Permeability of P and K-nutrient through polystyrene membrane from aqueous solutions of urea + KH2PO4

• Autorzy: Deng X. , Liu K. , Han X. , Hu X. , Zheng S.

Identyfikatory

DOI

10.2478/pjct-2018-0063

• Języki publikacji: EN

Abstrakty

EN

With the polymer-coated fertilizer as background, the permeability of P- and K-nutrient through a representative polymer membrane-polystyrene membrane were investigated by measuring their permeability in the solutions of KH₂ PO₄ -water and urea-KH₂ PO₄ water at nominal temperature of 298 K using the Ussing chamber method. To analyze and interpret the variation of permeability with solute concentration, the solubility of permeate in polymer membrane were determined experimentally and the permeate diffusion coefficient were assessed by the measurements of density and apparent molar volume of the aqueous fertilizer solutions. An interesting “increase-decrease” trend for the permeability of both phosphorous (P)-nutrient, and potassium (K)-nutrient fertilizer with permeate concentration was observed, in which the increases in permeability at low concentrations of permeate could be attributed to the increase in solubility of KH₂ PO₄  in polymer while the decreases in permeability at high concentrations was due to the decrease in diffusion coefficient of permeate in polymer membrane. Finally, the release kinetics of these nutrients from a PS-coated urea-KH₂ PO₄  compound fertilizer granule was predicted using the Shaviv’s model along with the permeability data of P- and K-nutrient generated.

Słowa kluczowe

EN

Permeability; polymer membrane; aqueous fertilizer solution; polymer-coated fertilizer

• Wydawca: West Pomeranian University of Technology. Publishing House
• Czasopismo: Polish Journal of Chemical Technology
• Rocznik: 2018
• Tom: Vol. 20, nr 4
• Strony: 113--122
• Opis fizyczny: Bibliogr. 32 poz., rys., tab.

Twórcy

autor

Deng X.

• Hefei University of Technology, College of Mechanical Engineering, 193 Tunxi Road, Hefei, Anhui, China, 230009

autor

Liu K.

• Hefei University of Technology, College of Chemical Engineering and Chemical Technology, 193 Tunxi Road, Hefei, Anhui, China, 230009

autor

Han X.

• University of Technology, College of Chemical Engineering and Chemical Technology, 193 Tunxi Road, Hefei, Anhui, China, 230009

autor

Hu X.

• Hefei University of Technology, College of Mechanical Engineering, 193 Tunxi Road, Hefei, Anhui, China, 230009

autor

Zheng S.

• Cotton Research Institute of Anhui Academy of Agricultural Sciences, 40 Nongke Road, Hefei, Anhui, China, 230001

Bibliografia

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).