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Ba0.85(La,Y)0.15Fe12O19 hexaferrite magnets were produced using the powder metallurgy method. The phase analysis of the ferrite magnets was carried out by X-ray diffraction (XRD) technique. A single hexaferrite phase was present in both samples as revealed by XRD patterns. The microstructural evolution in the hexaferrite samples was examined using Scanning Electron Microscopy (SEM) equipped with Energy Dispersive X-Ray Spectroscopy (EDS). The grain morphology altered with the sintering temperature. Room temperature ferrimagnetic hysteresis curves were obtained by Vibrating Sample Magnetometer (VSM). The crystallite size and the lattice parameters (a,c) were also calculated after sintering at 1150ºC and 1250ºC. Saturation magnetizations, Ms were determined to be 48.60 emu/g and 52.95 emu/g for the samples sintered at 1150ºC and 1250ºC, respectively whereas the remanent magnetizations, Mr were 29.26 emu/g and 31.17 emu/g. The coercivity, Hc decreased from 3.95 kOe to the value of 2.44 kOe with the sintering temperature due to the increase of the crystallite size. The squareness ratios (Mr/Ms) of the ferrimagnetic samples were different because the uniaxial anisotropies altered after sintering at 1150ºC and 1250ºC. The maximum energy product, (BH)max dropped from 35.81 kJ/m3 to 27.38 kJ/m3 when the sintering temperature increased. This result can be attributed to a combination of higher magnetization and the lower coercivity.
Wydawca
Czasopismo
Rocznik
Strony
23--35
Opis fizyczny
Bibliogr. 57 poz., rys., tab.
Twórcy
autor
- Nişantaşı University, Department of Mechanical Engineering, 34398-Istanbul, Turkey
autor
- Nişantaşı University, Department of Mechatronics Engineering, 34398 -Istanbul, Turkey
autor
- Nişantaşı University, Department of Genetics and Bioengineering, 34398-Istanbul, Turkey
autor
- Eskişehir Technical University, Department of Materials Science and Engineering, 26555- Eskişehir, Turkey
Bibliografia
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- 23. Serletis C., Litsardakis G., Pavlidou E., Efthimiadis K.G.: Magnetic properties of co-precipitated hexaferrite powders with Sm-Co substitutions optimized with the molten flux method. Physica B: Condensed Matter, (2017), 52515, 78-83.
- 24. Satyapal H.K., Singh R.K., Kumar N., Sharma S.: Low temperature synthesis and influence of rare earth Nd3+ substitution on the structural, magnetic behaviour of M-type barium hexaferrite nanomaterials. Materials Today: Proceedings, 2020.
- 25. Verma S., Pandey O.P., Paesano A., Sharma P.: Comparison of structural and magnetic properties of La3+ substituted BaFe12O19 prepared by different substitution methods. Physica B: Condensed Matter, (2014), 4481, 57-59.
- 26. Almessiere M.A., Slimani Y., Guner S., Aldakhil S., Baykal A.: Ultrasonic synthesis, magnetic and optical characterization of Tm3+ and Tb3+ ions co-doped barium nanohexaferrites. Journal of Solid State Chemistry, (2020), 286, 121310.
- 27. Almessiere M.A., Slimani Y.A., Korkmaz D., Baykal A., Ercan I.: A study on the spectral, microstructural, and magnetic properties of Eu-Nd double-substituted Ba0.5Sr0.5Fe12O19 hexaferrites synthesized by an ultrasonic-assisted approach. Ultrasonics Sonochemistry, (2020), 62, 104847.
- 28. Shekhawat D., Singh A.K., Roy P.K.: Structural and electro-magnetic properties of high (BH)max La-Sm substituted Sr-hexaferrite for brushless DC electric motors application. Journal of Molecular Structure, (2019), 11795, 787-794.
- 29. Mohseni F., Pullar R.C., Vieira J.M., Amaral J.S.: Enhancement of maximum energy product in exchange-coupled BaFe12O19/Fe3O4 core-shell-like nanocomposites. Journal of Alloys and Compounds, (2019), 80625, 120-126.
- 30. Mahmood S., Aloqaily A., Maswadeh Y., Awadallah A., Bsoul I., Juwhari H.: Structural and magnetic properties of mo-zn substituted (BaFe12-4xMoxZn3xO19) M-type hexaferrites. Material Science Research India, (2014), 11, 09-20.
- 31. Awadallah A., Mahmood S., Maswadeh Y., Bsoul I., Awawdeh Q., Mohaidat H., Juwhari H.: Structural, magnetic, and Mossbauer spectroscopy of Cu substituted M-type hexaferrites. Materials Research Bulletin, (2016), 74, 192-201.
- 32. Kang Y.M., Kwon Y.H., Kim M.H., Lee D.Y.: Enhancement of magnetic properties in Mn-Zn substituted M-type Sr-hexaferrites. Journal of Magnetism and Magnetic Materials, (2015), 382, 10-14.
- 33. Joshi R., Singh C., Kaur D., Zaki H., Ghimire M.: Structural and magnetic properties of Co2+-W4+ ions doped M-type Ba-Sr hexaferrites synthesized by a ceramic method. Journal of Alloys and Compounds, (2017), 695, 909-914.
- 34. Singh J., Singh C., Kaur D., Zaki H., Meena S.S.: Elucidation of phase evolution, microstructural, Mössbauer and magnetic properties of Co2+-Al3+ doped M-type BaSr hexaferrites synthesized by a ceramic method. Journal of Alloys and Compounds, (2017), 695, 1112-1121.
- 35. Din M.F., Ahmad I., Ahmad M., Farid M.T., Iqbal M.A., Murtaza G., Khan M.A.: Influence of Cd substitution on structural, electrical and magnetic properties of M-type barium hexaferrites co-precipitated nanomaterials. Journal of Alloys and Compounds, (2014), 584, 646-651.
- 36. Mosleh Z., Kameli P., Poorbaferani A., Ranjbar M., Salamati H.: Structural, magnetic and microwave absorption properties of Ce-doped barium hexaferrite. Journal of Magnetism and Magnetic Materials, (2016), 397, 101-107.
- 37. Jamalian M.: An investigation of structural, magnetic and microwave properties of strontium hexaferrite nanoparticles prepared by a sol-gel process with doping Sn and Tb. Journal of Magnetism and Magnetic Materials, (2015), 378, 217-220.
- 38. Kaur P., Chawla S.K., Meena S.S., Yusuf S.M., Bindra Narang S.: Synthesis of Co-Zr doped nanocrystalline strontium hexaferrites by sol-gel auto-combustion route using sucrose as fuel and study of their structural, magnetic and electrical properties. Ceramics International, (2016), 42(13), 14475-14489.
- 39. Kaur P., Chawla S.K., Bindra Narang S., Pubby K.: Structural, magnetic and microwave absorption behavior of Co-Zr substituted strontium hexaferrites prepared using tartaric acid fuel for electromagnetic interference suppression. Journal of Magnetism and Magnetic Materials, (2017), 422, 304-314.
- 40. Kaur P., Chawla S.K., Meena S.S., Yusuf S.M., Bindra Narang S.: Modulation of physico-chemical, magnetic, microwave and electromagnetic properties of nanocrystalline strontium hexaferrite by Co-Zr doping synthesized using citrate precursor sol-gel method. Ceramics International, (2017), 43(1), 590-598.
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- 42. Speakman S.A.: Estimating Crystallite Size Using XRD. The MIT Materials Research Science and Engineering Center (MRSEC), 2019.
- 43. Rahimi F., Rahmati A., Mardani S.: Determination and analysis of structural and optical properties for thermally evaporated ZnO thin films. Soft Nanoscience Letters, (2014), 4(01), 1-5.
- 44. Sardjono P., Suprapedi S., Muljadi M., Djauhari N.R.: Microstructure, physical properties, and magnetic flux density analysis of permanent magnet BaFe12O19 using milling and sintering preparation methods. Journal of Physics: Conference Series, (2016), 739(1), 1-6.
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- 46. Davarpanah A.M., Rahdar A., Azizi Dastnae M., Zeybek O., Beyzaei H.: (1-x)BaFe12O19/xCoFe2O4 hard/soft magnetic nanocomposites: Synthesis, physical characterization and antibacterial activities study. Journal of Molecular Structure, (2019), 1175, 445-449.
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- 53. Mahmood S.H., Abu-Aljarayesh I.: Hexaferrite Permanent Magnetic Materials. Materials Research Forum LLC, 2016.
- 54. Rusianto T., Waziz Wildan M., Abraha K., Kusmono K.: The magnetic and mechanical properties of sintered ceramic magnets SrxBa1-xFe12O19. Ijet-Ijens, (2015), 15(05), 41-45.
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- 56. Li L., Zhang Z., Xie Y., Zhao J.: Preparation, characterization and magnetic properties of the BaFe12O19-chitosan composites. Solid State Sciences, (2016), 57, 44-48.
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Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2021).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-87aaa10b-1671-47a6-98a5-d6f5a888cc52