Regularities of Crystallization Heat Release During Solidification of Alloyed Cast Irons

• Autorzy: Aftandiliants Y. , Gnyloskurenko S. , Meniailo H. , Khrychikov V. , Lomakin V.

Identyfikatory

DOI

10.24425/afe.2023.144286

• Języki publikacji: EN

Abstrakty

EN

The chemical composition of alloys plays an important role at their crystallization and influences the solid phase formation, and thus, microstructure and properties. The present paper studies the release of the heat of crystallization of alloyed wear-resistant cast irons in order to determine the quantitative patterns of the chemical composition influence to the kinetics of crystallization. The differential thermal analysis was applied to get the data of heat release, its rate at cast iron temperature decrease. The normalized dependence of the amount of crystallization heat over time was obtained. The main temperature parameters were analyzed and four stages at irons crystallization were established and characterized with their duration and released heat. The multiple correlation analysis allowed considering a numerous physical and chemical factors and distinguishing their role at crystallization of irons. As a result, the quantitative regularities are determined of influencing the content of alloying elements, impurities and carbides on a heat and time of crystallization at the different stages of solidification, which are of great importance in developing alloyed irons with required quality and properties.

Słowa kluczowe

EN

alloying; cast irons; crystallization; kinetics of crystallization; chemical composition

PL

stopowanie; żeliwo; krystalizacja; kinetyka krystalizacji; skład chemiczny; właściwości

• Wydawca: Komisja Odlewnictwa Polskiej Akademii Nauk Oddział w Katowicach
• Czasopismo: Archives of Foundry Engineering
• Rocznik: 2023
• Tom: Vol. 23, iss. 1
• Strony: 110--117
• Opis fizyczny: Bibliogr. 25 poz., il., tab., wykr.

Twórcy

autor

Aftandiliants Y.

• National University of Life and Environmental Sciences of Ukraine, Ukraine

• https://orcid.org/0000-0001-5864-9855

autor

Gnyloskurenko S.

• Physical and Technological Institute of Metals and Alloys, National Academy of Sciences of Ukraine, Ukraine
• National University of Life and Environmental Sciences of Ukraine, Ukraine

• https://orcid.org/0000-0003-0201-7191

autor

Meniailo H.

• Ukrainian State University of Science and Technologies, Ukraine

• https://orcid.org/0000-0002-6874-7202

autor

Khrychikov V.

• Ukrainian State University of Science and Technologies, Ukraine

autor

Lomakin V.

• Central Ukrainian National Technical University, Ukraine

Bibliografia

• [1] Girshovich, N.G. (1966). Crystallization and properties of cast iron in castings. M., L.: Mashinostroenie. (in Russian)
• [2] Khudokormov, D.P. (1968). The role of impurities in the process of graphitization of cast irons. Moscow: Science and technology.
• [3] Levi, L.I. & Nikitichin, A.M. (1973). On the influence of the hereditary properties of ferrosilicon on the structure and properties of cast iron in castings. Foundry production. 11, 23-25.
• [4] Chalmers, B. (1968). Theory of solidification. Trans. from English M.: Metallurgy.
• [5] Kan, R. (1968). Physical metallurgy. Vol. 3. Mir: Moscow.
• [6] Stefanescu, D.M. (2015). Thermal analysis - theory and applications in metalcasting. International Journal of Metalcasting. 9, 7-22. https://doi.org/10.1007/BF03355598.
• [7] Stefanescu, D.M., Suarez, R. & Kim, S.B. (2020). 90 years of thermal analysis as a control tool in the melting of cast iron. China Foundry. 17(2), 69-84. https://doi.org/10.1007/s41230-020-0039-x.
• [8] Ignaszak, Z., Popielarski, P. & Codina, E. (2015). Methodology of comparative validation of selected foundry simulation codes. Archives of Foundry Engineering. 15(4), 37-44. DOI: 10.1515/afe-2015-0076.
• [9] Bhat, M.N., Khan, D.M.A. & Singh, K.K. (2019). Thermal analysis and graphitization ability of spheroidal graphite cast iron preconditioned by Al,Zr,Ca-FeSi. International Journal of metal casting. 13(4), 928-936. DOI 10.1007/s40962-019- 00311-6.
• [10] Cojocaru, A.M., Riposan, I. & Stan, S. (2019). Solidification influence in the control of inoculation effects in ductile cast irons by thermal analysis. Journal of thermal analysis and calorimetry. 138(3), 2131-2143. https://doi.org/10.1007/ s10973-019-08808-2.
• [11] Stan, I., Anca, D., Stan, S., Riposan, I. (2021). Solidification pattern of Si-alloyed, inoculated ductile cast irons, evaluated by thermal analysis. Metals. 11(5), 846, 1-16. https://doi.org/10.3390/met11050846.
• [12] Dwulat, R., Janerka, K. & Grzesiak, K. (2021). The influence of final inoculation on the metallurgical quality of nodular cast iron. Archives of Foundry Engineering. 21(4), 5-14. DOI: 10.24425/afe.2021.138673.
• [13] Persson, P.E., Ignaszak, Z. & Kump, A. (2019). Increasing precision and yield in casting production by simulation of the solidification process based on realistic material data evaluated from thermal analysis (using the ATAS MetStar system). Archives of Foundry Engineering. 19(1), 117-126. DOI: 10.24425/afe.2019.127104.
• [14] Gulyaev, B.B. (1960). Foundry processes. Moscow: Mashgiz.
• [15] Shvedkov, E.L. (1975). Elementary mathematical statistics in experimental problems of materials science. Kyiv: Naukova Dumka. (in Russian)
• [16] Ono, A. (1980). Solidification of metals. M.: Metallurgy.
• [17] Hein, K., Buriga. E. (1987). Crystallization from melts. Handbook. M.: Metallurgy.
• [18] Morita, Z. & Tanaka, T. (1988). Thermodynamics and coefficients of equilibrium distribution of dissolved elements between solid and liquid phases in iron alloys. Tetsu to hagane. Transactions of the Iron and Steel Institute of. Japan. 74(7), 1210-1218.
• [19] Popel, S.I. (1971). Theory of metallurgical processes. M.: VINITI.
• [20] Arsentiev, P.P., Koledov, L.A. (1976). Metal melts and their properties. Moscow: Metallurgy.
• [21] Andronov, V.N., Chekin, B.V., Nesterenko, S.V. (1976). Liquid metals and slags. M.: Metallurgy.
• [22] Ershov, G.S., Bychkov, Yu.B. (1983). Properties of metallurgical melts and their interaction in steelmaking processes. M.: Metallurgy.
• [23] Garber, M.E. (1972). Castings from white wear-resistant cast irons. M.: Mashinostroenie.
• [24] Maratray, F. (1971). Memoires scientifiques de la revue de metallurgie. 68(2), 67-74
• [25] Tsypin, I.I. (1983). White wear-resistant cast irons. M.: Metallurgy.

Uwagi

Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023)