Determination of ascorbic acid using differential pulse voltammetry method on aniline-co-para–aminophenol modified electrode

• Autorzy: Parsa A. , Tajik M.

Identyfikatory

DOI

10.1515/pjct-2017-0038

• Języki publikacji: EN

Abstrakty

EN

The electro-synthesis of poly(aniline-co-para–aminophenol) on graphite electrode was examined using cyclic voltammetry (CV) over the potential window of −0.2 V to 1 V in phosphoric acid medium, which was comprised of potassium chloride and para–Toluene sulfonic acid (pTSA) as electrolyte support. Fourier transform infrared (FTIR) spectroscopy was employed to identify the electro-synthesized copolymer while impedance techniques were used to determine charge transfer resistance (Rct) in modified and unmodified electrodes. After this, the electro-catalytic effect of the modified electrode on ascorbic acid was examined using differential pulse voltammetry (DPV) and a very strong response was observed. A negative shift of about 0.33 V was found in the peak anodic potentials for ascorbic acid. Measurement using DPV indicated a proper response by the electrode to a wide range of ascorbic acid concentrations, from 0.0001 to 0.0004 M. The peak anodic currents for increased concentrations showed a proper linear range.

Słowa kluczowe

EN

polyaniline; para-aminophenol; ascorbic acid; differential pulse voltammetry

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2017
• Tom: Vol. 19, nr 2
• Strony: 125--129
• Opis fizyczny: Bibliogr. 45 poz., rys., tab.

Twórcy

autor

Parsa A.

• Department of Chemistry, College of Science, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran (Islamic Republic of Iran)

autor

Tajik M.

• Department of Chemistry, College of Science, Yadegar-e-Imam Khomeini (RAH) Shahre Rey Branch, Islamic Azad University, Tehran, Iran (Islamic Republic of Iran)

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Uwagi

Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017).