A new porphyrin sensitizer with phenolic binding group for high efficiency dye-sensitized solar cells

• Autorzy: Jin L. , Wang H. , Wang S. , Wen L. , Zhai J. , Wei T.

Identyfikatory

DOI

10.2478/s13536-014-0230-0

• Języki publikacji: EN

Abstrakty

EN

A novel zinc porphyrin (5,10,15-tri-dodecoxyphenyl-20-(4-hydroxyphenyl-azo-benzenyl)-porphyrinatozinc (tdhab-ZnP)) with benzenyl-azo-phenolic group, able to adsorb on the nanocrystalline-TiO2 film, has been synthesized. We constructed a dye-sensitized solar cell based on the nanocrystalline-TiO2 hierarchical structure film, with a power conversion efficiency of 4.15 % and a high current density of 14 mA/cm2 under AM 1.5 irradiation. UV-Vis absorption spectra measurements indicated that the tdhab-ZnP molecules formed a charge transfer complex with TiO2 nanoparticles (NPs) through the phenolic group. Cyclic voltammetry measurement showed that the charge separation resulting from the tdhab-ZnP excited singlet state to the conduction band (CB) of TiO2 and charge shifting from the I−/I−3 couple to the porphyrin radical cation were thermodynamically feasible.

Słowa kluczowe

EN

dye-sensitized solar cell; porphyrin; nanocrystalline TiO2

• Wydawca: De Gruyter
• Czasopismo: Materials Science Poland
• Rocznik: 2014
• Tom: Vol. 32, No. 4
• Strony: 610--616
• Opis fizyczny: Bibliogr. 29 poz., rys., wykr., tab.

Twórcy

autor

Jin L.

• The School of Material Science & Engineering, Harbin University of Science and Technology, Harbin 150040, P. R. China

autor

Wang H.

• The School of Material Science & Engineering, Harbin University of Science and Technology, Harbin 150040, P. R. China

autor

Wang S.

• The School of Material Science & Engineering, Harbin University of Science and Technology, Harbin 150040, P. R. China

autor

Wen L.

• Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China

autor

Zhai J.

• Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, School of Chemistry and Environment, Beihang University, Beijing 100191, P. R. China

autor

Wei T.

• Institute for Chemical Physics, Beijing Institute of Technology, Beijing, 100081, P. R. China

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