Zastosowanie chromatografii gazowej do rozdzielania i oznaczania lotnych związków azoto-organicznych (LZN) w próbkach wody i ścieków

Makoś, P.; Boczkaj, G.

Artykuł - szczegóły

Tytuł artykułu

Zastosowanie chromatografii gazowej do rozdzielania i oznaczania lotnych związków azoto-organicznych (LZN) w próbkach wody i ścieków

Autorzy

Makoś P. , Boczkaj G.

Treść / Zawartość

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_cs_2014_zastosowanie_chromatografii.pdf

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Warianty tytułu

Application of gas chromatography for separation and guantification of Volatile Nitrogen-containing Compounds (VNCs) in samples of water and wastewater

Języki publikacji

Abstrakty

W pracy dokonano przeglądu i porównania metod opartych na chromatografii gazowej do oznaczania lotnych związków azoto-organicznych (LZN) w próbkach wody i ścieków. Przedstawione zostały metodyki analityczne wykorzystujące zarówno detektory selektywne tj. detektor azotowo-fosforowy (NPD), detektor powierzchniowej jonizacji (SID), detektor chemiluminescencyjny azotu (CLND), detektor wychwytu elektronów (ECD) jak i detektorów uniwersalnych typu spektrometr mas (MS), tandemowy spektrometr mas (MS/MS) oraz detektor płomieniowo jonizacyjny (FID). Ze względu na wysoką toksyczność oraz negatywne oddziaływanie LZN na środowisko, konieczne staje się opracowanie nowych metod analitycznych, które umożliwią oznaczenie związków na niskich poziomach stężeń. Spośród dostępnych metod największą popularnością i największym potencjałem do różnorodnych zastosowań jest chromatografia gazowa sprzężona ze spektrometrią mas, ponieważ w połączeniu z odpowiednią techniką izolacji lub/i wzbogacania analitów, zapewnia niskie granice wykrywalności względem większości związków z grupy LZN. Pozostałe detektory wykazują wysoką selektywność dla mniejszej liczby związków LZN.

The paper presents a review and comparison of gas chromatographic methods for determination of Volatile Nitrogen-containing Compounds (VNCs) in samples of water and wastewater. The analytical methods that uses both selective detectors such as Nitrogen-Phosphorus Detector (NPD), Surface lonization Detector (SID), Nitrogen Chemiluminescence Detector (CLND), Electron Capture Detector (ECD) and universal detectors: Mass Spectrometry (MS), Tandem Mass Spectrometry (MS/MS) and Flame lonization Detector (FID) were described. Due to the high toxicity and negative effects of VNCs on the environment, it becomes necessary to develop new analytical methods that allow determination of compounds ar Iow concentration level. Among all available methods, the most popular and the greatest potential for a variety of applications have gas chromatography coupled with mass spectrometry, because in combination with techniques of isolation and / or enrichment of the analytes, provide Iow limits of detection for most VNCs. Other detectors have a high selectMty for a smaller number of VNCs compounds.

Słowa kluczowe

Lotne związki azoto-organiczne LZN woda ścieki chromatografia gazowa detektory uniwersalne detektory selektywne

Volatile Nitrogen-containing Compounds VNCs water wastewater gas chromatography universal detectors selective detectors

Wydawca

Publishing House of Siedlce University of Natural Sciences and Humanities

Czasopismo

Camera Separatoria

Rocznik

2014

Tom

Vol. 6, No. 2

Strony

73--86

Opis fizyczny

Bibliogr. 95 poz., tab.

Twórcy

autor

Makoś P.

Katedra Inżynierii Chemicznej i Procesowej, Wydział Chemiczny, Politechnika Gdańska

autor

Boczkaj G.

grzegorz.boczkaj@gmail.com

Katedra Inżynierii Chemicznej i Procesowej, Wydział Chemiczny, Politechnika Gdańska

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