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Laboratory Wastewater Treatment by Using Combination Methods of AOPs and Chemical-Physical Pretreatments

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Experimental activities carried out in laboratories usually produce complex wastewater. Due to practicum and research activities in educational laboratories, the wastewater generating from these laboratories contains organic and inorganic compounds which are dangerous for the environment if disposed of without prior treatment. Apart from high chemical oxygen demand (COD) and biological oxygen demand (BOD) values, laboratory wastewater also often contains heavy metals such as zinc (Zn), copper (Cu), chromium (Cr), lead (Pb), and iron (Fe) which are included in the hazardous waste category and can pollute the ground water. Therefore, this wastewater must be treated properly. The objective of this study is to reduce the pollutant load contained in laboratory wastewater by using combination methods of advanced oxidation processes (AOPs), and chemical-physical treatment namely coagulation and adsorption processes. The photo-Fenton process was selected as one of AOPs applied in this treatment. The effect of molar ratio variation and irradiation time in the Photo-Fenton process on the pollution load in the form of pH, COD, BOD, TSS, and heavy metals of Zn, Cu, Cr, Pb, and Fe was studied in this research. The results of the analysis of untreated laboratory wastewater samples showed that laboratory wastewater did not meet the wastewater quality standards regulated by the government of Republic of Indonesia. In this study, laboratory wastewater was treated using the pretreatment method of coagulation with alum and adsorption with activated carbon. The best results in this study were obtained in the final adsorption results after treatment with the photo-Fenton method using a molar ratio of 1: 300 for 60 minutes in which several parameters such as pH, Zn, Cu, Pb, and Fe had met environmental quality standards with the value of each parameter of 7; 0.01 mg/L; 2.9 mg/L; 0.03 mg/L; and 3.15 mg/L respectively. Meanwhile, the percentage reduction of COD, BOD, and TSS parameters was 87.49%, 87.02%, and 72.45% respectively.
Twórcy
  • Chemical Engineering Department, Faculty of Engineering, Universitas Sriwijaya, Jl. Palembang Prabumulih Km 32, Indralaya, South Sumatera, Indonesia
autor
  • Chemical Engineering Department, Faculty of Engineering, Universitas Sriwijaya, Jl. Palembang Prabumulih Km 32, Indralaya, South Sumatera, Indonesia
autor
  • Chemical Engineering Department, Faculty of Engineering, Universitas Sriwijaya, Jl. Palembang Prabumulih Km 32, Indralaya, South Sumatera, Indonesia
autor
  • Chemical Engineering Department, Faculty of Engineering, Universitas Sriwijaya, Jl. Palembang Prabumulih Km 32, Indralaya, South Sumatera, Indonesia
  • Chemical Engineering Department, Faculty of Engineering, Universitas Sriwijaya, Jl. Palembang Prabumulih Km 32, Indralaya, South Sumatera, Indonesia
  • Chemical Engineering Department, Faculty of Engineering, Universitas Sriwijaya, Jl. Palembang Prabumulih Km 32, Indralaya, South Sumatera, Indonesia
autor
  • Chemical Engineering Master Program, Faculty of Engineering, Universitas Sriwijaya, Srijayanegara, Palembang, South Sumatera, Indonesia
Bibliografia
  • 1. Agustina, T.E., Habiburrahman, M., Amalia, F., Arita, S., Faizal, M., Novia, N., Gayatri, R. 2022. Reduction of Copper, Iron, and Lead Content in Laboratory Wastewater Using Zinc Oxide Photocatalyst under Solar Irradiation. Journal of Ecological Engineering, 23(10), 107–115.
  • 2. Aprilianti, W., dan Wahyudi. 2020. Pengaruh Pembubuhan Tawas sebagai Koagulan terhadap Penurunan Biological Oxygen Demand Air Limbah Tahu di Dusun Bunsyafaah Desa Puyung Kecamatan Jonggat Lombok Tengah. Jurnal Sanitasi dan Lingkungan, 1(2), 65–71.
  • 3. Arita, S., Agustina, T.E., Ilmi, N., Pranajaya, V.D.W., Rianyza, G. 2022. Treatment of Laboratory Waste-water by Using Fenton Reagent and Combination of Coagulation-Adsorption as pretreatment. Journal of Ecological Engineering, 23(8), 211–221.
  • 4. Atalay, S., Ersöz, G. 2016. Advanced Oxidation Processes. Novel Catalysts in Advanced Oxidation of Organic Pollutants, 23–34.
  • 5. Deng, Y., Zhao, R. 2015. Advanced Oxidation Processes (AOPs) in Wastewater Treatment. Springer International Publishing, 1, 167–176.
  • 6. Ghime, D., Ghosh, P. 2020. Advanced Oxidation Processes: Applications, Trends, and Prospects. London: IntechOpen.
  • 7. Hasibuan, R., dan Marbun, I.D.S. 2018. Efektifitas Jenis Desikan dan Kecepatan Udara Terhadap Penyerapan Uap di Udara. Jurnal Teknik Kimia USU, 7(1), 41–47.
  • 8. Heriyani, O., dan Mugisidi, D. 2016. Pengaruh Karbon Aktif dan Zeolit pada pH Hasil Filtrasi Air Banjir. Seminar Nasional Teknoka. Jakarta, 30 Januari 2016.
  • 9. Jiang, J.Q. 2015. The role of Coagulation in the Water Treatment. Current Opinion in Chemical Engineering, 8, 36–44.
  • 10. Lesa, W.S., Ali, M., dan Rosariawari, F. 2020. Proses Foto Fenton dalam Reaktor Resirkulasi untuk Menyisihkan Beban Pencemar pada Lindi. Jukung Jurnal Teknik Lingkungan, 6(1), 54–65.
  • 11. Muthukumar, K., Babuponnusami, A. 2013. A Review on Fenton and Improvements to the Photo-Fenton Process for Wastewater Treatment. Journal of Environmental Chemical Engineering, 2(1), 557–572.
  • 12. Novia, Agustina, T.E., Riduan, S., Pangestu, G. 2023. Testing of a Laboratory Wastewater Treatment Prototype Using Coagulation, Adsorption, and Photo-Fenton Processes. Ecological Engineering & Environmental Technology, 24(5), 202–209.
  • 13. Nurhayati, I., Sugito., dan Pertiwi, A. 2018. Pengolahan Air limbah Laboratorium dengan Adsorpsi dan Pretreatment Netralisasi dan Koagulasi. Jurnal Sains dan Teknologi Lingkungan, 10(2), 125–138.
  • 14. Pungut., Kholif, M. A., dan Pratiwi, W.D.I. 2021. Penurunan Kadar Chemical Oxygen Demand (COD) dan Fosfat pada Limbah Laundry dengan Metode Adsorpsi. Jurnal Sains dan Teknologi Lingkungan, 13(2), 155–165.
  • 15.Rahmawati., Wilaksono, A., Amri, N., Davidson, K. N., Rimawan, B., dan Heriyanti. 2018. Adsorpsi Air Gambut Menggunakan Karbon Aktif dari Buah Bintaro. Chempublish Journal, 2(2), 11–20.
  • 16. Sukatiman dan Harjunowibowo, D. 2014. Pengaruh Porositas Buatan pada Adsorber terhadap Kualitas Transfer Panas dan Massa. JIPTEK, 7(2), 46–54.
  • 17. Swaminathan, M., Manickavachagam, M., Sillanpaa, M. 2014. Advanced Oxidation Processes for Wastewater Treatment 2013, International Journal of Photoenergy, 2014, 1–3.
  • 18. Tandiarrang, J., Devy, S. D., dan Trides, T. 2016. Studi Perbandingan Penggunaan Tawas dalam Pengolahan Air Asam Tambang di PT. Kaltim (Research Ratio Employing Aluminum Sulfat (Al2 (SO4) 3) And Calcium Hidroksida (Ca(OH)2) in Processing Acid Mine Drainage At PT Kaltim Diamond Coal Subdistri. Jurnal Teknologi Mineral FT UNMUL, 4(1), 23–30.
  • 19. Utama, S., Kristanto, H., dan Andreas, A. 2016. Adsorpsi Ion Logam Kromium (Cr(VI)) Menggunakan Karbon Aktif dan Bahan Baku Kulit Salah. Prosiding Seminar Nasional Teknik Kimia “Kejuangan”. Yogyakarta, 17 Maret 2016.
  • 20. Wahyuni, E.T., Supraba, D., Raharjo, S., dan Siswanta, D. 2019. Kajian Metode Foto-Fenton untuk Penurunan Konsentrasi Ion Logam Berat Pb(II) dan Cu(II) dalam Larutan Secara Simultan dan Sinergi. Jurnal Kimia Sains dan Aplikasi, 22(5), 192-199.
  • 21. Witono, J.R.B., Angela, M., Agnes, Y., dan Carissa, C. 2015. Sistem Integrasi Koagulasi dan Adsorpsi dalam Reduksi Logam (Cr6+ dan Cu2+) pada Limbah Cair Industri Tekstil. Prosiding Seminar Nasional Teknik Kimia “Kejuangan”. Yogyakarta, 18 Maret 2015.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa nr SONP/SP/546092/2022 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2024).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7d9cf17c-850a-4d02-afe2-51d3e591bd1e
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