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Kinetics and isotherm modelling of Zn(II) ions adsorption onto mine soils

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
The soils consist of various components that can play a significant role in control of heavy metals in the environment. Therefore, understanding of adsorption properties of soil is essential in solving pollution problems around mine sites. The goal of this paper is to study Zn(II) ions adsorption onto copper mine soil. Soils were examined via X-ray diffraction and scanning electron microscopy. The influence of various parameters such as effect of pH, adsorbent dose, and initial concentration of Zn(II) ions on adsorption was evaluated by batch method. The adsorption isotherms of Zn(II) ions such as Langmuir, Freundlich, and Temkin were studied. The Langmuir isotherm indicated an excellent fit for the experimental data in comparison with other isotherms that shown monolayer adsorption onto a homogenous surface. A number of kinetic models were tested to fit the kinetic data. The results show that soils can be more effective in decreasing heavy metals contamination specially Zn(II) ions from solution phase.
Rocznik
Strony
767--779
Opis fizyczny
Bibliogr. 32 poz., rys., tab.
Twórcy
autor
  • Department of Mining Engineering, Petroleum and Geophysics, Shahrood University of Technology, Shahrood, Iran
  • Department of Mining Engineering and Metallurgy, Amirkabir University of Technology, Tehran, Iran
autor
  • Department of Mining Engineering, Petroleum and Geophysics, Shahrood University of Technology, Shahrood, Iran
Bibliografia
  • ACAR F.N., EREN Z., 2006, Removal of Cu (II) Ions by Activated Poplar Sawdust (Samsun Clone) from Aqueous Solutions, J. Hazard. Mater. B 137, 909-914.
  • ADAMSON A.W., GAST A.P., 1997, Physical Chemistry of Surfaces, Wiley-Interscience, New York.
  • AHARONI C., UNGARISH M., 1977, Kinetics of Activated Chemisorption. Part 2. Theoretical Models, J. Chem. Soc. Faraday Trans. 73, 456-464.
  • ALLISON L.E., MOODIE C.D., 1965, Carbonate. Methods of Soil Analysis, American Society of Agronomy, Madison.
  • BRADL H.B., 2004, Adsorption of Heavy Metal Ionson Soils and Soils Constituents, J. Colloid Interface Sci. 277, 1-18.
  • COVELO E.F., ANDRADE M.L., VEGA F.A., 2004a, Competitive Adsorption and Desorption of Cadmium, Chromium, Copper, Nickel, Lead and Zinc by Humic Umbrisols, Commun. Soil Sci. Plant Anal. 35, 2709-2729.
  • COVELO E.F., ANDRADE M.L., VEGA F.A., 2004b, Heavy Metal Adsorption by Humic Umbrisols: Selectivity Sequences and Competitive Sorption Kinetics, J. Colloid Interface Sci. 280, 1-8.
  • DABROWSKI A., 2001, Adsorption From Theory to Practice, Adv. Colloid Interface Sci. 93, 135-224.
  • DAY P.R., 1965, Particle Size Analysis, Methods of Soil Analysis. Part I, American Society of Agronomy, Madison.
  • FOO K.Y., HAMEED B.H., 2010, Insights into the Modeling of Adsorption Isotherm Systems, Chem. Eng. J. 156, 2-10.
  • FREUNDLICH H.M.F., 1906 Over the Adsorption in Solution, J. Phys. Chem. 57, 385-471.
  • GOMES P.C., FONTES M.P.F., DA SILVA D.G., MENDONCA E., DE S., NETTO A.R., 2001, Selectivity Sequence and Competitive Adsorption of Heavy Metals by Brazilian Soils, Soil Sci. Soc. Am. J. 65, 1115-1121.
  • GUITIAN F., CARBALLAS T., 1976, Tecnicas de análisis de suelos, Pico Sacro, Santiago de Compostella.
  • HENDERSHOT W., DUQUETTE M., 1986, A Simple Barium Chloride Method for Determining Cation Exchanges Capacity and Exchangeable Cations, Soil Sci. Soc. Am. J. 50, 605-608.
  • KAPOOR A., YANG R.T., 1989, Correlation of Equilibrium Adsorption Data of Condensable Vapours on Porous Adsorbents, Gas Sep. Purif. 3, 187-192.
  • KHORASANIPOUR M., MOORE F., NASEH R., 2011, Lime Treatment of Mine Drainage at the Sarcheshmeh Porphyry Copper Mine, Iran. Mine Water Environ. 30, 216-230.
  • KINNIBURGH D.G., VAN RIEMSDIJK W.H., KOOPAL L.K., BORKOVEC M., BENEDETTI M.F., AVENA M.J., 1999, Ion Binding to Natural Organic Matter: Competition, Heterogeneity, Stechiometry and Thermodynamic Consistency, Colloids Surf. A: Physicochem. Eng. Asp. 151, 147-166.
  • LANGMUIR I., 1916, The Constitution and Fundamental Properties of Solids and Liquids, J. Am. Chem. Soc. 38, 2221-2295.
  • LI Y., YUE Q., GAO B., 2010, Adsorption Kinetics and Desorption of Cu (II) and Zn(II) from Aqueous Solution onto Humic Acid, J. Hazard. Mater. 178, 455-461.
  • LIMOUSIN G., GAUDET J.P., CHARLET L., SZENKNECT S., BARTHE`S V., KRIMISSA M., 2007, Sorption Isotherms: A Review on Physical Bases, Modeling and Measurement, Appl. Geochem. 22, 249-275.
  • MACIAS F., CARABALLO M.A., NIETO J.M., 2012, Environmental Assessment and Management of Metal-rich Wastes Generated in Acid Mine Drainage Passive Remediation Systems, J. Hazard. Mater. 229-230, 107-114.
  • NANDI B.K., GOSWAMI A., PURKAIT M.K., 2009, Adsorption Characteristics of Brilliant Green Dye on Kaolin, J. Hazard. Mater. 161, 387-395.
  • EL NEMR A., 2009, Potential of Pomegranate Husk Carbon for Cr(VI) Removal From Wastewater: Kinetic and Isotherm Studies, J. Hazard. Mater. 161, 132-141.
  • REDDY M.R., DUNN S.J., 1986, Distribution Coefficients for Nickel and Zinc in Soils, Environ. Pollut. 11, 303-313.
  • SHERDRICK B.H., MCKEAGUE J.A., 1975, A Comparison of Extractable Fe and Al Data Using Methods Followed in the U.S.A. and Canada, Can. J. Soil Sci. 55, 77-78.
  • SPARKS D.L., 2003, Environmental Soil Chemistry, Second Edition, Academic Press of University of Delawere, Delaware
  • SREEJALEKSHMI K.G., ANOOPKRISHNAN K., ANIRUDHAN T.S., 2009, Adsorption of Pb(II) and Pb(II)-citric Acid on Sawdust Activated Carbon: Kinetic and Equilibrium Isotherm Studies, J. Hazard. Mater. 161, 1506-1513.
  • TEMPKIN M.I., PYZHEV V., 1940, Kinetics of Ammonia Synthesis on Promoted Iron Catalyst, Acta. Phys. Chim. USSR 12, 327-356.
  • KUMAR VASANTH K., SIVANESAN S., 2006., Selection of Optimum Sorption Kinetics: Comparison of Linear and Non-Linear Method, J. Hazard. Mater. B 134, 277-279.
  • VERNERSSON T., BONELLI P.R., CERRELA E.G., CUKIERMAN A.L., 2002, Arundo Donax Cane as a Precursor for Activated Carbons Preparation by Phosphoric Acid Activation, Bioresour. Technol. 83, 95-104.
  • VIDALA M., SANTOS M.J., ABRAO T., RODRIGUEZ J., RIGOL A., 2009, Modeling Competitive Metal Sorption in a Mineral Soil, Geoderma 149, 189-198.
  • WALKLEY A.J., BLACK I.A., 1934, Estimation of Soil Organic Carbon by Chromic acid Titration Method, Soil Sci. 34, 29-38.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-800a86f5-a2ff-4d97-bc78-eeadc1a381e3
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