Hydrogen Peroxide Treated Desiccated Coconut Waste as a Biosorbent in Malachite Green Removal from Aqueous Solutions

• Autorzy: Hussin Shuhaila Mohd , Al-Amrani Waheeba Ahmed , Suah Faiz Bukhari Mohd , Harimu La , Hanafiah Megat Ahmad Kamal Megat

Identyfikatory

DOI

10.12911/22998993/182870

• Języki publikacji: EN

Abstrakty

EN

Malachite green (MG), commonly employed in the textile and dyeing sectors, is a prevalent and enduring contaminant found in wastewater and the environment. Its presence poses harmful effects to humans and aquatic organisms. This work utilised hydrogen peroxide‑treated desiccated coconut waste (HPDCW) to remove MG from an aqueous solution. The HPDCW underwent characterisation utilising FTIR, SEM-EDX, pH_slurry , and pH_pzc . Based on the results obtained, it was found that HPDCW recorded a biosorption capacity of 211.88 mg/g, attained at a temperature of 302 K, a pH of 9, a contact period of 5 min, and a dosage of 0.02 g. MG biosorption rates accurately followed the pseudo‑second‑order kinetic model, while the equilibrium data presented a step‑shaped isotherm model. The relatively small percentages of MG desorption observed when using distilled water and HCl (0.01 and 0.02 M) indicate that electrostatic interaction is one of the mechanisms responsible for the interaction between MG and HPDCW. There is also a possibility of the involvement of hydrogen bonding and π-π interactions.

Słowa kluczowe

EN

biosorption; desiccated coconut; isotherm; kinetic; malachite green

• Wydawca: Polskie Towarzystwo Inżynierii Ekologicznej ; Lublin University of Technology
• Czasopismo: Journal of Ecological Engineering
• Rocznik: 2024
• Tom: Vol. 25, nr 3
• Strony: 323--333
• Opis fizyczny: Bibliogr. 27 poz., rys., tab.

Twórcy

autor

Hussin Shuhaila Mohd

• Faculty of Applied Sciences, Universiti Teknologi MARA Pahang, 26400, Jengka, Pahang, Malaysia

• https://orcid.org/0009-0008-0641-7356

autor

Al-Amrani Waheeba Ahmed

• Department of Chemistry, College of Science, Ibb University, Ibb, Yemen

autor

Suah Faiz Bukhari Mohd

• School of Chemical Sciences, Universiti Sains Malaysia, 11800, Minden, Penang, Malaysia

• https://orcid.org/0000-0002-9361-4524

autor

Harimu La

• Department of Chemistry Education, Faculty of Teacher Training and Education, Halu Oleo University, Kendari, Sulawesi Tenggara, Indonesia

autor

Hanafiah Megat Ahmad Kamal Megat

• Faculty of Applied Sciences, Universiti Teknologi MARA Pahang, 26400, Jengka, Pahang, Malaysia

• https://orcid.org/0000-0001-8215-8036

Bibliografia

• 1. Al‑Amrani, W.A., Hanafah, M.A.K.M., Mohammed, A.A. 2022. A comprehensive review of anionic azo dyes adsorption on surface‑functionalised silicas. Environmental Science and Pollution Research. 29, 76565-76610
• 2. Azaman, S.A.H., Afandi, A., Hameed, B.H., Din, A.T.M. 2018. Removal of malachite green from aqueous phase using coconut shell activated carbon: Adsorption, desorption, and reusability studies. Journal of Applied Science and Engineering, 21(3), 317–330.
• 3. Bello, O.S., Ahmad, M.A. 2012. Coconut (Cocos nucifera) shell based activated carbon for the removal of malachite green dye from aqueous solutions. Separation Science and Technology, 47(6), 903–912.
• 4. Chong, M.Y., Tam, Y.J. 2020. Bioremediation of dyes using coconut parts via adsorption: a review. SN Applied Sciences, 2(187).
• 5. El Khomri, M., El Messaoudi, N., Dbik, A., Bentahar, S., Lacherai, A., Faska, N., Jada, A. 2022. Regeneration of argan nutshell and almond shell using HNO3 for their reusability to remove cationic dye from aqueous solution. Chemical Engineering Communications, 209(10), 1304–1315.
• 6. Ganiyu, S.A., Suleiman, M.A., Al-Amrani, W.A., Usman, A.K., Onaizi, S.A. 2023. Adsorptive removal of organic pollutants from contaminated waters using zeolitic imidazolate framework Composites: A comprehensive and Up-to-date review. Separation and Purification Technology, 318, 123765.
• 7. Hanafiah, M.A.K.M., Bakar, N.A.A., Al-Amrani, W.A., Ibrahim, S., Malek, N.A.N.N., Jawad, A. H. 2022. Preparation, characterization and application of sulphuric acid‑treated soursop (Annona muricata L.) seeds powder in the adsorption of Cu(II) ions. Nature Environment and Pollution Technology, 21(1), 217–223.
• 8. He, J., Mo, P., Luo, Y.-S., Yang, P.-H. 2023. Strategies for solving the issue of malachite green residues in aquatic products: a review. Aquaculture Research, 2023, 8578570.
• 9. Ho, Y.S., McKay, G. 1999. Pseudo-second order model for sorption processes. Process Biochemistry, 34(5), 451–465.
• 10. Jabar, J.M., Adebayo, M.A., Odusote, Y.A., Yılmaz, M., Rangabhashiyam, S. 2023. Valorization of microwave‑assisted H3 PO4‑activated plantain (Musa paradisiacal L) leaf biochar for malachite green sequestration: models and mechanism of adsorption. Results in Engineering, 18, 101129.
• 11. Khalid, K., Hanafiah, M.A.K., Al-Amrani, W.A., Malek, N.A.N., Fatinathan, S. 2022. Comparative adsorption of methylene blue dye on hexane‑washed and xanthated spent grated coconut (Cocos nucifera L.): Isotherms, thermodynamics and mechanisms. Journal of Ecological Engineering, 23(3), 1–11.
• 12. Lagergren, S.K. 1898. About the theory of so-called adsorption of soluble substances. Sven Vetenskapsakad Handingar, 24, 1–39.
• 13. Lemos, E.S., Fiorentini, E.F., Bonilla-Petriciolet, A., Escudero, L. B. 2023. Malachite green removal by grape stalks biosorption from natural waters and effluents. Adsorption Science & Technology, 2023, 6695937.
• 14. Musah, M., Azeh, Y., Mathew, J.T., Umar, M.T., Abdulhamid, Z., Muhammad, A.I. 2022. Adsorption kinetics and isotherm models: a review. CaJoST, 4(1), 20–26.
• 15. Nguyen, P.X.T., Ho, K.H., Do, N.H.N., Nguyen, C.T.X., Nguyen, H.M., Tran, K.A., Le, K.A., Le, P.K. 2022. A comparative study on modification of aerogel-based biosorbents from coconut fibers for treatment of dye‑ and oil‑contaminated water. Materials Today Sustainability, 19, 100175.
• 16. Phan, H.T., Nguyen, K.D., Nguyen, H.H.M., Dao, N.T., Le, P.T.K., Le, H.V. 2023. Nata de coco as an abundant bacterial cellulose resource to prepare aerogels for the removal of organic dyes in water. Bioresource Technology Reports, 24, 101613.
• 17. Piriya, R.S., Jayabalakrishnan, R.M., Maheswari, M., Boomiraj, K., Oumabady, S. 2023. Comparative adsorption study of malachite green dye on acid-activated carbon. International Journal of Environmental Analytical Chemistry, 103(1), 16–30.
• 18. Prasad, B., Mishra, A., Goswami, R. 2023. Malachite green dye adsorption using activated pine ash. AIP Conference Proceedings, 2521(1).
• 19. Qaiyum, M.A., Mohanta, J., Kumari, R., Samal, P.P., Dey, B., Dey, S. 2022. Alkali treated water chestnut (Trapa natans L.) shells as a promising phytosorbent for malachite green removal from water. International Journal of Phytoremediation, 24(8), 822–830.
• 20. Revellame, E.D., Fortela, D.L., Sharp, W., Hernandez, R., Zappi, M.E. 2020. Adsorption kinetic modeling using pseudo-first order and pseudo-second order rate laws: A review. Cleaner Engineering and Technology, 1, 100032.
• 21. Saikia, H., Brahma, D., Nath, H., Borah, D., Debnath, M. 2022. Coconut husk ash fabricated CoAllayered double hydroxide composite for the enhanced sorption of malachite green dye: isotherm, kinetics and thermodynamic studies. Inorganic Chemistry Communications, 144, 109878.
• 22. Somsiripan, T., Sangwichien, C. 2023. Enhancement of adsorption capacity of methylene blue, malachite green, and rhodamine B onto KOH activated carbon derived from oil palm empty fruit bunches. Arabian Journal of Chemistry, 16(12), 105270.
• 23. Song, C., Gao, C., Fatehi, P., Wang, S., Jiang, C., Kong, F. 2023. Influence of structure and functional group of modified kraft lignin on adsorption behavior of dye. International Journal of Biological Macromolecules, 240, 124368.
• 24. Umeh, C.T., Akinyele, A.B., Okoye, N. H., Emmanuel, S.S., Iwuozor, K.O., Oyekunle, I.P., Ocheje, J.O., Ighalo, J.O. 2023. Recent approach in the application of nanoadsorbents for malachite green (MG) dye uptake from contaminated water: A critical review. Environmental Nanotechnology, Monitoring & Management, 20, 100891.
• 25. Widiartyasari Prihatdini, R., Suratman, A., Siswanta, D. 2023. Linear and nonlinear modeling of kinetics and isotherm of malachite green dye adsorption to trimellitic-modified pineapple peel. Materials Today: Proceedings, 88, 33–40.
• 26. Zainon, A.Z.A., Al-Amrani, W.A., Mohd, S.F.B., Ibrahim, S., Megat Hanafiah, M.A.K. 2023. Phosphoric acid treated oil palm trunk waste for removal of malachite green–kinetics and isotherm investigations. Ecological Engineering & Environmental Technology, 24, 33‑43.
• 27. Zhang, Y., Zheng, Y., Yang, Y., Huang, J., Zimmerman, A.R., Chen, H., Hu, X., Gao, B. 2021. Mechanisms and adsorption capacities of hydrogen peroxide modified ball milled biochar for the removal of methylene blue from aqueous solutions. Bioresource Technology, 337, 125432.