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Tytuł artykułu

Evaluation of Degradation Efficiency of 2’-Ethylhexyl 4-(Dimethylamino)Benzoate under the Influence of Oxidizing Agents

Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The aim of the studies was to evaluate the effect of oxidizing agents on the degradation of 2-ethylhexyl 4-(dimethylamino)benzoate (ODPABA). The oxidation reaction was carried out in the presence of oxidizing agents used for disinfection of water and treatment of sewage containing organic pollutants. Oxidants, such as: sodium hypochlorite, hydrogen peroxide or ozone with UV radiation were applied. ODPABA degradation and analysis of products were performed using a gas chromatograph coupled with mass spectrometry detector. The use of sodium hypochlorite and UV radiation proved to be the most effective solutions. As a result, halogenoorganic products are formed. It is likely that the resulting by-products can be more toxic than the initial substrate. In the case of ozone and hydrogen peroxide, it was shown that these agents are characterized by weaker oxidative activity and therefore, fewer metabolites are formed.
Słowa kluczowe
Rocznik
Strony
236--241
Opis fizyczny
Bibliogr. 26 poz., rys., tab.
Twórcy
  • Faculty of Chemical Technology and Engineering, UTP University of Science and Technology, Seminaryjna 3, 85-326 Bydgoszcz, Poland
autor
  • Faculty of Chemical Technology and Engineering, UTP University of Science and Technology, Seminaryjna 3, 85-326 Bydgoszcz, Poland
Bibliografia
  • 1. Bedner M. and MacCrehan W.A. 2006. Transformation of acetaminophen by chlorination produces the toxicants 1,4-benzoquinone and N-acetyl-pbenzoquinone imine. Environ. Sci. Technol., 40(2), 516-522.
  • 2. Díaz-Cruz M.S., Gago-Ferrero P., Liorca M., Barceló D. 2012. Analysis of UV filters in tap water and other clean waters in Spain. Anal. Bioanal. Chem., 402(7), 2325-2333.
  • 3. Díaz-Cruz M.S., Liorca M., Barceló D. 2008. Organic UV filters and their photodegradates, metabolites and disinfection by-products in the aquat ics environment. Trends Analyt. Chem., 27 (10), 873-887.
  • 4. Dirtu A.C., Ede N., Malarvannan G., Ionas A.C., Covaci A. 2012. Analytical methods for selected emerging contaminants in human matrices – a review. Anal. Bioanal. Chem., 404(9), 2555-2581.
  • 5. Emri G., Schaefer D., Held B. 2004. Low concentrations of formaldehyde induce DNA damage and delay DNA repair after UV irradiation in human skin cells. Exp. Dermatol., 13(5), 305-315.
  • 6. Farré La Marinenel., Pérez S., Kantiani L., Barceló D. 2008. Fate and toxicity of emerging pollutants, their metabolites and transformation products in the aquatic environment. Trends Analyt. Chem., 27(11), 991-1007.
  • 7. Gackowska A., Przybyłek M., Studziński W., Gaca J. 2014. Experimental and theoretical studies on the photodegradation of 2-ethylhexyl 4-methoxycinnamate in the presence of reactive oxygen and chlorine species. Cent. Eur. J. of Chem., 12(5), 612-623.
  • 8. Gackowska A., Studziński W., Gaca J. 2016. Effect of sodium hypochlorite on conversions of octyldimethyl-para -aminobenzoic acid. Desalin. Water Treat., 57(3), 1429-1435.
  • 9. Gago-Ferrero P., Demeestere K., Silvia Díaz-Cruz M., Barceló D. 2013. Ozonation and peroxone oxidation of benzophenone-3 in water: effect of operational parameters and identification of intermediate products. Sci. Total. Environ. 443, 209-217.
  • 10. Giokas D.L., Salvador A., Chisvert A. 2007. UV filters: From sunscreens to human body and the environment. Trends Anal. Chem., 26(5), 360-374.
  • 11. Gomez E., Bachelot M., Boillot C., Munaron D., Chiron S., Casellas C., Fenet H. 2012. Bioconcentration of two pharmaceuticals (benzodiazepines) and two personal care products (UV filters) in marine mussels (Mytilus galloprovincialis) under controlled laboratory conditions. Environ Sci Pollut Res 19(7), 2561-2569.
  • 12. Hopkins Z.R., Snowberger S., Blaney L. 2017. Ozonation of the oxybenzone, octinoxate, and octocrylene UV-filters: Reaction kinetics, absorbance characteristics, and transformation products. J Hazard Mater., 338, 23-32.
  • 13. Kasih T.P. 2017. Investigation of the non-thermal plasma-based advanced oxidation process for removal of organic contaminants in azo dyes solution. J. Ecol. Eng. 18(2), 1-6.
  • 14. Krzemińska D., Neczaj E., Borowski G. 2015. Advanced oxidation processes for food industrial wastewater decontamination. J. Ecol. Eng., 16(2), 61-71.
  • 15. Kuśmierek K., Świątkowski A., Dąbek L. 2015. Oxidative degradation of 2-chlorophenol by persulfate. J. Ecol. Eng. 16(3), 115-123.
  • 16. Lee J., Ha K-T., Zoh K-D. 2009. Characteristics of trihalomethane (THM) production and associated health risk assessment in swimming pool waters treated with different disinfection methods. Sci Total Environ. 407(6), 1990-1997.
  • 17. Li W.H., Ma Y.M., Guo C.S., Hu W., Liu K.M., Wang Y.Q., Zhu T. 2007. Occurrence and behavior of four ofthe most used sunscreen UV filters in a wastewater reclamation plant. Water Res., 41(15), 3506-3512.
  • 18. Nakajima M., T. Kawakami T., Niino T., Takahashi Y. and Onodera S. 2009. Aquatic fate of sunscreen agents octyl-4-methoxycinnamate and octyl-4-dimethylaminobenzoate in model swimming pools and the mutagenic assays of their chlorination byproducts. J. Health Sci., 55(3), 363-372.
  • 19. Negreira N., Canosa P., Rodriguez I., Rubi R., Cele R. 2008. Study of some UV filters stability in chlorinated water and identification of halogenated byproducts by gas chromatography-mass spectrometry, J. Chromatogr. A 1178(1-2) 208-214.
  • 20. Przywara L., 2017. Alternative treatment strategy for different streams of tannery wastewater. J. Ecol. Eng. 18(4), 160-168.
  • 21. Sakkas V.A., Giokas D.A., Lambropoulou D.A. and Albanis T.A., 2003. Aqueous photolysis of the sunscreen agent octyl-dimethyl-p-aminobenzoic acid Formation of disinfection byproducts in chlorinated swimming pool water, J. Chromatogr. A, 1016(2), 211-222.
  • 22. Santos A. Joel M., Crista D.M.A., Miranda M.S., Almeida I.F., Sousa E Silva J.P., Costa P. C., Amaral M.H., Lobão A.L., Sousa Lobo J.M., Esteves Da Silva J.C.G. 2013. Degradation of UV filters 2-ethylhexyl-4-methoxycinnamate and 4-tert-butyl-4’-methoxydibenzoylmethane in chlorinated water. Csiro Publishing, 36(10), 1319-1326.
  • 23. Serpone N, Salinaro A, Emeline AV, Horikoshi S, Hidaka H., Zhao J. 2002. An in vitro systematic spectroscopic examination of the photostabilities of a random set of commercial sunscreen lotions and their chemical UVB/UVA active agents, Photochem Photobiol Sci., 1(12), 970-981.
  • 24. Studziński W., Gackowska A. 2017. Comparison of methods for ethylhexyl 4-methoxycinnamate acid ester oxidation in water medium. J. Ecol. Eng, 18(4), 204-210.
  • 25. Studziński W., Gackowska A., Przybyłek M., Gaca J. 2017b. Studies on the formation of formaldehyde during 2-ethylhexyl 4-(dimethylamino)benzoate demethylation in the presence of reactive oxygen and chlorine species. Environ. Sci. Pollut. Res, 24(9), 8049-8061.
  • 26. Zuloaga O., Navarro P., Bizkarguena E., Iparraguirre A., Vallejo A., Olivares M., Prieto A. 2012. Overview of extraction, clean-up and detection techniques for the determination of organic pollutants in sewage sluge: A review. Anal. Chim. Acta, 736, 7-29.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-86c141fb-cefd-45b6-95b0-deaafeeb28af
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