Microgravimetric Studies of Selenium Electrodeposition Onto Different Substrates

• Autorzy: Kowalik R.

Identyfikatory

DOI

10.2478/amm-2014-0147

Warianty tytułu

PL

Mikrograwimetryczna analiza procesu elektrochemicznego procesu osadzania selenu na różnych podłożach

• Języki publikacji: EN

Abstrakty

EN

The mechanism of selenium electrodeposition from sulfuric acid solution on different substrates was studied with the electrochemical techniques. The cyclic voltammetry was combined with the quartz crystal microbalance technique to analyze selenium deposition process. The electrochemical reduction of selenous acid on gold, silver and copper electrodes was investigated. It was found that reduction of selenous acid is a very complex process and it strongly depends from the applied substrate. The voltammetric measurements indicate the range of potentials in which the process of reduction of selenous acids on the applied substrate is possible. Additionally, the microgravimetric data confirm the deposition of selenium and they reveal the mechanism of the deposition process.

PL

Przedstawione w niniejszej pracy wyniki badań opisują mechanizm elektrochemicznego osadzania selenu z roztworów siarczanowych na różnych podłożach. W celu dokładnej analizy zachodzących procesów elektrodowych w badaniach zastosowano technikę cyklicznej woltamperometrii połączoną z elektrochemiczną mikrowagą kwarcową. W pracy porównano procesy redukcji kwasu selenowego(IV) na elektrodach złotej, srebrnej i miedzianej. Dzięki zastosowanym technikom badawczym jednoznacznie określono zakres osadzania się selenu na wybranych podłożach oraz wskazano możliwy mechanizm przebiegających reakcji elektrodowych.

Słowa kluczowe

EN

selenium; electrochemistry; electrodeposition; cyclic voltammetry; electrochemical quartz crystal microbalance

PL

selen; elektrochemia; elektroosadzanie; cykliczna woltamperometria; elektrochemiczna mikrowaga kwarcowa

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2014
• Tom: Vol. 59, iss. 3
• Strony: 871--877
• Opis fizyczny: Bibliogr. 75 poz., rys.

Twórcy

autor

Kowalik R.

• AGH University of Science and Technology, Faculty of Metals Engineering and Industrial Computer Science, Al. A. Mickiewicza 30, 30-059 Kraków, Poland

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