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Coal Char Kinetics of Oxidation and Gasification Reactions

Autorzy
Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Experimental investigations and numerical simulations have been conducted in this study to derive and test the values of kinetic parameters describing oxidation and gasification reactions between char carbon and O2 and CO2 occurring at standard air and oxy-fuel combustion conditions. Experiments were carried out in an electrically heated drop-tube at heating rates comparable to fullscale pulverized fuel combustion chambers. Values of the kinetic parameters, obtained by minimization of the difference between the experimental and modeled values of char burnout, have been derived and CFD simulations reproducing the experimental conditions of the drop tube furnace confirmed proper agreement between numerical and experimental char burnout.
Rocznik
Strony
135--145
Opis fizyczny
Bibliogr. 22 poz., rys.
Twórcy
autor
  • Institute of Power Engineering, Thermal Processes Department, Augustówka 36, 02-981 Warsaw, Poland
autor
  • Institute of Power Engineering, Thermal Processes Department, Augustówka 36, 02-981 Warsaw, Poland
Bibliografia
  • 1. Al-Makhadmeh L., 2009. Coal pyrolysis and char combustion under oxy-fuel conditions, PhD thesis, Stuttgart, Universität Stuttgart.
  • 2. Baum M.M., Street P.J., 1971. Predicting the combustion behaviour of coal particles. Combust. Sci. Technol., 3 (5), 231-243. DOI: 10.1080/00102207108952290.
  • 3. Brix J., Jensen P.A., Jensen A.D., 2010. Coal devolatilization and char conversion under suspension fired conditions in O2/N2 and O2/CO2 atmospheres. Fuel, 89, 3373–3380. DOI: 10.1016/j.fuel.2010.03.019.
  • 4. Caram H.S., Amundson N.R., 1977. Diffusion and reaction in a stagnant boundary layer about a carbon particle. Industrial & Engineering Chemistry Fundamentals, 16 (2), 171–181. DOI: 10.1021/i160062a001.
  • 5. Chen L., Yong S.Z., Ghoniem A.F., 2012. Oxy-fuel combustion of pulverized coal: Characterization, fundamentals, stabilization and CFD modeling. Progress in Energy and Combustion Science, 38, 156-214. DOI: 10.1016/j.pecs.2011.09.003.
  • 6. Fendell F.E., 1969. The burning of spheres gasified by chemical attack. Combust. Sci. Technol., 1, 13–24. DOI: 10.1080/00102206908952188.
  • 7. Goel S., Lee C.H., Longwell J.P., Sarofim A.F., 1996, Modelling of ignition and CO oxidation in the boundary layer of a single char particle, Energy Fuels, 10, 1091-1098. DOI: 10.1021/ef9502416.
  • 8. Gonzalo–Tirado C., Jiménez S., Ballester J., 2012. Gasification of a pulverized subbituminous coal in CO2 at atmospheric pressure in an entrained reactor. Combust. Flame, 159, 385 – 395. DOI: 10.1016/j.combustflame.2011.07.001.
  • 9. Haas J.H.P., Maalman T., Gallagher G., van de Kamp W., 1997. Pulverized fuel combustion. Characterization of coal blends. IFRF Doc No F 37/y/38.
  • 10. Hurt R., Calo J., 2001. Semi–global intrinsic kinetics for char combustion modelling. Combust. Flame, 125, 1138- 1149. DOI: 10.1016/S0010-2180(01)00234-6.
  • 11. Jenni K.E., Baker E.D., Nemet G.F., 2013. Expert elicitations of energy penalties for carbon capture technologies. Int. J. Greenhouse Gas Control, 12, 136–145. DOI: 10.1016/j.ijggc.2012.11.022.
  • 12. Lasdon L.S., Waren A.D., Jain A., Ratner M., 1975. Design and testing of a generalized reduced gradient code for nonlinear optimization. USA, NTIS.
  • 13. Lewtak R., Milewska A., 2013. Application of different diffusion approaches in oxy-fuel combustion of single coal char particles. Fuel, 113, 844-853. DOI: 10.1016/j.fuel.2013.01.053.
  • 14. Maloney J.O., Perry’s chemical engineers’ handbook, McGraw-Hill; 2008.
  • 15. Maffei T., Khatami R., Pierucci S., Faravelli T., Ranzi E., Levendis Y.A., 2013. Experimental and modeling study of single coal particle combustion in O2/N2 and Oxy-fuel (O2/CO2) atmospheres. Combust. Flame, 160, 2559-2572. DOI: 10.1016/j.combustflame.2013.06.002.
  • 16. Mitchell R.E., 1987. Experimentally determined overall burning rates of coal chars. Combust. Sci. Technol., 53,165–186. DOI: 10.1080/00102208708947025.
  • 17. Rathnam RK, Elliott LK, Wall TF, Liu Y, Moghtaderi B., 2009. Differences in reactivity of pulverised coal in air (O2/N2) and oxy-fuel (O2/CO2) conditions. Fuel Process Technol., 90, 797–802. DOI: 10.1016/j.fuproc.2009.02.009.
  • 18. Shaddix C.R., Holzleithner F., Geier M., Haynes B.S., 2013. Numerical assessment of Tognotti determination of CO2/CO production ratio during char oxidation. Combust. Flame, 160, 1827 – 1834. DOI: 10.1016/j.combustflame.2013.03.019.
  • 19. Smith I.W., 1982. The combustion rates of coal chars: a review. 19th Int. Symposium on Combustion, Technion-Israel Institute of Technology, Haifa, Israel, 8-13 August 1982, 1045-1065. DOI: 10.1016/S0082- 0784(82)80281-6.
  • 20. Smith K.L Smoot L.D., Fletcher T.H., Pugmire R.J., 1994. The structure and reaction processes of coal. The Plenum Chemical Engineering Series.
  • 21. Toftegaard M.B., Brix J., Jensen P.A., Glarborg P., Jensen A.D., 2010. Oxy–fuel combustion of solid fuels. Prog. Energy Combust. Sci., 36, 581–625. DOI: 10.1016/j.pecs.2010.02.001.
  • 22. Wall T.F., Gururajan V.S., 1986. Combustion kinetics and the heterogeneous ignition of pulverized coal. Combust. Flame, 66, 151-157. DOI: 10.1016/0010-2180(86)90087-8.
Uwagi
PL
Opracowanie ze środków MNiSW w ramach umowy 812/P-DUN/2016 na działalność upowszechniającą naukę (zadania 2017)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7db233b0-39d9-4fab-be22-5c3ec5a4e288
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