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The paper details with of the preparation and physicochemical characterisation of nano- and microstructured TiO2 doped with Fe and Co produced by the sol-gel method using titanium alkoxide as the precursor of titania as well as iron or cobalt nitrates as dopant sources. Fe and Co doped TiO2 materials were successfully prepared with two different methods. The effect of the dopant type on the synthesis of TiO2 powders was investigated. The physicochemical properties of the studied samples were determined. The characterisation included determination of the dispersion and morphology of the systems (particle size distribution, SEM images), characteristics of porous structure (BET isotherms), crystalline structure (XRD), surface composition (EDS), as well as thermal stability (TG/DTA).
Rocznik
Tom
Strony
265--276
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
- Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Marii Sklodowskiej-Curie 2, PL-60-965, Poznan, Poland
autor
- Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Marii Sklodowskiej-Curie 2, PL-60-965, Poznan, Poland
autor
- Poznan University of Technology, Faculty of Mechanical Engineering and Managment, Institute of Materials Science and Engineering, Jana Pawla II 24, PL-60-965, Poznan, Poland
autor
- Poznan University of Technology, Faculty of Chemical Technology, Institute of Chemical Technology and Engineering, Marii Sklodowskiej-Curie 2, PL-60-965, Poznan, Poland
Bibliografia
- 1. AMADELLI R., SAMIOLO L., MALDOTTI A., MOLINARI A., VALIGI M., GAZZOLI D., 2008, Preparation, characterisation, and photocatalytic behaviour of Co-TiO2 with visible light response, International Journal of Photoenergy, Article ID 853753, 9 pages, doi: 10.1155/2008/853753.
- 2. AMBRUS Z., BALÁZS N., ALAPI T., WITTMANN G., SIPOS P., DOMBI A., MOGYORÓSI K., 2008, Synthesis, structure and photocatalytic properties of Fe(III)-doped TiO2 prepared from TiCl3, Applied Catalysis B: Environmental 81, 27–37.
- 3. ANPO M., 2000, Use of visible light. Second-generation titanium dioxide photocatalysts prepared by the application of an advanced metal ion-implantation metod, Pure and Applied Chemistry 72, 1787–1792.
- 4. CHATTERJEE D., MAHATA A., 2001, Demineralization of organic pollutants on the dye modified TiO2 semiconductor particulate system using visible light, Applied Catalysis B: Environmental 33, 119–125.
- 5. FUERTE M.D.H.A., MAIRA A.J., MARTINEZ-ARIAS A., FERNADEZ-GARCIA M., CONESA J.C., SORIA J., 2001, Visible light-activated nanosized doped-TiO2 photocatalysts, Chemical Communications 24, 2718–2719.
- 6. FUJISHIMA X., ZHANG C.R., 2006, Titanium dioxide photocatalysis: Present situation and future approaches, Chimie 9, 750–760.
- 7. HAMADANIAN M., REISI-VANANI A., MAJEDI A., 2010, Sol-gel preparation and characterization of Co/TiO2 nanoparticles: application to degradation of Methyl Orange, Journal of the Iranian Chemical Society 7, S52–S58.
- 8. HE Z.L., QUE W.X., XIE H.X., CHEN J.,Y. YUAN, P. SUN., 2012, Facile synthesis of self-sensitized TiO2 photocatalysts and their higher photocatalytic activity, Journal of the American Ceramic Society 95, 3941–3946.
- 9. HIRAI T., SUZUKI K., KOMASAWA I., 2001, Preparation and photocatalytic properties of composite CdS nanoparticles-titanium dioxide particles, Journal of Colloid and Interface Science 244, 262–265.
- 10. HUANG D.G., LIAO S.J., ZHOU W.B., QUAN S.Q., LIU L., HE Z.J., WAN J.B., 2009, Synthesis of samarium- and nitrogen-co-doped TiO2 by modified hydrothermal method and its photocatalytic performance for the degradation of 4-chlorophenol, Journal of Physics and Chemistry of Solids 70, 853–859.
- 11. IHARA T., MIYOSHI M., ANDO M., SUGIHARA S., IRIYAMA Y., 2001, Preparation of a visiblelight-active TiO2 photocatalyst by RF plasma treatment, Journal of Materials Science 36, 4201–4207.
- 12. JCPDS International Center of Diffraction Data (1980), JCPDS Powder Diffraction File, Card 21-1272.
- 13. LIU Y., CHEN X., LI J., BURDA C., 2005, Photocatalytic degradation of azo dyes by nitrogen-doped TiO2 nanocatalysts, Chemosphere 61, 11–18.
- 14. OHNO T., MITSUI T., MATSUMURA M., 2003, Photocatalytic activity of S-doped TiO2 photocatalyst under visible light, Chemistry Letters 32, 364–365.
- 15. TAKEUCHI K., NAKAMURA I., MATSUMOTO O., SUGIHARA S., ANDO M., IHARA T., 2000, Preparation of visible-light-responsive titanium oxide photocatalysts by plasma treatment, Chemistry Letters 29, 1354–1355.
- 16. WANG J., MA T., ZHANG G., ZHANG Z., ZHANG X., JIANG Y., ZHAO G., ZHANG P., 2007,Preparation of nanometer TiO2 catalyst doped with upconversion luminescence agent and investigation on degradation of acid red B dye using visible light, Catalysis Communications 8, 607–611.
- 17. WANG J., TAFEN D.N., LEWIS J.P., HONG Z.L., MANIVANNAN A., ZHI M.J., LI M., WU N.Q.,2009, Origin of photocatalytic activity of nitrogen-doped TiO2 nanobelts, Journal of the American Ceramic Society 131, 12290–12297.
- 18. WEN L., LIU B., ZHAO X., NAKATA K., MURAKAMI T., FUJISHIMA A., 2012, Synthesis, characterization, and photocatalysis of Fe-doped TiO2: a combined experimental and theoretical study, Internationaal Journal of Photoenergy, Article ID 368750, 10 pages, doi:10.1155/2012/368750.
- 19. WU X.H., QIN W., DING X.B., WEN Y., LIU H.L., JIANG Z.H., 2007, Photocatalytic activity of Eudoped TiO2 ceramic films prepared by microplasma oxidation method, Journal of Physics and Chemistry of Solids 68, 2387–2393.
- 20. XU X.J., FANG X.S., ZHAI T.Y., ZENG H.B., LIU B.D., HU X.Y., BANDO Y., GOLBERG D., 2011, Tube-in-tube TiO2 nanotubes with porous walls: Fabrication, formation mechanism, and photocatalytic properties, Small 7, 445–449.
- 21. YAMASHITA H., HARADA M., MISAKA J., 2001, Application of ion beam techniques for preparation of metal ion-implanted TiO2 thin film photocatalyst available under visible light irradiation: Metal ion implantation and ionized cluster beam method, Journal of Synchrotron Radiation 8, 569–571.
- 22. YU J.C., ZHANG L., ZHENG Z., ZHAO J., 2003, Synthesis and characterization of phosphated mesoporous titanium dioxide with high photocatalytic activity, Chemistry of Materials 15, 2280–2286.
- 23. ZHOU W., ZHENG Y., WU G., 2006, Novel luminescent RE/TiO2 (RE=Eu, Gd) catalysts prepared by in-situation sol-gel approach construction of multi-functional precursors and their photo or photocatalytic oxidation properties, Applied Surface Science 252, 1387–1392.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7dab6c88-fa0b-4568-a228-2c0b0c0d23ea