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Potential Application of Used Coffee Grounds in Leather Tanning

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Języki publikacji
EN
Abstrakty
EN
Safety of environment and human health is an essential requirement of modern industrial techniques. Therefore, using natural agents in tanning industry may emerge as a trusted method to avoid the chemical contamination caused by using traditional chromium salts in tanning process. This study aimed to evaluate the hot water extract of used coffee grounds (UCGs) as a vegetable tanning agent. The collected UCGs were dried and extracted with hot water at 90 °C for 2h. The phytochemical screening properties of UCGs extract were determined. Sufficient amount of extract was prepared to be used in leather tanning. Three groups were tanned with UCGs extract solely at concentrations of 20, 30 or 40% of pelts’ weight, while another three groups were tanned with the same concentrations and then re-tanned with 10% of a synthetic tanning agent “Phenol sulfonates”. On tanned leathers, organoleptic, physical and chemical properties were determined; scanning electron micrographs were depicted to examine the leather surface and collagen fiber bundles. Analysis of UCGs extract revealed that it has good tanning properties, as it contained tannins (14.92%), tannins/non tannins ratio (2.06), hide powder (39.57) and Stiasny number (21.16). The results of leather properties showed that using UCGs extract alone at concentration of 40% achieved the best results for the vegetable tanning where the tanned leather had higher (P<0.05) tensile strength, tearing strength and shrinking temperature than that treated with the lower level of 20% UCGs extract. However, 40% of UCGs extract is highly recommended to be used to accomplish the required shrinkage temperature that should be ≥ 70 °C. UCGs extract could be successfully used as tanning agent in vegetable tanning to produce durable leathers with good fullness; it may be used for different manufacturing products, such as footwear and bags. Moreover, using a combination of UCGs extract at any of the used concentrations with phenol sulfonates 10% led to significant improvement in all studied traits as compared with using UCGs extract alone.
Słowa kluczowe
Rocznik
Strony
10--19
Opis fizyczny
Bibliogr. 28 poz., rys., tab.
Twórcy
  • Wool Production and Technology Department, Animal and Poultry Production Division, Desert Research Center, Cairo, Egypt
  • Department of Agricultural Biochemistry, Faculty of Agriculture, Al-Azhar University, Cairo, Egypt
  • Department of Agricultural Biochemistry, Faculty of Agriculture, Al-Azhar University, Cairo, Egypt
Bibliografia
  • 1. Abdelsalam M.M., El-Gabbas H.M., Abdelaziz N.M. 1998. Physical properties of raw hides and leather of the Egyptian Camel. Alexandria J. Agric. Res., 43, 3–19.
  • 2. Ahmed H.A., Halilu M.E., Mathias S.N., Lawal M. 2018. Phytochemical analysis and free radical scavenging activity of Isoberlinia doka leaves. GSC Biological and Pharmaceutical Sciences, 4(1), 48–52.
  • 3. Alim, Haj Ali, Gasm elseed G.A., Ahmed A.E. 2019. Innovation an Eco Friendly Technology: Tanning System using Semi Chrome and Improved Indigenous Tannins (Acacia Nilotica Pods). J. Biotechnol Biomed, 2(1), 15–23.
  • 4. ASTM. 2014. Books of standards. Vol.15.04, American Society for Testing and Materials, USA.
  • 5. BASF. 2007. Pocket book for leather technologist. Badische Anilin- und Soda-Fabrik, 4. 67056 Ludwigshafen, Germany.
  • 6. Choi, Bogyoung, Eunmi Koh. 2017. Spent coffee as a rich source of antioxidative compounds. Food Sci Biotechnol, 26(4), 921–927.
  • 7. Combalia F., Morera J.M., Bartolí, E. 2016. Study of several variables in the penetration stage of a vegetable tannage using ultrasound. Journal of Cleaner Production, 125, 314-319.
  • 8. Covington A.D. 2009. Tanning chemistry the science of leather. RSC publishing, Cambrige, London.
  • 9. Das A.K., Islam M.N., Faruk M.O., Ashaduzzaman M., Dungani R. 2020. Review on tannins: Extraction processes, applications and possibilities. South African Journal of Botany, 135, 58–70.
  • 10. Dutta S.S. 2008. An Introduction to the Principles of Leather Manufacture. 4th edition, Indian Leather Techno Association, India.
  • 11. Erdem M., Ozverdi A. 2008. Leaching behavior of chromium in chrome shaving generated in tanning process and its stabilization. Journal of Hazardous Materials, 156, 51–55.
  • 12. Lina F., Araújo M.E.M. 2018. Vegetable Tannins Used in the Manufacture of Historic Leathers. molecules, 23(1081), 1–20.
  • 13. FAOSTAT. 2020. Production-Crops data. World Food And Agriculture Organization, Rome.
  • 14. Galvez J.M., Riedl B., Conner A.H. 1997. Analytical studies on Tara tannins. Holzforschung, 51, 235–243.
  • 15. Guo L., Qiang T., Ma Y., Wang K., Du K. 2020. Optimisation of tannin extraction from Coriaria nepalensis bark as a renewable resource for use in tanning. Industrial Crops & Products, 149(112360), 1–10.
  • 16. Amzad H.M., AL-Raqmi K.A.S., AL-Mijizy Z.H., Weli A.M., Al-Riyami Q. 2013. Study of total phenol, flavonoids contents and phytochemical screening of various leaves crude extracts of locally grown Thymus vulgaris. Asian Pacific Journal of Tropical Biomedicine, 3(9), 705–710.
  • 17. Jia L., Ma J., Gao D., Lyu B., Zhang J. 2016. Application of an amphoteric polymer for leather pickling to obtain a less total dissolved solids residual process. Journal of Cleaner Production, 139, 788–795.
  • 18. Kasmudjiastuti E., Murti R.S. 2017. The effects of finish type on permeability and organoleptic properties of python (Python reticulatus) skin finished leather. Majalah Kulit Karet dan Plastik, 33(1), 19–28.
  • 19. Li J., Maplesden F. 1998. Commercial production of tannins from radiata pine bark for wood adhesives. IPENZ Transactions, 25, 46–52.
  • 20. Low J.H., Rahman W.A.W.A., Jamaluddin J. 2015. The influence of extraction parameters on spent coffee grounds as a renewable tannin resource. Journal of Cleaner Production, 101, 222–228.
  • 21. Makkar Harinder P.S. 2003. Quantification of Tannins in Tree and Shrub Foliage A Laboratory Manual. Springer-Science+Business Media, B.V., Vienna.
  • 22. Marques S.R.R., Azevêdo T.K.B., de Castilho A.R.F., Brag R.M., Pimenta A.S. 2021. Extraction, quantification, and ftir characterization of bark tannins of four forest species grown in northeast Brazil. Revista Árvore, 45(e4541), 1–10.
  • 23. Mutuku M., Ombui J., Onyuka A. 2022. Assessment of coffee pulp as a potential source of tannins for leather processing. Textile & Leather Review, 5, 132–146.
  • 24. Nasr A.I., Mueller H., Abdelsalam M.M., Azzam A.H., Jungandreas C., Poppitz W. 2017. Evaluation of Potential Application for Sunt Pod Extracts (Acacia Nilotica) in Leather Tanning. JALCA, 112, 23–32.
  • 25. SAS. 2008. SAS/STAT 9.2 User’s guide. 2nd edition. SAS Institute Inc., Cary, NC.
  • 26. Tran T.M.K., Kirkman T., Nguyen M., Vuong Q.V. 2020. Effects of drying on physical properties, phenolic compounds and antioxidant capacity of Robusta wet coffee pulp (Coffea canephora). Heliyon, 6(e04498), 1–7.
  • 27. UNIDO. 1994. Acceptable quality standards in the leather and footwear industry. United Nations Industrial Development Organization, Vienna.
  • 28. Vázquez G., González-Alvarez J., Santos J., Freire M.S., Antorrena G. 2008. Evaluation of potential applications for chestnut (Castanea sativa) shell and eucalyptus (Eucalyptus globulus) bark extracts. Industrial crops and products, 29, 364–370.
Uwagi
Opracowanie rekordu ze środków MEiN, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2022-2023).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-80659d88-853f-46f0-9542-533cb17ee887
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