Review on hierarchically microstructured monolithic reactors for high yield continuous production of fine chemicals

• Autorzy: Mrowiec-Białoń J. , Ciemięga A. , Maresz K. , Szymańska K. , Pudło W. , Jarzębski A. B.

Identyfikatory

DOI

10.24425/122957

• Języki publikacji: EN

Abstrakty

EN

Preparation and properties of hierarchically structured porous silica monoliths have been discussed from the viewpoint of their application as continuous microreactors for liquid-phase synthesis of fine chemical in multi kilogram scales. The results of recent topical papers published by two research teams of Institute of Chemical Engineering Polish Academy of Sciences (ICE) and Department of Chemical Engineering and Process Design, Chemical Faculty, Silesian University of Technology (SUT) have been analyzed to specify the governing traits of microreactors. It was concluded that even enhancement factor of 100 in activity, seen in enzyme catalyzed reactions, can be explained by a proportional reduction of its physical constraints, i.e. huge enhancement of external mass transfer and micromixing. It is induced by very chaotic flows of liquid in tens of thousands of waving connected channels of ca. 25–50 mm in diameter, present in the skeleton. The scale of enhancement in the caseof less active catalysts was smaller, but still large enough to consider the most practical applications.

Słowa kluczowe

EN

microreactors; in-flow synthesis; process intensification; nanostructured materials

PL

mikroreaktory; synteza wewnątrzpłynna; intensyfikacja procesu; materiały nanostrukturalne

• Wydawca: Komitet Inżynierii Chemicznej i Procesowej Polskiej Akademii Nauk
• Czasopismo: Chemical and Process Engineering
• Rocznik: 2018
• Tom: Vol. 39, nr 4
• Strony: 367–--375
• Opis fizyczny: Bibliogr. 27 poz.

Twórcy

autor

Mrowiec-Białoń J.

• Institute of Chemical Engineering Polish Academy of Sciences, Bałtycka 5, 44-100 Gliwice
• Department of Chemical Engineering and Process Design, Chemical Faculty, Silesian University of Technology, 10 Ks. M. Strzody 9, 44-100 Gliwice

autor

Ciemięga A.

• Institute of Chemical Engineering Polish Academy of Sciences, Bałtycka 5, 44-100 Gliwice

autor

Maresz K.

• Institute of Chemical Engineering Polish Academy of Sciences, Bałtycka 5, 44-100 Gliwice

autor

Szymańska K.

• Department of Chemical Engineering and Process Design, Chemical Faculty, Silesian University of Technology, 10 Ks. M. Strzody 9, 44-100 Gliwice

autor

Pudło W.

• Department of Chemical Engineering and Process Design, Chemical Faculty, Silesian University of Technology, 10 Ks. M. Strzody 9, 44-100 Gliwice

autor

Jarzębski A. B.

• Institute of Chemical Engineering Polish Academy of Sciences, Bałtycka 5, 44-100 Gliwice
• Department of Chemical Engineering and Process Design, Chemical Faculty, Silesian University of Technology, 10 Ks. M. Strzody 9, 44-100 Gliwice

Bibliografia

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• 2. Ciemięga A., Maresz K., Malinowski J.J., Mrowiec-Białoń J., 2017a. Continuous-flow monolithic silica microreactors with arenesulphonic acid groups: structure-catalytic activity relationships. Catalysts, 7(9), 255. DOI: 10.3390/catal7090255.
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• 20. Szymańska K., Bryjak J., Mrowiec-Białoń J., Jarzebski A.B., 2007. Application and properties of siliceous mesostructured cellular foams as enzymes carriers to obtain efficient biocatalysts. Microporous Mesoporous Mater., 99, 167–175. DOI: 10.1016/j.micromeso.2006.08.035.
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Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).