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Tytuł artykułu

Removal of silver from chloride solutions using new polymer materials

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
This work presents the synthesis of polymer resins with heterocyclic functional groups, that is, N-(3-aminopropyl)-2-pipecoline, N-(3-aminopropyl)-2-pyrrolidinone, and trans-1,4-diaminocyclohexane for the recovery of Ag(I) from chloride solutions. The modification yield was 69.2, 74.6 and 88.3%, respectively. The best Ag(I) sorption was achieved from synthetic and real chloride solutions in the case of trans-1,4-diaminocyclohexane resin (sorption was 26.8 and 21.5 mg/g, respectively). The sorption kinetic data were well fitted to the pseudo-first-order kinetic model. The maximum sorption capacity of Ag(I) is 105.4, 117.8 and 130.7 mg Ag(I)/g for N-(3-aminopropyl)-2-pipecoline resin, N-(3-aminopropyl)-2-pyrrolidinone resin and trans-1,4-diaminocyclohexane resin, respectively. The trans-1,4-diaminocyclohexane modified resin was very selective towards Ag(I) compared to Cu(II), Pb(II), and Zn(II) from the real chloride leaching solution. The N-(3-aminopropyl)-2-pipecoline and N-(3-aminopropyl)-2-pyrrolidinone resins showed high preferences for Ag(I) over Pb(II) in real solution. These results indicated that the polymers can be applied in the recovery of Ag(I).
Rocznik
Strony
art. no. 174357
Opis fizyczny
Bibliogr. 41 poz., rys., tab., wykr.
Twórcy
  • Depart. of Analytical Chemistry and Chemical Metallurgy, Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wroclaw, Poland
  • Depart. of Process Engineering and Technology of Polymeric and Carbon Materials, Faculty of Chemistry, Wroclaw University of Science and Technology, Wybrzeże Wyspiańskiego 27, 50-370 Wroclaw, Poland
Bibliografia
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Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-84db2624-6093-4192-8070-f7a6d5bcbf14
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