Study of Molecular Perovskite (H2dabco)[NH4(ClO4)3]/Carbon Nanotubes Energetic Composite

• Autorzy: Hu Li-shuang , Liu Yang , He Dan , Yang Yajun , Gong Shida , Guang Chunyu , Deng Peng , Hu Shuangqi

Identyfikatory

DOI

10.22211/cejem/147766

• Języki publikacji: EN

Abstrakty

EN

An ammonium perchlorate (AP, NH4(ClO4)3)-based molecular perovskite energetic material (H2dabco)[NH4(ClO4)3]/carbon nanotubes (DAP/CNTs) composite was prepared and characterized. Molecular perovskite DAP samples were synthesized by a facile one-pot reaction of triethylenediamine, perchloric acid (PCA, HClO4), and AP via a molecular assembly strategy. The results showed that the mechanical sensitivity (impact and friction sensitivities: >120 cm and 20%) and electrostatic spark sensitivity (8.90 J) of the DAP/CNTs energetic composite with 10 wt.% CNTs exhibited less sensitivity than that of DAP (impact, friction and electrostatic spark sensitivities: 112.3 cm, 45%, and 5.39 J, respectively), because of the mixing desensitization mechanism of CNTs. Compared with the pure DAP, the DAP/CNTs energetic composite has better performance with respect to thermal stability, exothermic capacity, and excellent continuous combustion properties. The DAP/CNTs energetic composite has potential application in a weapons system.

Słowa kluczowe

EN

ammonium perchlorate; (H2dabco)[NH4(ClO4)3]; carbon nanotubes; mechanical sensitivity; thermal stability

• Wydawca: Sieć Badawcza Łukasiewicz - Instytut Przemysłu Organicznego
• Czasopismo: Central European Journal of Energetic Materials
• Rocznik: 2022
• Tom: Vol. 19, no. 1
• Strony: 91--105
• Opis fizyczny: Bibliogr. 29 poz., rys., tab.

Twórcy

autor

Hu Li-shuang

• School of Environment and Safety Engineering, North University of China, Taiyuan, 030051, China

autor

Liu Yang

• School of Environment and Safety Engineering, North University of China, Taiyuan, 030051, China

autor

He Dan

• Gan Su Yin Guang Chemical Industry Group CO., LTD, Baiyin, 730900, China

autor

Yang Yajun

• Shanxi Jiangyang Xing’an Industrial Explosive Materials CO., LTD, Taiyuan, 030051, China

autor

Gong Shida

• School of Environment and Safety Engineering, North University of China, Taiyuan, 030051, China

autor

Guang Chunyu

• School of Environment and Safety Engineering, North University of China, Taiyuan, 030051, China

autor

Deng Peng

• School of Environment and Safety Engineering, North University of China, Taiyuan, 030051, China

autor

Hu Shuangqi

• School of Environment and Safety Engineering, North University of China, Taiyuan, 030051, China

Bibliografia

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