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Tytuł artykułu

Plasticization of Submicron-Structured LOVA Propellants by a Linear Dinitramine

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Raman spectroscopy is a powerful tool for the analysis of complex energetic materials. In this work, this technique has been used to observe the inter-molecular interactions occurring in nitrocellulose-based propellants containing 1,3,5-trinitro-1,3,5-triazinane (RDX) and plasticized with 2,4-dinitro-2,4-diazahexane (DNDA6). The plasticization mechanism of nitrocellulose by DNDA6 was observed. RDX was found to be markedly uninvolved in chemical interactions in these matrices, hinting at a potential loss of stability in compositions for LOVA (LOw Vulnerability Ammunitions).
Słowa kluczowe
Rocznik
Strony
547--556
Opis fizyczny
Bibliogr. 17 poz., rys., tab.
Twórcy
autor
  • Nanomatériaux pour les Systèmes Sous Sollicitations Extrêmes (NS3E) Laboratory, UMR 3208 ISL-CNRS-UNISTRA, French-German Research Institute of Saint-Louis (ISL), 5 rue du Général Cassagnou, 68301 SAINT-LOUIS, France
autor
  • Nanomatériaux pour les Systèmes Sous Sollicitations Extrêmes (NS3E) Laboratory, UMR 3208 ISL-CNRS-UNISTRA, French-German Research Institute of Saint-Louis (ISL), 5 rue du Général Cassagnou, 68301 SAINT-LOUIS, France
Bibliografia
  • [1] Langlotz W., Diehl D., Mueller I.C.T., Propellant Powder for Barrelled Weapons, PCT, WO Patent 98/34891, 1998.
  • [2] Spitzer D., Wanders B., Schäfer M.R., Welter R., Molecular Structures of Seven Methylenedinitramines with Plasticising Abilities, J. Mol. Struct., 2003, 644, 37-48.
  • [3] Spitzer D., Braun S., Schäfer M.R., Ciszek F., Comparative Crystallization Study of Several Linear Dinitramines in Nitrocellulose-based Gels, Propellants Explos. Pyrotech., 2003, 28(2), 58-64.
  • [4] Fell Jr N.F., Vanderhoff J.A., Pesce-Rodrigez R.A., McNesby K.L., Characterization of Raman Spectral Changes in Energetic Materials and Propellants During Heating, J. Raman Spectrosc., 1998, 29, 165-172.
  • [5] Trewartha S., Shapter J., Gibson C.T., Mikajlo E., Jones A., Determination of Deterrent Profiles in Nitrocellulose Propellant Grains Using Confocal Raman Microscopy, Propellants Explos. Pyrotech., 2011, 36, 451-458.
  • [6] Infante-Castillo R., Pacheco-Londoño L.C., Hernández-Rivera S.P., Monitoring the α → β Solid-solid Phase Transition of RDX with Raman Spectroscopy: A Theoretical and Experimental Study, J. Mol. Struct., 2010, 970, 51-58.
  • [7] Moore D.S., McGrane S.D., Comparative Infrared and Raman Spectroscopy of Energetic Polymers, J. Mol. Struct., 2003, 661-662, 561-566.
  • [8] Kumari D., Yamajala D.B., Singh H., Sanghavi R.R., Asthana S.N., Raju K., Banerjee S., Application of Azido Esters as Energetic Plasticizers for LOVA Propellant Formulations, Propellants Explos. Pyrotech., 2013, 38, 805-809.
  • [9] Sanghavi R.R., Kamale P.J., Shaikh M.A.R., Shelar S.D., Sunil Kumar K., Singh A., HMX Based Enhanced Energy LOVA Gun Propellant, J. Hazard. Mater., 2007, 143, 532-534.
  • [10] Risse B., Hassler D., Spitzer D., Preparation of Nanoparticles by Flash Evaporation, WO Patent 2013117671A1, 2013.
  • [11] Risse B., Continuous Crystallization of Ultra-fine Energetic Particles by the Flash-Evaporation Process, PhD thesis, Université de Lorraine, Saint-Louis, 2012.
  • [12] Risse B., Schnell F., Spitzer D., Synthesis and Desensitization of Nano-β-HMX, Propellants Explos. Pyrotech., 2014, 39, 397-401.
  • [13] Risse B., Spitzer D., Hassler D., Schnell F., Comet M., Pichot V., Muhr H., Continuous Formation of Submicron Energetic Particles by the Flash-evaporation Technique, Chem. Eng. J., 2012, 203, 158-165.
  • [14] Spitzer D., Risse B., Schnell F., Pichot V., Klaumünzer M., Schaefer M.R., Continuous Engineering of Nano-cocrystals for Medical and Energetic Applications, Sci. Rep., 2014, 4, 6575.
  • [15] Kovalenko V.I., Mukhamadeeva R.M., Maklakova L.N., Gustova N.G., Interpretation of the IR Spectrum and Structure of Cellulose Nitrate, J. Struct. Chem., 1993, 34(4), 59-66.
  • [16] Socrates G., Infrared and Raman Characteristic Group Frequencies: Tables and Charts, 3rd ed., John Wiley & Sons, LTD, Chichester, 2004.
  • [17] Gill R.C., Nauflett G.W., New Plasticizer for Nitropolymers, Patent US 4 457 791, 1984.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-8331fa1e-a61b-4dbe-ac64-bc078c4a88dc
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