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The mechanism of SO2 absorption in seawater is investigated, and the experiment was carried out accordingly. Emphasis is on applications of seawater scrubbing of ship’s power plant exhaust gas containing SO2. The formulated model is used to predict the influence of various parameters on both pH of tailwater and seawater desulfurization capability, e.g., the partial pressure of SO2, the partial pressure of CO2, tailwater temperature, pH and alkalinity of seawater. Experiment results indicated that the seawater desulfurization capacity increases with both increasing partial pressure of SO2, pH and alkalinity and decreasing partial pressure of CO2 and temperature. The study shows the desulfurization capacity of seawater with 3.5% salinity is approximately twice that of freshwater. Different scenarios in which the required absorbent supply rate for a given SO2 removal efficiency are studied. It is observed a 97% removal efficiency, corresponding to meeting the SOx limits in the SOx emission control areas (SECA) while operating on a heavy fuel oil containing sulfur 3.5 wt. %, requires a minimum water supply rate of 0.0407–0.0683 m3/kWh, depending mainly on the water composition in terms of alkalinity and salinity. Such data are important in assessing the operation cost of the water scrubbing system.
Słowa kluczowe
Czasopismo
Rocznik
Tom
Strony
31--47
Opis fizyczny
Bibliogr. 25 poz., tab., rys.
Twórcy
autor
- Merchant Marine College, Shanghai Maritime University, Shanghai 201306, China
autor
- Merchant Marine College, Shanghai Maritime University, Shanghai 201306, China
autor
- College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
autor
- College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
autor
- College of Ocean Science and Engineering, Shanghai Maritime University, Shanghai 201306, China
Bibliografia
- [1] CULLINANE K., CULLINANE S., Atmospheric emissions from shipping. The need for regulation and approaches to compliance, Trans. Rev., 2013, 33, 377.
- [2] IMO. Annex VI of MARPOL 73/78, Regulations for the prevention of air pollution from ships and NOx technical code, International Maritime Organization, London 1998.
- [3] JIANG L., KRONBAK J., CHRISTENSEN L.P., The costs and benefits of sulphur reduction measures. Sulphur scrubbers versus marine gas oil, Trans. Res., 2014, 28, 19.
- [4] MA H.R., STEERNBERG K., RIERA-PALOU X., TAIT N., Well-to-wake energy and greenhouse gas analysis of SOx abatement options for the marine industry, Transp. Res. D-Transp. Environ., 2012, 17, 301.
- [5] Ship Operations Cooperative Program. Exhaust gas cleaning system selection guide, File No. 10047.01, US Department of Transportation, Ellicott City, MD, 2011.
- [6] TANG X., LI T., YU H., ZHU Y., Prediction model for desulphurization efficiency of onboard magnesium-base seawater scrubber, Ocean Eng., 2014, 76, 98.
- [7] CAIAZZO G., LANGELLA G., MICCIO F., SCALA F., An experimental investigation on seawater SO2 scrubbing for marine application, Environ. Prog. Sustain. Energy, 2013, 36, 1179.
- [8] GHAZI A.E., HISHAM H.E., NAGLAA E.D., Solubility of sulfur dioxide in seawater, Ind. Eng. Chem. Res., 2001, 40, 1434.
- [9] ANDREASEN A., MAYER S., Use of seawater scrubbing for SO2 removal from marine engine exhaust gas, Energy Fuels, 2007, 21, 3274.
- [10] SUN X., MENG F., YANG F., Application of seawater to enhance SO2 removal from simulated flue gas through hollow fiber membrane contactor, J. Membr. Sci., 2008, 312, 6.
- [11] DARAKE S., RAHIMI A., HATAMIPOUR M.S., HAMZELOUI P., SO2 removal by seawater in a packed-bed tower. Experimental study and mathematical modeling, Sep. Sci. Technol., 2014, 49, 988.
- [12] TANG X., LI T., HAO Y., WU X., ZHU Y., Removal efficiency of magnesium-based seawater desulfurization for marine flue gas, J. Basic Sci. Eng., 2012, 20, 1081.
- [13] SCHULTES M., Absorption of sulphur dioxide with sodium hydroxide solution in packed columns, Chem. Eng. Technol., 1998, 21, 201.
- [14] EBRAHIMI S., PICIOREANU C., KLEEREBEZEM R., HEIJNEN J., LOOSDRECHT M.V., Rate-based modeling of SO2 absorption into aqueous NaHCO3/Na2CO3 solutions accompanied by the desorption of CO2, Chem. Eng. Sci., 2003, 58, 3589.
- [15] BIARD P.F., COUVERT A., Overview of mass transfer enhancement factor determination for acidic and basic compounds absorption in water, Chem. Eng. J., 2013, 222, 444.
- [16] MILLERO F.J., HERSHEY J.P., GEORGE J., ZHANG J.Z., The solubility of SO2 and the dissociation of H2SO3 in NaCl solutions, J. Atmos. Chem., 1989, 8, 377.
- [17] COX C., PASEL C., LUCKASA M., BATHEN D., Absorption of SO2 in different electrolyte solutions, seawater and brine, Fluid Phase Equil., 2015, 402, 89.
- [18] DOUABUL A., RILEY J., Solubility of sulfur dioxide in distilled water and decarbonated seawater, Chem. Eng., 1979, 24, 274.
- [19] ISO 22719:2008. Water quality. Determination of total alkalinity in seawater using high precision potentiometric titration, 30 June 2011.
- [20] China State Environmental Protection Administration. Determination of sulphur dioxide from exhausted gas of stationary source. Iodine titration method, 7 December 2000.
- [21] XIA J., RUMPF B., MAURER G., Solubility of sulfur dioxide in aqueous solutions of acetic acid, sodium acetate, and ammonium acetate in the temperature range from 313 to 393 K at pressures up to 3.3 MPa. Experimental results and comparison with correlations/predictions, Ind. Eng. Chem. Res., 1999, 38, 1149.
- [22] JUAN R.S., ALVAREZ M., DIAZ M.C., MARRERO M.C., Absorption equilibria of dilute SO2 in seawater, Chem. Eng., 2004, 49, 1710.
- [23] BEYAD Y., PUXTY G., WEI S., YANG N., XU D., MAEDER M., An SO2 tolerant process for CO2 capture, Int. J. Green. Gas Con., 2014, 31, 205.
- [24] LIU Y., LIU D., WALL T., Reporting of well stirred scrubber results. Scrubbing of SO2 and CO2 by caustic solutions at atmospheric pressure, The University of Newcastle, NSW, Australia, February 2012.
- [25] ERAN S., Handbook of Air Pollution from Internal Combustion Engines. Pollutant Formation and Control, Academic Press, New York 1998.
Uwagi
Opracowanie rekordu ze środków MNiSW, umowa Nr 461252 w ramach programu "Społeczna odpowiedzialność nauki" - moduł: Popularyzacja nauki i promocja sportu (2020).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7d748592-4709-4859-8a49-4f639200e322