poland tel.: +48 58 6901504, fax: +48 58 6901399
autor
  • Gdynia Maritime University Faculty of Marine Engineering Morska Street 81-87, 81-225 Gdynia, Poland tel.: +48 58 6901504, fax: +48 58 6901399
Bibliografia
  • [1] Drozdowska, V., Analysis of variability of surface waters fluorescence spectra using lidar method (in Polish), Ph. D. thesis, Inst. Oceanol. PAS, Sopot 2005.
  • [2] Frank, U., Jeleniewski, H., A Method For Quantitating Oil Directly In Water By Fluorescence Spectrophotometry, Epa Anal. Qc Newsletter, 18, 1973.
  • [3] GESAMP (Joint Group of Experts on the Scientific Aspects of Marine Pollution), Impact of oil and related chemicals and wastes on the marine environment, Reports and Studies, 50, 1993.
  • [4] GESAMP, Estimates of oil entering the marine environment from sea-based activities, Reports and Studies, 75, 2007.
  • [5] GMOPIG (Global Marine Oil Pollution Information Gateway), http://oils.gpa.unep.org/.
  • [6] HELCOM (Helsinki Commission, Baltic Marine Environment Protection Commission), http://www.helcom.fi/, 2011.
  • [7] Hornig, A. W., Identification, Estimation And Monitoring Of Petroleum In Marine Waters By Luminescence Methods, Proc. Nbs Symp., Nbs Spec. Publ., 409, 135-137, 1974.
  • [8] International Convention for the Prevention of Pollution from Ships MARPOL 73/78, IMO (International Maritime Organization), Polish Ship Register, Gdańsk 1997.
  • [9] Jha, M. N., Levy, J., Gao, Y., Advances in Remote Sensing for Oil Spill Disaster Management:State-of-the-Art Sensors Technology for Oil Spill Surveillance, Sensors, 8, pp. 236-255, 2008.
  • [10] Keizer, P. D., Gordon, D. C., Detection Of Trace Amounts Of Oil In Sea Water By Fluorescence Spectroscopy, J. Fish. Res. Board Can., 30, 1039-1046, 1973.
  • [11] Migliaccio, M., Gambardella, A., Tranfaglia, M., Sar Polarimetry To Observe Oil Spills, Ieee Trans. Geosci. Remote. Sens., 43 (2), 506-511, 2007.
  • [12] Robbe, N., Zielinski, O., Airborne remote sensing of oil spills- analysis and fusion of multispectral near-range data, J. Mar. Sci. Environ., C2, 19-27, 2004.
  • [13] Rudź, K., Baszanowska, E., Rohde, P., Zielinski, O., Fluorescence Methods and Monte Carlo Radiative Transfer Simulation Applied to Oil Detection in Baltic Sea, Joint Proceedings, 24, Bremerhaven 2011.
  • [14] Rudź, K., Darecki, M., Toczek, H., Modelling of Seawater Polluted by Light and Heavy Crude Oil Droplets, Journal of KONES Powertrain and Transport, Vol. 19, No. 2, pp. 473-480, Warsaw 2012.
  • [15] Rudź, K., Emulsified Fuels of Machine Origin in Seawater – a Contribute to Remote Detection, Journal of KONES Powertrain and Transport, 18(3), Warsaw 2011.
  • [16] Rudź, K., Modelling of Seawater Polluted by Light and Heavy Crude Oil Droplets, Journal of Polish CIMAC, Vol. 7, No. 1, Warsaw 2012.
  • [17] Stelmaszewski, A., The contribution of fluorescence to measurements of light scattering in oil-in-water emulsions, Oceanologia 53 (2), pp. 549-564, 2011.
  • [18] Stelmaszewski, A., Determination of petroleum pollutants in coastal waters of the Gulf of Gdansk, Oceanologia, 51(1), 85-92, 2009.
  • [19] Stelmaszewski, A., Fluorescence method for determination of oil identity, Optica Appl., XXXIV (3), 2004.
  • [20] Zielinski, O., Dittmar, T., Rohde, P., Ungermann, R., Voss, D., CDOM and PAHs in the Marine Environment - in situ Sensing with Time Resolved Fluorescence and Liquid Core Waveguides, Ocean Optics XX, Anchorage 2010.
  • [21] Zielinski, O., Hengstermann, T., Robbe, N., Detection Of Oil Spills By Airborne Sensors, in: Marine Surface Films, edited by: Gade, M., Huehnerfuss, H., Korenowski, G. M., Springer, 255-271, 2006.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-87f7cbff-43aa-45f5-8e54-02271b22dfc5
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