The Effect of Natural Silica from Rice Husk Ash and Nickel as a Catalyst on the Hydrogen Storage Properties of MgH2

• Autorzy: Malahayati , Yufita Evi , Ismail Ismail , Mursal Mursal , Idroes Rinaldi , Jalil Zulkarnain

Identyfikatory

DOI

10.12911/22998993/142959

• Języki publikacji: EN

Abstrakty

EN

The characteristics of MgH₂ as a hydrogen storage material in this study were observed by varying the composition of the catalyst. The added catalyst was a dual catalyst, namely nickel and natural silica extracted from rice husk ash with a composition of MgH₂ + 10 wt% SiO₂ + 10 wt% Ni (Sample A), then MgH₂ + 5 wt% SiO₂ + 10 wt% Ni (Sample B) , and MgH₂ + 10 wt% SiO₂ + 5 wt% Ni (sample C). The samples were prepared using the high energy ball milling (HEBM). The results showed that the natural silica extracted from rice husk ash (hereafter called “RHA“) can be used as a catalyst in MgH₂. Then, simultaneous use of nickel with silica as dual catalyst has shown the improvement in the hydrogen storage characteristics such as temperature and desorption time. The results of this study also indicate that the composition of the catalyst affects the particle size, although the time and milling treatment are the same. Furthermore, the particle size affects the characteristics of MgH₂ as a hydrogen storage material. Apart from particle size, there are other parameters that influence the characteristics of MgH₂, which appear during the sample preparation process such as impurity and agglomeration phases, all of which are closely related to the composition and type of catalyst used and the milling treatment applied to the sample. The 10 hours milling time used in this study has succeeded in reducing the sample to nano size. The Mg-based materials which have a nanostructure will have a larger contact area for the hydrogen reaction. The diffusion distance during the hydrogen absorption reaction also becomes smaller so as to improve the kinetic and thermodynamic characteristics of MgH₂.

Słowa kluczowe

EN

hydrogen storage; natural silica; rice husk ash; high energy ball milling; desorption temperature

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2021
• Tom: Vol. 22, nr 11
• Strony: 79--85
• Opis fizyczny: Bibliogr. 30 poz., rys., tab.

Twórcy

autor

Malahayati

• Graduate School of Mathematics and Applied Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia
• Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

autor

Yufita Evi

• Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

autor

Ismail Ismail

• Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

autor

Mursal Mursal

• Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

autor

Idroes Rinaldi

• Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

autor

Jalil Zulkarnain

• Department of Physics, Faculty of Mathematics and Natural Sciences, Universitas Syiah Kuala, Banda Aceh 23111, Indonesia

• https://orcid.org/0000-0003-2153-7045

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