Improving the carbon dioxide uptake efficiency of activated carbons using a secondary activation with potassium hydroxide

Zgrzebnicki, M.; Michalczyszyn, E.; Wrobel, R. J.

doi:10.2478/pjct-2018-0043

Artykuł - szczegóły

Tytuł artykułu

Improving the carbon dioxide uptake efficiency of activated carbons using a secondary activation with potassium hydroxide

Autorzy

Zgrzebnicki M. , Michalczyszyn E. , Wrobel R. J.

Treść / Zawartość

Pełne teksty:

Polish Journal of Chemical Technology_3_2018_Zgrzebnicki.pdf

Pobierz

Identyfikatory

DOI

10.2478/pjct-2018-0043

Warianty tytułu

Języki publikacji

Abstrakty

Secondary activation of commercial activated carbon (AC) ORGANOSORB 10-CO was carried out at 600, 700 and 800°C with mass ratios of potassium to AC (K/AC) in range 1–3. Crucial samples have shown following CO₂ uptakes and SSA – 3.90 mmol/g and 1225 m²/g, 4.54 mmol/g and 1546 m²/g, 4.28 and 1717 m²/g for pristine material and samples obtained at 700°C with K/AC = 2 and at 800°C with K/AC = 3 respectively. Last sample also indicated significant mesopore volume increase in diameter range 2–5 nm, from 0.11 to 0.24 cm3/g. CO₂ uptake increase was explained by formation of micropores up to diameter of 0.8 nm, which distribution was established from CO₂ sorption using DFT. Surface chemistry of all samples has not changed during modification, what was proven by XPS. Moreover, deeper incorporation of potassium ions into graphite at higher temperatures was observed as confirmed with EDS, XPS and XRD.

Słowa kluczowe

activated carbon activation pore size distribution DFT

Wydawca

West Pomeranian University of Technology. Publishing House

Czasopismo

Polish Journal of Chemical Technology

Rocznik

2018

Tom

Vol. 20, nr 3

Strony

87--94

Opis fizyczny

Bibliogr. 37 poz., rys., tab.

Twórcy

autor

Zgrzebnicki M.

West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, ul. Pulaskiego 10, 70-322 Szczecin, Poland

autor

Michalczyszyn E.

West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, ul. Pulaskiego 10, 70-322 Szczecin, Poland

autor

Wrobel R. J.

Rafal.Wrobel@zut.edu.pl

West Pomeranian University of Technology, Szczecin, Institute of Chemical and Environment Engineering, ul. Pulaskiego 10, 70-322 Szczecin, Poland

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).

Typ dokumentu

Bibliografia

Identyfikator YADDA

bwmeta1.element.baztech-80091b13-e5f1-461e-b78b-801738873367