Investigation of new potential amine activators for carbon dioxide absorption in carbonate solutions

• Autorzy: Bińczak G. , Pohorecki R. , Moniuk W. , Możeński C

Identyfikatory

DOI

10.24425/122956

• Języki publikacji: EN

Abstrakty

EN

Results of an extensive research program, aimed at finding new, more efficient activators of carbon dioxide absorption into aqueous carbonate/bicarbonate solutions are presented. Both single amines (2-ethyl-aminoethanol, 2-isopropyl aminoethanol, piperazine, tetraethylenepentamine, N-ethyl-piperazine and glicyne) and amine mixtures have been investigated. Absorption rate measurements were conducted in a laminar-jet absorber. Reaction rate constants for the particular activators were determined. Mixtures of aliphatic amines with cyclic amines, as well as mixtures of cyclic amines with cyclic amines were found to exhibit synergetic effect. Such amine mixtures might be used as new promoters for CO2 absorption in carbonate solutions in the modified Benfield process.

Słowa kluczowe

EN

carbon dioxide; absorption; potassium carbonates; amine activators; laminar jet

PL

dwutlenek węgla; wchłanianie; węglan potasu; aktywator aminowy; strumień laminarny

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering
• Rocznik: 2018
• Tom: Vol. 39, nr 4
• Strony: 353--–365
• Opis fizyczny: Bibliogr. 39 poz.

Twórcy

autor

Bińczak G.

• New Chemical Syntheses Institute, Tysiąclecia PP 13a, 24-110 Puławy, Poland
• Grupa Azoty Nitrogen Works PUŁAWY S.A., Tysiąclecia PP 13, 24-110 Puławy, Poland

autor

Pohorecki R.

• Warsaw University of Technology, Faculty of Chemical and Process Engineering, Waryńskiego 1, 00-645 Warsaw, Poland

autor

Moniuk W.

• Warsaw University of Technology, Faculty of Chemical and Process Engineering, Waryńskiego 1, 00-645 Warsaw, Poland

autor

Możeński C

• New Chemical Syntheses Institute, Tysiąclecia PP 13a, 24-110 Puławy, Poland

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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).