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Abstrakty
In the present work, a new organic second order NLO material: L-isoleucinium p-toluenesulfonate monohydrate (LIPT) is synthesized and reported for the first time. The LIPT is crystallized in a non-centrosymmetric monoclinic space group P21. Structural and hydrogen bond nature of the compound is analyzed using single crystal X-ray diffraction studies. The crystal exhibits very good optical properties such as wide optical transparency in the region of 210 nm to 1100 nm and the ultraviolet wavelength emission (λ = 283 nm). The second harmonic generation efficiency is found to be 1.7 times the standard KDP. Good thermal, mechanical properties and low dielectric constant at high frequency range show that the material may be a potential candidate for optoelectronic applications.
Słowa kluczowe
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Czasopismo
Rocznik
Tom
Strony
196--205
Opis fizyczny
Bibliogr. 29 poz., rys., tab.
Twórcy
autor
- Department of Physics,Er. Perumal Manimekalai College of Engineering, Hosur, Tamil Nadu-635117, India
autor
- Department of Physics, Kalasalingam Academy of Research and Education, Krishnankoil, Tamil Nadu - 626 190, India
autor
- Department of Physics, University College of Engineering, Anna University Constituent College, Nagercoil, Tamil Nadu - 629 004, India
Bibliografia
- [1] Gunter P., Nonlinear Optical Effects and Materials, Springer-Verlag, Berlin, Germany, 2000.
- [2] Zyss J., Molecular Nonlinear Optics: Materials, Physics, Devices, Academic Press, New York, 1994.
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- [4] Datta A., Pati S.K., J. Phys. Chem. A., 108 (2004), 320.
- [5] Suresh M., Asath Bahadur S., Athimoolam S., Optik., 126, (2015), 5452
- [6] Suresh M., Asath Bahadur S., Athimoolam S., J. Mater. Sci. Mater. El., 27(5), (2016), 4578.
- [7] Suresh M., Asath Bahadur S., Athimoolam S., J. Mol. Struct., 1112 (2016), 71.
- [8] Suresh M., Asath Bahadur S., Athimoolam S., J. Mater. Sci. Mater. El., 28(1), (2017), 661.
- [9] Yu Jin., Acta Cryst. E, 68 (2012), o1648
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- [11] Selvakumar E., Anandha Babu G., Ramasamy P., Rajnikant Uma Devi T., Meenakshi R., Chandramohan A., Spectrochim. Acta Part A, 125 (2014), 114.
- [12] Peramaiyan G., Mohankumar R., Bhagavannarayana G., J. Cryst. Growth, 408 (2014), 14.
- [13] Rekha P., Peramaiyan G., Nizammohideen M., Mohan Kumar R., Kanagadurai R., Spectrochimi. Acta Part A, 139 (2015), 302.
- [14] Ramasamy G., Meenakshisundaram S., Optik, 125 (2014), 4422.
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- [23] Spreiter R., Bosshard C.H., Pan F., Gunter P., Opt. Lett., 22(8) (1997), 564.
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Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-87b0ca83-3de8-421e-b308-5cde7a04d152