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Study of aluminum phosphide levels in waste fumigants from food shipments following simple immersion treatment

Treść / Zawartość
Identyfikatory
Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Increasing concentrations of aluminum phosphide (AlP) in waste fumigants and residues pose a serious threat to human health. This study focused on the effectiveness of the widely used simple immersion treatment for waste fumigants from shipments, which usually have a higher concentration of residual AlP. A field survey of an operational process was conducted followed by a quantitative analysis of the immersion treatment's hydrolytic effect on AlP. Further investigation on the safety of waste fumigants after the immersion treatment was conducted. It was found that the AlP concentration in the waste fumigant varied significantly with the sampling date, ranging from 12.93 +/- 0.67 wt. % to 29.50 +/- 1.18 wt. %. Simple immersion treatment could reduce the concentration of residual AlP in waste fumigants but the hydrolytic effect varied largely ranging from 19.5% to 31.9%. The concentration of residual AlP remained high (9.1-20.1 wt. %) after the immersion treatment. About 3.2-15.2 wt. % of AlP remained in the samples, following an additional 40 days of natural air-drying when phosphine gas release was not detected. The study indicates that conventional simple immersion treatment cannot ensure the complete hydrolysis of AlP from waste fumigants of shipments.
Rocznik
Strony
19--27
Opis fizyczny
Bibliogr. 20 poz., tab., rys.
Twórcy
autor
  • Zhoushan Entry-Exit Inspection and Quarantine Bureau, Zhoushan 316000, China.
autor
  • Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycing, HangZhou 310012, China.
  • School of Environment Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012, China
autor
  • School of Environment Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012, China
autor
  • School of Environment Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012, China
  • Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycing, HangZhou 310012, China.
autor
  • School of Environment Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012, China
  • Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycing, HangZhou 310012, China.
autor
  • School of Environment Science and Engineering, Zhejiang Gongshang University, Hangzhou 310012, China
  • Zhejiang Provincial Key Laboratory of Solid Waste Treatment and Recycing, HangZhou 310012, China.
Bibliografia
  • [1] SCHMIDT E.L., JUZWIK J., SCHNEIDER B., Sulfuryl fluoride fumigation of red oak logs eradicates the oak wilt fungus, Eur. J. Wood Wood Prod., 1997, 55, 315–318.
  • [2] PANT H., TRIPATHI S., Fumigation of wood with aluminium phosphide for protection against fungi, J. Trop. For. Sci., 2011, 23 (4), 363–370.
  • [3] HANSEN H.L., PEDERSEN G., Poisoning at sea. Iinjuries caused by chemicals aboard Danish merchant ships 1988–1996, J. Toxicol. Clin. Toxicol., 2001, 39 (1), 21–26.
  • [4] MUSSHOFF F., PREUSS J., LIGNITZ E., MADEA B., A gas chromatographic analysis of phosphine in biological material in a case of suicide, Forensic. Sci. Int., 2008, 177 (2–3), 35–38.
  • [5] PHILLIPS T.W., THOMS E.M., DEMARK J., WALSE S., Fumigation [In:] D.W. Hagstrum, T.W. Phillips, G. Cuperus (Eds.), Stored Product Protection, Kansas State University. Manhattan, KS, 2012,157.
  • [6] BANKS H.J., A continuous cumulative procedure for analysis of phosphine, J. Stored Prod. Res.,1987, 23, 213–221.
  • [7] Degesch, Material safety data sheet. Spent Degesch aluminium phosphide products, Degesch America, Inc., Weyers Cave, VA 24486 USA, 2000, 4.
  • [8] LODDÉ B., LUCAS D., LETORT J.M., JEGADEN D., POUGNET R., DEWITTE J.D., Acute phosphine poisoning on board a bulk carrier. Analysis of factors leading to a fatal case, J. Occup. Med. Toxicol., 2015, 10, 10.
  • [9] GRAVER J.V.S., WHITTLE C.P., Phosphine residues remaining in aluminium phosphide preparations after burial, Phytoparasitica, 2001, supplement.
  • [10] FINKELMAN S., NAVARRO S., NAVARRO H., ASHBELL G., GLASER U., Fumigation of fresh herbs with phosphine as a new quarantine treatment, IOBC/WPRS Bull., 2012, 81, 193–197.
  • [11] ZHAO Y., ABBAR S., PHILLIPS T.W., SCHILLING M.W., Phosphine fumigation and residues in dry-cured ham in commercial applications, Meat Sci., 2015, 17, 57–63.
  • [12] CASA B., Application procedures for Gastoxin® tablets and Gastoxin® pellets, Casa Bernardo, Samaritá, 11346-300 São Vicente/SP, Brazil, 2000, <http://www.casabernardo.com.br/manutp.html>.
  • [13] Degesch, Applicator’s manual for Degesch Phostoxin® Pellets and Tablets, R. Degesch America Inc., Weyers Cave, VA 24486, USA, 1999, 21–22.
  • [14] BRUCE R.B., ROBBINS A.J., TUFT T.O., Fumigant residues, phosphine residues from phostoxin-treated grain, J. Agric. Food Chem., 1962, 10 (1), 18–21.
  • [15] CHEN C., HU X.J., ZHANG L.L., LI C.B., BI W.Y., MA M.P., The study on the determination of deliquescence velocity of aluminum phosphide pills and its application, J. Henan Univ. Techn., Nat. Sci. Ed., 2015, 36 (3), 81–85.
  • [16] AQSIQ, 56% Aluminium phosphide tablets (GB 5452-2001), General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China (AQSIQ), Beijing 2010.
  • [17] AQSIQ, Water quality. Determination of total phosphorus. Ammonium molybdate spectrophotometric method (GB 11893-89), General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China (AQSIQ), Beijing 1989.
  • [18] MEP, Water quality, Determination of total nitrogen. Alkaline potassium persulfate digestion UV spectrophotometric method (HJ 636-2012), Ministry of Environmental Protection of the People’s Republic of China (MEP), Beijing 2012.
  • [19] PESHIN S.S., SRIVASTAVA A., HALDER N., GUPTA Y.K., Pesticide poisoning trend analysis of 13 years. A retrospective study based on telephone calls at the National Poisons Information Centre, All India Institute of Medical Sciences, New Delhi, J. Forensic. Leg. Med., 2014, 22, 57–61.
  • [20] RAIZADA A., KALRA O.P, KHAIRA A., YADAV A., Profile of hospital admissions following acute poisoning from a major teaching hospital in North India, Trop Doct., 2012, 42 (2), 70–73.
Uwagi
PL
Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2018).
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-7d4e22d2-083e-40a3-b50c-f19ab79eb844
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