The Contribution of Electrochemistry for a Better Understanding of the Degradation by Tribocorrosion of Metallic Implant Materials

• Autorzy: Benea Lidia

Identyfikatory

DOI

10.24425/amm.2022.137789

• Języki publikacji: EN

Abstrakty

EN

In this paper there are presented some results obtained by open circuit potential and electrochemical impedance spectroscopy measurements from studies performed on the behavior of tribocorrosion on metallic implant biomaterials as: 304L stainless steel, Co/nano-CeO₂ nanocomposite layer and Ti6Al4V untreated and oxidized alloy to form a nanoporous TiO₂ film. The open circuit potential technique used in measuring the tribocorrosion process provide information on the active or passive behavior of the investigated metallic biomaterial in the biological fluid, before, during friction and after stopping the friction. Thus it clearly show a better behavior of Co/nano-CeO₂ nanocomposite coatings as compared with 304L stainless steel to tribocorrosion degradation in Hank solution; as well the better behavior of nanoporous TiO₂ film formed annodically on Ti6Al4V alloy surface as compared with untreated alloy to tribocorrosion degradation in artificial saliva Fusayama Meyer. The slight decrease in polarization resistance value resulted from electrochemical impedance spectroscopy measured during friction in the case of the Co/nano-CeO₂ nanocomposite layer (four times smaller), compared to 304L stainless steel, whose polarization resistance decreased more than 1000 times during friction shows the higher sensitivity of stainless steel to degradation by tribocorrosion. The same behavior is observed when comparing the polarization resistance of untreated titanium alloy recorded during friction that is about 200 hundred times smaller, while the specific polarization resistance of the oxidized alloy with the nanoporous film of titanium oxide, decreases very little during friction, highlighting the beneficial effect of modifying the titanium alloy by anodic oxidation to increase its resistance to the degradation process by tribocorrosion.

Słowa kluczowe

EN

tribocorrosion; biological fluids; biomaterials; nanocomposite layer; electrochemical methods

• Wydawca: Institute of Metallurgy and Materials Science of Polish Academy of Sciences ; Committee of Materials Engineering and Metallurgy of Polish Academy of Sciences
• Czasopismo: Archives of Metallurgy and Materials
• Rocznik: 2022
• Tom: Vol. 67, iss. 2
• Strony: 547--554
• Opis fizyczny: Bibliogr. 25 poz., rys., wzory

Twórcy

autor

Benea Lidia

• Dunarea de Jos University of Galati, Competences Centre: Interfaces-Tribocorrosion and Electrochemical Systems (CC-ITES), 47 Domneasca Street, RO-800008 Galati, Romania

• https://orcid.org/0000-0003-1551-3960

Bibliografia

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Uwagi

1. All the experimental work was performed at Competences Center Interfaces - Tribocorrosion and Electrochemical Systems (CC-ITES). The authors would like to express appreciation for Prof. Jean-Pierre Celis from Katholieke University of Leuven, Belgium and Prof. Pierre Ponthiaux from Ecole Centrale Paris, France for they valuable scientific advice.

2. Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).